Demonstrate the removal efficiency and capacity of MOF materials for krypton recovery

Technical Report · Thu Aug 01 04:00:00 EDT 2013

DOI:https://doi.org/10.2172/1111231· OSTI ID:1111231

Thallapally, Praveen K. ^[1]; Liu, Jian ^[1]; Strachan, Denis M. ^[1]

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1. Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Metal organic framework materials (MOFs) were developed and tested in support of the U.S. Department of Energy Office of Nuclear Energy, Fuel Cycle Technology Separations and Waste Forms Campaign. Specifically, materials are being developed for the removal of xenon (Xe) and krypton (Kr) from gaseous products of nuclear fuel reprocessing unit operations. Two metal organic framework structures were investigated in greater detail to demonstrate the removal efficiency and capacity of MOF materials for krypton recovery. Our two bed breakthrough measurements on NiDOBDC and FMOFCu indicate these materials can capture and separate parts per million levels of Xe and Kr from air. The removal efficiency and adsorption capacity for Kr on these two MOFs were further increased upon removal of Xe upfront.

• Research Organization: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
• Sponsoring Organization: USDOE Office of Nuclear Energy (NE), Nuclear Fuel Cycle and Supply Chain
• DOE Contract Number: AC05-76RL01830
• OSTI ID: 1111231
• Report Number(s): PNNL--22693; FCR&D-SWF--2013-000278; AF5805000
• Country of Publication: United States
• Language: English

Related Subjects

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS
36 MATERIALS SCIENCE
krypton
metal organic framework
noble gas removal
nuclear fuel reprocessing
xenon