Modification of Hydroxyapatite with Ion-Selective Complexants: 1-Hydroxyethane-1,1-diphosphonic Acid

Daniels, Yasmine; Lyczko, Nathalie; Nzihou, Ange; Alexandratos, Spiro D.

doi:10.1021/ie504181z

Title: Modification of Hydroxyapatite with Ion-Selective Complexants: 1-Hydroxyethane-1,1-diphosphonic Acid

Journal Article · Fri Jan 09 00:00:00 EST 2015 · Industrial and Engineering Chemistry Research

DOI:https://doi.org/10.1021/ie504181z· OSTI ID:1167144

Daniels, Yasmine ^[1]; Lyczko, Nathalie ^[2]; Nzihou, Ange ^[2]; Alexandratos, Spiro D. ^[1]

Department of Chemistry, Graduate Center of the City University of New York, 365 Fifth Avenue, New York, New York 10016, United States, Department of Chemistry, Hunter College of the City University of New York, 695 Park Avenue, New York, New York 10065, United States
Université de Toulouse, Ecole des Mines d’Albi, CNRS, Centre RAPSODEE, Campus Jarlard, F-81013 Albi cedex 09, France

Hydroxyapatite (HAP) was modified with 1-hydroxyethane-1,1-diphosphonic acid (HEDP), and its effect on divalent metal ion binding was determined. HAP was synthesized from calcium hydroxide and phosphoric acid. After calcination, it was modified with HEDP, and the influence of time and temperature on the modification was investigated. HEDP incorporation increased as its initial solution concentration increased from 0.01 to 0.50 M. Unmodified and modified HAP were characterized using Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy, and specific surface area analysis. Ca/P ratios, acid capacities, and phosphorus elemental analyses gave the effect of modification on composition and surface characteristics. A high reaction temperature produced new phosphonate bands at 993, 1082, and 1144 cm^–1 that indicated the presence of HEDP. HAP modification at a high temperature–long reaction time had the highest HEDP loading and gave the sharpest XRD peaks. The emergence of new HAP–HEDP strands was observed in SEM images for treated samples while EDS showed high phosphorus contents in these strands. Modified HAP had a high acid capacity from the additional P–OH groups in HEDP. The P(O)OH groups maintain their ability to bind metal ions within the HAP matrix: contacting the modified HAP with 10–4 N nitrate solutions of five transition metal ions gives an affinity sequence of Pb(II) > Cd(II) > Zn(II) > Ni(II) > Cu(II). Here, this result is comparable to that of commercially available di(2-ethylhexyl)phosphoric acid, a common solvent extractant, and the trend is consistent with the Misono softness parameter of metal ion polarizabilities.

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Research Organization:: Hunter College, New York, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-02ER15287

OSTI ID:: 1167144

Alternate ID(s):: OSTI ID: 1345804

Journal Information:: Industrial and Engineering Chemistry Research, Journal Name: Industrial and Engineering Chemistry Research Vol. 54 Journal Issue: 2; ISSN 0888-5885

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 17 works

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