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Molecular dynamics simulation of hydration in myoglobin

Technical Report ·
DOI:https://doi.org/10.2172/104441· OSTI ID:104441
 [1];  [2]
  1. New Mexico Univ., Albuquerque, NM (United States). Dept. of Biochemistry
  2. Los Alamos National Lab., NM (United States)

This study was carried out to evaluate the stability of the 89 bound water molecules that were observed in the neutron diffraction study of CO myoglobin. The myoglobin structure derived from the neutron analysis was used as the starting point in the molecular dynamics simulation using the software package CHARMM. After salvation of the protein, energy minimization and equilibration of the system, 50 pico seconds of Newtonian dynamics was performed. This data showed that only 4 water molecules are continously bound during the length of this simulation while the other solvent molecules exhibit considerable mobility and are breaking and reforming hydrogen bonds with the protein. At any instant during the simulation, 73 of the hydration sites observed in the neutron structure are occupied by water.

Research Organization:
Los Alamos National Lab., NM (United States); New Mexico Univ., Albuquerque, NM (United States). Dept. of Biochemistry
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
W-7405-ENG-36
OSTI ID:
104441
Report Number(s):
LA-SUB--95-103; ON: DE95017363
Country of Publication:
United States
Language:
English

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