A Two-Column Method for the Separation of Kr and Xe from Process Off-Gases

Journal Article · Tue Jul 29 04:00:00 EDT 2014 · Industrial and Engineering Chemistry Research, 53(32):12893-12899

DOI:https://doi.org/10.1021/ie502156h· OSTI ID:1171292

Liu, Jian; Fernandez, Carlos A.; Martin, Paul F.; Thallapally, Praveen K.; Strachan, Denis M.

Two metal organic framework materials were investigated to determine the removal efficiency and capacity of MOF materials for krypton recovery from air at non-cryogenic temperatures. Our two bed breakthrough measurements on NiDOBDC and a partially fluorinated FMOFCu indicate these materials can capture and separate parts per million levels of Xe and Kr from air and, with a two-bed system, separate Xe from Kr. In a two-bed system, the he removal efficiency and adsorption capacity for Kr on these two MOFs were further increased Xe was removed in the first bed. This shows a promising future for MOFs in a radioactive nuclides separation from spent fuel.

• Research Organization: Pacific Northwest National Laboratory (PNNL), Richland, WA (US)
• Sponsoring Organization: USDOE
• DOE Contract Number: AC05-76RL01830
• OSTI ID: 1171292
• Report Number(s): PNNL-SA-100864; AF5805010
• Journal Information: Industrial and Engineering Chemistry Research, 53(32):12893-12899, Journal Name: Industrial and Engineering Chemistry Research, 53(32):12893-12899
• Country of Publication: United States
• Language: English