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Electrically conductive diamond electrodes

Patent ·
OSTI ID:988388

An electrically conductive diamond electrode and process for preparation thereof is described. The electrode comprises diamond particles coated with electrically conductive doped diamond preferably by chemical vapor deposition which are held together with a binder. The electrodes are useful for oxidation reduction in gas, such as hydrogen generation by electrolysis.

Research Organization:
Michigan State University
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-01ER15120
Assignee:
Board of Trustees of Michigan State University (East Lansing, MI)
Patent Number(s):
7,534,296
Application Number:
11/378,109
OSTI ID:
988388
Country of Publication:
United States
Language:
English

References (36)

Diamond Electrodes journal January 1998
The impact of semiconductors on the concepts of electrochemistry journal November 1990
Electrochemical selectivity for redox systems at oxygen-terminated diamond electrodes journal September 1999
Conductive diamond thin-films in electrochemistry journal October 2003
Carbons as supports for industrial precious metal catalysts journal October 1998
Standard Electrochemical Behavior of High-Quality, Boron-Doped Polycrystalline Diamond Thin-Film Electrodes journal August 2000
Effects of redox system structure on electron-transfer kinetics at ordered graphite and glassy carbon electrodes journal November 1992
Imaging the incipient electrochemical oxidation of highly oriented pyrolytic graphite journal May 1993
Electron Transfer Kinetics at Modified Carbon Electrode Surfaces: The Role of Specific Surface Sites journal September 1995
Vacuum heat-treatment for activation of glassy carbon electrodes journal December 1985
Electrochemical Performance of Diamond Thin-Film Electrodes from Different Commercial Sources journal May 2004
Peer Reviewed: Boron-Doped Diamond Thin-Film Electrodes journal October 1997
Electrochemical Oxidation of NADH at Highly Boron-Doped Diamond Electrodes journal July 1999
Characterization and Electrochemical Responsiveness of Boron-Doped Nanocrystalline Diamond Thin-Film Electrodes journal February 2003
A Confocal Raman Imaging Study of an Optically Transparent Boron-Doped Diamond Electrode journal October 2002
Mechanism of electrochemical activation of carbon electrodes: role of graphite lattice defects journal May 1989
Formation, microstructural characteristics and stability of carbon supported platinum catalysts for low temperature fuel cells journal January 2003
Materials for fuel-cell technologies journal November 2001
Raman and photoluminescence analysis of stress state and impurity distribution in diamond thin films journal December 1995
Synthetic diamond in electrochemistry journal May 1999
Detonation synthesis ultradispersed diamonds: properties and applications journal July 2001
Summary of Recent Progress with Diamond Electrodes in Electroanalysis, Spectroelectrochemistry and Electrocatalysis journal January 2001
Incorporation of Pt Particles in Boron-Doped Diamond Thin Films Applications in Electrocatalysis journal January 1999
The Influence of Surface Interactions on the Reversibility of Ferri/Ferrocyanide at Boron-Doped Diamond Thin-Film Electrodes journal January 1999
Dimensionally Stable Pt/Diamond Composite Electrodes in Concentrated H[sub 3]PO[sub 4] at High Temperature journal January 2002
Fabrication and Evaluation of Platinum/Diamond Composite Electrodes for Electrocatalysis journal January 2003
Electrocatalytic Corrosion of Carbon Support in PEMFC Cathodes journal January 2004
Extent of PEMFC Cathode Surface Oxidation by Oxygen and Water Measured by CV journal January 2004
Characterization of Vulcan Electrochemically Oxidized under Simulated PEM Fuel Cell Conditions journal January 2004
Effect of sp[sup 2]-Bonded Nondiamond Carbon Impurity on the Response of Boron-Doped Polycrystalline Diamond Thin-Film Electrodes journal January 2004
Electrochemical Behavior of Boron-Doped Diamond Electrodes journal January 1996
Morphological and Microstructural Stability of Boron-Doped Diamond Thin Film Electrodes in an Acidic Chloride Medium at High Anodic Current Densities journal January 1997
Preparation and Characterization of Boron-Doped Diamond Powder journal January 2005
The Susceptibility to Surface Corrosion in Acidic Fluoride Media: A Comparison of Diamond, HOPG, and Glassy Carbon Electrodes journal January 1994
In Situ Observations of Shape Evolution during Copper Dissolution Using Atomic Force Microscopy journal January 1992
Applications of Diamond Thin Films in Electrochemistry journal September 1998