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Organic hybrid planar-nanocrystalline bulk heterojunctions

Patent ·
OSTI ID:1083786
A photosensitive optoelectronic device having an improved hybrid planar bulk heterojunction includes a plurality of photoconductive materials disposed between the anode and the cathode. The photoconductive materials include a first continuous layer of donor material and a second continuous layer of acceptor material. A first network of donor material or materials extends from the first continuous layer toward the second continuous layer, providing continuous pathways for conduction of holes to the first continuous layer. A second network of acceptor material or materials extends from the second continuous layer toward the first continuous layer, providing continuous pathways for conduction of electrons to the second continuous layer. The first network and the second network are interlaced with each other. At least one other photoconductive material is interspersed between the interlaced networks. This other photoconductive material or materials has an absorption spectra different from the donor and acceptor materials.
Research Organization:
NETL (National Energy Technology Laboratory, Pittsburgh, PA, and Morgantown, WV (United States))
Sponsoring Organization:
USDOE
Assignee:
The Trustees of Princeton University (Princeton, NJ) ; The Regents of the University of Michigan (Ann Arbor, MI)
Patent Number(s):
8,415,757
Application Number:
13/011,255
OSTI ID:
1083786
Country of Publication:
United States
Language:
English

References (8)

Long-range absorption enhancement in organic tandem thin-film solar cells containing silver nanoclusters journal December 2004
Efficient photon harvesting at high optical intensities in ultrathin organic double-heterostructure photovoltaic diodes journal May 2000
Controlled growth of a molecular bulk heterojunction photovoltaic cell journal December 2004
Novel photovoltaic devices based on donor-acceptor molecular and conducting polymer systems journal January 1997
Organic Solar Cells Using Transparent SnO2–F Anodes journal August 2006
Efficient bulk heterojunction photovoltaic cells using small-molecular-weight organic thin films journal September 2003
Small molecular weight organic thin-film photodetectors and solar cells journal April 2003
Improvement of Sensitivity in Long-Wavelength Range in Organic Thin-Film Solar Cell with Interpenetrating Semilayered Structure journal January 2006

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