Small-Scale Experiments-Sandia Instrumented Thermal Ignition (SITI) testing summary
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
A number of cook-off experiments were performed to provide understanding of potential thermal ignition of drum 68660 in the February 14, 2014 radiation release at WIPP. Testing was begun according to the plan provided in Appendix B, and deviated significantly based on initial findings and other information developed during the testing. Two general types of experiments were performed: ones with nitric acid neutralized to varying degrees with Kolorsafe neutralizer, and ones with no added free liquid. Results indicate that reactivity is greater in the dry mixture, and that Fe nitrate and Ca nitrate play significant roles in ignition behavior whereas Pb nitrate, Cr nitrate, and oxalic acid do not. Within mixtures with liquid, very little exothermic behavior is observed with Swheat and water, but adding neutralized acid and nitrate salts results in significant reactivity and ignition. This behavior is suppressed by liquid water, and ignition occurs after the water has fully vaporized, although it is not clear if ignition occurs quickly because of the relatively high wall temperature at the end of the vaporization process.
- Research Organization:
- Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Organization:
- USDOE National Nuclear Security Administration (NNSA)
- DOE Contract Number:
- AC04-94AL85000
- OSTI ID:
- 1177755
- Report Number(s):
- SAND--2015-0861R; 563498
- Country of Publication:
- United States
- Language:
- English
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