Electrically conductive polycrystalline diamond and particulate metal based electrodes

Swain, Greg M.; Wang, Jian

Title: Electrically conductive polycrystalline diamond and particulate metal based electrodes

Patent · Tue Apr 26 00:00:00 EDT 2005

OSTI ID:1175327

Swain, Greg M.; Wang, Jian

An electrically conducting and dimensionally stable diamond (12, 14) and metal particle (13) electrode produced by electrodepositing the metal on the diamond is described. The electrode is particularly useful in harsh chemical environments and at high current densities and potentials. The electrode is particularly useful for generating hydrogen, and for reducing oxygen and oxidizing methanol in reactions which are of importance in fuel cells.

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Research Organization:: Michigan State Univ., East Lansing, MI (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG02-01ER15120

Assignee:: Board of Trustees of Michigan State University (East Lansing, MI)

Patent Number(s):: 6,884,290

Application Number:: 10/338,318

OSTI ID:: 1175327

Country of Publication:: United States

Language:: English

References (11)

Peer Reviewed: Boron-Doped Diamond Thin-Film Electrodes Xu, Jishou; Granger, Michael C.; Chen, Qingyun Analytical Chemistry, Vol. 69, Issue 19 https://doi.org/10.1021/ac971791z	journal	October 1997
Applications of Diamond Thin Films in Electrochemistry Swain, Greg M.; Anderson, Alfred B.; Angus, John C. MRS Bulletin, Vol. 23, Issue 9 https://doi.org/10.1557/S0883769400029389	journal	September 1998
Electrochemical Oxidation of NADH at Highly Boron-Doped Diamond Electrodes Rao, Tata N.; Yagi, I.; Miwa, T. Analytical Chemistry, Vol. 71, Issue 13 https://doi.org/10.1021/ac981376m	journal	July 1999
Summary of Recent Progress with Diamond Electrodes in Electroanalysis, Spectroelectrochemistry and Electrocatalysis Witek, M.; Wang, J.; Stotter, J. Journal of Wide Bandgap Materials, Vol. 8, Issue 3-4 https://doi.org/10.1106/152451102024653	journal	January 2001
Incorporation of Pt Particles in Boron-Doped Diamond Thin Films Applications in Electrocatalysis Wang, Jian Electrochemical and Solid-State Letters, Vol. 3, Issue 6 https://doi.org/10.1149/1.1391126	journal	January 1999
The Susceptibility to Surface Corrosion in Acidic Fluoride Media: A Comparison of Diamond, HOPG, and Glassy Carbon Electrodes Swain, Greg M. Journal of The Electrochemical Society, Vol. 141, Issue 12 https://doi.org/10.1149/1.2059343	journal	January 1994
Diamond Electrodes Tenne, Reshef; Lévy-Clément, Claude Israel Journal of Chemistry, Vol. 38, Issue 1-2 https://doi.org/10.1002/ijch.199800007	journal	January 1998
Morphological and Microstructural Stability of Boron-Doped Diamond Thin Film Electrodes in an Acidic Chloride Medium at High Anodic Current Densities Chen, Qingyun Journal of The Electrochemical Society, Vol. 144, Issue 11 https://doi.org/10.1149/1.1838096	journal	January 1997
Carbons as supports for industrial precious metal catalysts Auer, E.; Freund, A.; Pietsch, J. Applied Catalysis A: General, Vol. 173, Issue 2 https://doi.org/10.1016/S0926-860X(98)00184-7	journal	October 1998
Synthetic diamond in electrochemistry Pleskov, Yurii V. Russian Chemical Reviews, Vol. 68, Issue 5 https://doi.org/10.1070/RC1999v068n05ABEH000494	journal	May 1999
Electrochemical Behavior of Boron-Doped Diamond Electrodes Vinokur, N. Journal of The Electrochemical Society, Vol. 143, Issue 10 https://doi.org/10.1149/1.1837157	journal	January 1996

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