Probabilistic evaluation of shallow groundwater resources at a hypothetical carbon sequestration site

Dai, Zhenxue; Keating, Elizabeth; Bacon, Diana H.; Viswanathan, Hari; Stauffer, Philip; Jordan, Amy B.; Pawar, Rajesh

doi:10.1038/srep04006

Title: Probabilistic evaluation of shallow groundwater resources at a hypothetical carbon sequestration site

Journal Article · Fri Mar 07 00:00:00 EST 2014 · Scientific Reports

DOI:https://doi.org/10.1038/srep04006· OSTI ID:1158456

Dai, Zhenxue ^[1]; Keating, Elizabeth ^[1]; Bacon, Diana H. ^[2]; Viswanathan, Hari ^[1]; Stauffer, Philip ^[1]; Jordan, Amy B. ^[1]; Pawar, Rajesh ^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Carbon sequestration in geologic reservoirs is an important approach for mitigating greenhouse gases emissions to the atmosphere. This study first develops an integrated Monte Carlo method for simulating CO₂ and brine leakage from carbon sequestration and subsequent geochemical interactions in shallow aquifers. Then, we estimate probability distributions of five risk proxies related to the likelihood and volume of changes in pH, total dissolved solids, and trace concentrations of lead, arsenic, and cadmium for two possible consequence thresholds. The results indicate that shallow groundwater resources may degrade locally around leakage points by reduced pH and increased total dissolved solids (TDS). The volumes of pH and TDS plumes are most sensitive to aquifer porosity, permeability, and CO₂ and brine leakage rates. The estimated plume size of pH change is the largest, while that of cadmium is the smallest among the risk proxies. Plume volume distributions of arsenic and lead are similar to those of TDS. The scientific results from this study provide substantial insight for understanding risks of deep fluids leaking into shallow aquifers, determining the area of review, and designing monitoring networks at carbon sequestration sites.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1158456

Report Number(s):: PNNL-SA-100638; AA9010200

Journal Information:: Scientific Reports, Vol. 4; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 60 works

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References (24)

Evaluation of Potential Changes in Groundwater Quality in Response to CO2 Leakage from Deep Geologic Storage Apps, J. A.; Zheng, L.; Zhang, Y. Transport in Porous Media, Vol. 82, Issue 1 https://doi.org/10.1007/s11242-009-9509-8	journal	January 2010
Geochemical Implications of Gas Leakage associated with Geologic CO ₂ Storage—A Qualitative Review Harvey, Omar R.; Qafoku, Nikolla P.; Cantrell, Kirk J. Environmental Science & Technology, Vol. 47, Issue 1 https://doi.org/10.1021/es3029457	journal	August 2012
Trace Metal Source Terms in Carbon Sequestration Environments Karamalidis, Athanasios K.; Torres, Sharon G.; Hakala, J. Alexandra Environmental Science & Technology, Vol. 47, Issue 1 https://doi.org/10.1021/es304832m	journal	August 2012
Changes in the chemistry of shallow groundwater related to the 2008 injection of CO₂ at the ZERT field site, Bozeman, Montana Kharaka, Yousif K.; Thordsen, James J.; Kakouros, Evangelos Environmental Earth Sciences, Vol. 60, Issue 2, p. 273-284 https://doi.org/10.1007/s12665-009-0401-1	journal	December 2009
Potential Impacts of Leakage from Deep CO ₂ Geosequestration on Overlying Freshwater Aquifers Little, Mark G.; Jackson, Robert B. Environmental Science & Technology, Vol. 44, Issue 23 https://doi.org/10.1021/es102235w	journal	December 2010
Potential risks to freshwater resources as a result of leakage from CO2 geological storage: a batch-reaction experiment Lu, Jiemin; Partin, Judson W.; Hovorka, Susan D. Environmental Earth Sciences, Vol. 60, Issue 2 https://doi.org/10.1007/s12665-009-0382-0	journal	December 2009
A System Model for Geologic Sequestration of Carbon Dioxide Stauffer, Philip H.; Viswanathan, Hari S.; Pawar, Rajesh J. Environmental Science & Technology, Vol. 43, Issue 3 https://doi.org/10.1021/es800403w	journal	February 2009
Greening Coal: Breakthroughs and Challenges in Carbon Capture and Storage Stauffer, Philip H.; Keating, Gordon N.; Middleton, Richard S. Environmental Science & Technology, Vol. 45, Issue 20 https://doi.org/10.1021/es200510f	journal	October 2011
Effect of Dissolved CO ₂ on a Shallow Groundwater System: A Controlled Release Field Experiment Trautz, Robert C.; Pugh, John D.; Varadharajan, Charuleka Environmental Science & Technology, Vol. 47, Issue 1 https://doi.org/10.1021/es301280t	journal	August 2012
Developing a robust geochemical and reactive transport model to evaluate possible sources of arsenic at the CO2 sequestration natural analog site in Chimayo, New Mexico Viswanathan, Hari; Dai, Zhenxue; Lopano, Christina International Journal of Greenhouse Gas Control, Vol. 10 https://doi.org/10.1016/j.ijggc.2012.06.007	journal	September 2012
Dissolution of a mineral phase in potable aquifers due to CO2 releases from deep formations; effect of dissolution kinetics Wang, Sookyun; Jaffe, Peter R. Energy Conversion and Management, Vol. 45, Issue 18-19 https://doi.org/10.1016/j.enconman.2004.01.002	journal	November 2004
Geochemical Impacts to Groundwater from Geologic Carbon Sequestration: Controls on pH and Inorganic Carbon Concentrations from Reaction Path and Kinetic Modeling Wilkin, Richard T.; DiGiulio, Dominic C. Environmental Science & Technology, Vol. 44, Issue 12 https://doi.org/10.1021/es100559j	journal	June 2010
Geochemical modeling of changes in shallow groundwater chemistry observed during the MSU-ZERT CO2 injection experiment Zheng, Liange; Apps, John A.; Spycher, Nicolas International Journal of Greenhouse Gas Control, Vol. 7 https://doi.org/10.1016/j.ijggc.2011.10.003	journal	March 2012
Single-well push–pull test for assessing potential impacts of CO2 leakage on groundwater quality in a shallow Gulf Coast aquifer in Cranfield, Mississippi Yang, Changbing; Mickler, Patrick J.; Reedy, Robert International Journal of Greenhouse Gas Control, Vol. 18 https://doi.org/10.1016/j.ijggc.2012.12.030	journal	October 2013
CO2 leakage impacts on shallow groundwater: Field-scale reactive-transport simulations informed by observations at a natural analog site Keating, Elizabeth H.; Hakala, J. Alexandra; Viswanathan, Hari Applied Geochemistry, Vol. 30 https://doi.org/10.1016/j.apgeochem.2012.08.007	journal	March 2013
Simulation of industrial-scale CO2 storage: Multi-scale heterogeneity and its impacts on storage capacity, injectivity and leakage Deng, Hailin; Stauffer, Philip H.; Dai, Zhenxue International Journal of Greenhouse Gas Control, Vol. 10 https://doi.org/10.1016/j.ijggc.2012.07.003	journal	September 2012
An Integrated Framework for Optimizing CO ₂ Sequestration and Enhanced Oil Recovery Dai, Zhenxue; Middleton, Richard; Viswanathan, Hari Environmental Science & Technology Letters, Vol. 1, Issue 1 https://doi.org/10.1021/ez4001033	journal	November 2013
On modeling the potential impacts of CO2 sequestration on shallow groundwater: Transport of organics and co-injected H2S by supercritical CO2 to shallow aquifers Zheng, Liange; Spycher, Nicolas; Birkholzer, Jens International Journal of Greenhouse Gas Control, Vol. 14 https://doi.org/10.1016/j.ijggc.2013.01.014	journal	May 2013
Transmissivity estimation for highly heterogeneous aquifers: comparison of three methods applied to the Edwards Aquifer, Texas, USA Painter, Scott L.; Woodbury, Allan D.; Jiang, Yefang Hydrogeology Journal, Vol. 15, Issue 2 https://doi.org/10.1007/s10040-006-0071-y	journal	July 2006
Development of a Hybrid Process and System Model for the Assessment of Wellbore Leakage at a Geologic CO ₂ Sequestration Site Viswanathan, Hari S.; Pawar, Rajesh J.; Stauffer, Philip H. Environmental Science & Technology, Vol. 42, Issue 19 https://doi.org/10.1021/es800417x	journal	October 2008
Representing aquifer architecture in macrodispersivity models with an analytical solution of the transition probability matrix Dai, Zhenxue; Wolfsberg, Andrew; Lu, Zhiming Geophysical Research Letters, Vol. 34, Issue 20 https://doi.org/10.1029/2007GL031608	journal	January 2007
Aquifer structure identification using stochastic inversion Harp, Dylan R.; Dai, Zhenxue; Wolfsberg, Andrew V. Geophysical Research Letters, Vol. 35, Issue 8 https://doi.org/10.1029/2008GL033585	journal	January 2008
Multiphase flow dynamics during CO2 disposal into saline aquifers Pruess, Karsten; García, Julio Environmental Geology, Vol. 42, Issue 2-3 https://doi.org/10.1007/s00254-001-0498-3	journal	March 2002
Identification of relative conductivity models for water flow and solute transport in unsaturated bentonite Dai, Zhenxue; Samper, Javier; Wolfsberg, Andrew Physics and Chemistry of the Earth, Parts A/B/C, Vol. 33 https://doi.org/10.1016/j.pce.2008.10.012	journal	January 2008

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Sensitivity thresholds of groundwater parameters for detecting CO2 leakage at a geologic carbon sequestration site Berger, Peter M.; Wimmer, Bracken; Iranmanesh, Abbas Environmental Monitoring and Assessment, Vol. 191, Issue 11 https://doi.org/10.1007/s10661-019-7880-7	journal	October 2019
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Reactive transport modeling of arsenic mobilization in shallow groundwater: impacts of CO2 and brine leakage Xiao, Ting; Dai, Zhenxue; McPherson, Brian Geomechanics and Geophysics for Geo-Energy and Geo-Resources, Vol. 3, Issue 3 https://doi.org/10.1007/s40948-017-0058-2	journal	April 2017
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