Low-temperature oxidation of methane in the presence of SiO{sub 2}-supported palladium(II) complexes and phosphorus - molybdenum - vanadium heteropoly compounds
Journal Article
·
· Theoretical and Experimental Chemistry
- L.M. Litvinenko Institute of Physical and Organic Chemistry and Carbon Chemistry (Russian Federation)
In the presence of silica-gel supported PdCl{sub 2} and phosphorus - molybdenum - vanadium heteropoly compounds of the 12th series, methane is oxidized at 300{degree}C to form methyl chloride (up to 20% with respect to the reacted methane at the maximum CH{sub 3}Cl concentration), carbon dioxide (maximum yield 25%), and carbon compounds of catalyst components (up to 10% with respect to methane carbon).
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 110820
- Journal Information:
- Theoretical and Experimental Chemistry, Journal Name: Theoretical and Experimental Chemistry Journal Issue: 3 Vol. 30; ISSN 0040-5760; ISSN TEXCAK
- Country of Publication:
- United States
- Language:
- English
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