Asymmetric catalytic hydrogenation reactions in supercritical carbon dioxide
Journal Article
·
· Journal of the American Chemical Society
- Duke Univ., Durham, NC (United States)
- Los Alamos National Lab., NM (United States)
We demonstrate that asymmetric catalytic hydrogenation reactions can be conducted in supercritical CO{sub 2} and that, in some cases, higher enantioselectivities can be achieved in this solvent relative to conventional solvents. These preliminary studies effectively demonstrate the feasibility of conducting highly enantioselective hydrogenation reactions in supercritical CO{sub 2}. Importantly, we have shown that higher enantioselectivities may be achieved in supercritical CO{sub 2} relative to conventional solvents. 16 refs., 2 tabs.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 111209
- Journal Information:
- Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 31 Vol. 117; ISSN JACSAT; ISSN 0002-7863
- Country of Publication:
- United States
- Language:
- English
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