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U.S. Department of Energy
Office of Scientific and Technical Information

ACTUAL-WASTE TESTS OF ENHANCED CHEMICAL CLEANING FOR RETRIEVAL OF SRS HLW SLUDGE TANK HEELS AND DECOMPOSITION OF OXALIC ACID

Conference ·
OSTI ID:1033338
Savannah River National Laboratory conducted a series of tests on the Enhanced Chemical Cleaning (ECC) process using actual Savannah River Site waste material from Tanks 5F and 12H. Testing involved sludge dissolution with 2 wt% oxalic acid, the decomposition of the oxalates by ozonolysis (with and without the aid of ultraviolet light), the evaporation of water from the product, and tracking the concentrations of key components throughout the process. During ECC actual waste testing, the process was successful in decomposing oxalate to below the target levels without causing substantial physical or chemical changes in the product sludge.
Research Organization:
SRS
Sponsoring Organization:
DOE
DOE Contract Number:
AC09-08SR22470
OSTI ID:
1033338
Report Number(s):
SRNL-STI-2011-00496
Country of Publication:
United States
Language:
English