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Title: Fabrication of multilayered thin films via spin-assembly

Patent ·
OSTI ID:1176117

An process of forming multilayer thin film heterostructures is disclosed and includes applying a solution including a first water-soluble polymer from the group of polyanionic species, polycationic species and uncharged polymer species onto a substrate to form a first coating layer on the substrate, drying the first coating layer on the substrate, applying a solution including a second water-soluble polymer from the group of polyanionic species, polycationic species and uncharged polymer species onto the substrate having the first coating layer to form a second coating layer on the first coating layer wherein the second water-soluble polymer is of a different material than the first water-soluble polymer, and drying the second coating layer on the first coating layer so as to form a bilayer structure on the substrate. Optionally, one or more additional applying and drying sequences can be repeated with a water-soluble polymer from the group of polyanionic species, polycationic species and uncharged polymer species, so that a predetermined plurality of layers are built up upon the substrate.

Research Organization:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
W-7405-ENG-36
Assignee:
The Regents of the University of California (Los Alamos, NM)
Patent Number(s):
7,179,679
OSTI ID:
1176117
Resource Relation:
Patent File Date: 2003 Jul 11
Country of Publication:
United States
Language:
English

References (4)

Fuzzy Nanoassemblies: Toward Layered Polymeric Multicomposites journal August 1997
Polyelectrolyte Trilayer Combinations Using Spin-Assembly and Ionic Self-Assembly journal October 2003
Polyelectrolyte Spin-Assembly journal January 2002
Factors Controlling the Growth of Polyelectrolyte Multilayers journal November 1999

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