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Microcontact printing of octadecylsiloxane on the surface of silicon dioxide and its application in microfabrication

Journal Article · · Journal of the American Chemical Society
; ; ;  [1]
  1. Harvard Univ., Cambridge, MA (United States)

This paper describes the use of microcontact printing ({mu}CP) for patterning self-assembled monolayers (SAMs) of alkylsiloxanes on the surface of silicon dioxide. {mu}CP is a convenient technique for generating patterned SAMs of alkanethiolates on gold, but it has not been applied to Si/SiO{sub 2} and glass. The SAMs of alkyltrichlorosilanes on the hydroxyl-terminated surfaces are less ordered than those of alkanethiolates on gold, and they form more slowly. Here we demonstrate that {mu}CP can, nonetheless, be used to produce patterned SAMs of alkylsiloxanes on Si/SiO{sub 2}. We believe this technique will prove valuable for many other applications: for example, studies of protein absorption and cell attachment where high edge resolution is not critical. 17 refs., 2 figs., 1 tab.

Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-91ER45439
OSTI ID:
111228
Journal Information:
Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 37 Vol. 117; ISSN JACSAT; ISSN 0002-7863
Country of Publication:
United States
Language:
English

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