A Two-Column Method for the Separation of Kr and Xe from Process Off-Gases
Journal Article
·
· Industrial and Engineering Chemistry Research, 53(32):12893-12899
Two metal organic framework materials were investigated to determine the removal efficiency and capacity of MOF materials for krypton recovery from air at non-cryogenic temperatures. Our two bed breakthrough measurements on NiDOBDC and a partially fluorinated FMOFCu indicate these materials can capture and separate parts per million levels of Xe and Kr from air and, with a two-bed system, separate Xe from Kr. In a two-bed system, the he removal efficiency and adsorption capacity for Kr on these two MOFs were further increased Xe was removed in the first bed. This shows a promising future for MOFs in a radioactive nuclides separation from spent fuel.
- Research Organization:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 1171292
- Report Number(s):
- PNNL-SA-100864; AF5805010
- Journal Information:
- Industrial and Engineering Chemistry Research, 53(32):12893-12899, Journal Name: Industrial and Engineering Chemistry Research, 53(32):12893-12899
- Country of Publication:
- United States
- Language:
- English
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