A Three-Dimensional Microporous Metal-Metalloporphyrin Framework
- Ames
A new porphyrin-based microporous MOF, {Mn(II)0.5[Mn(II)4Cl(Mn(III)Cl-ttzpp)2(H2O)4]}·(DEF)20·(CH3OH)18·(H2O)12 (UTSA-57), has been constructed from {5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrinato} manganese(III) chloride as the metalloligand. The MOF adopts the rare scu topology with one-dimensional square nanotube-like channels of about 20 Å. UTSA-57a exhibits permanent porosity and displays moderately high performance for C2H2/CH4 separation at room temperature.
- Research Organization:
- Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)
- Sponsoring Organization:
- OTHER
- OSTI ID:
- 1168522
- Journal Information:
- Inorg. Chem., Journal Name: Inorg. Chem. Journal Issue: (1) ; 01, 2015 Vol. 54
- Country of Publication:
- United States
- Language:
- ENGLISH
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