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Selective inorganic thin films

Technical Report ·
DOI:https://doi.org/10.2172/105137· OSTI ID:105137
; ;  [1]
  1. Sandia National Laboratories, Albuquerque, NM (United States); and others

This project is developing inorganic thin films as membranes for gas separation applications, and as discriminating coatings for liquid-phase chemical sensors. Our goal is to synthesize these coatings with tailored porosity and surface chemistry on porous substrates and on acoustic and optical sensors. Molecular sieve films offer the possibility of performing separations involving hydrogen, air, and natural gas constituents at elevated temperatures with very high separation factors. We are focusing on improving permeability and molecular sieve properties of crystalline zeolitic membranes made by hydrothermally reacting layered multicomponent sol-gel films deposited on mesoporous substrates. We also used acoustic plate mode (APM) oscillator and surface plasmon resonance (SPR) sensor elements as substrates for sol-gel films, and have both used these modified sensors to determine physical properties of the films and have determined the sensitivity and selectivity of these sensors to aqueous chemical species.

Research Organization:
Oak Ridge National Lab., TN (United States)
OSTI ID:
105137
Report Number(s):
ORNL/TM--12963; ON: DE95016129
Country of Publication:
United States
Language:
English

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