Measurement of the effects of shape resonances on vibrational intensity distribution in molecular photoionization
- National Bureau of Standards, Washington, DC (United States), National Measurement Lab.
- Daresbury Lab., Warrington (United Kingdom)
- Argonne National Laboratory (ANL), Argonne, IL (United States)
We report striking non-Franck-Condon vibrational intensity distributions associated with the shape resonance in the 5σ photoionization channel of CO. This example confirms the recent theoretical prediction that shape resonances are very sensitive to internuclear separation, leading to different resonance energies and profiles, and non-Franck-Condon intensities in alternative vibrational channels.
- Research Organization:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- W-31109-ENG-38
- OSTI ID:
- 1178327
- Report Number(s):
- ANL--79-65-Pt.1
- Country of Publication:
- United States
- Language:
- English
Similar Records
Effects of shape resonances on vibrational intensity distributions in molecular photoionization
Wavelength and vibrational-state dependence of photoelectron angular distributions. Resonance effects in 5σ photoionization of CO
Theoretical prediction of shape-resonance-enhanced nuclear motion effects in molecular photionization
Journal Article
·
Mon Sep 10 00:00:00 EDT 1979
· Phys. Rev. Lett.; (United States)
·
OSTI ID:5815904
Wavelength and vibrational-state dependence of photoelectron angular distributions. Resonance effects in 5σ photoionization of CO
Technical Report
·
Fri Nov 30 23:00:00 EST 1979
·
OSTI ID:1178326
Theoretical prediction of shape-resonance-enhanced nuclear motion effects in molecular photionization
Technical Report
·
Fri Nov 30 23:00:00 EST 1979
·
OSTI ID:1178334