TESTING OF ENHANCED CHEMICAL CLEANING OF SRS ACTUAL WASTE TANK 5F AND TANK 12H SLUDGES

Technical Report · Mon Aug 22 04:00:00 EDT 2011

DOI:https://doi.org/10.2172/1023616· OSTI ID:1023616

Martino, C; King, W

Forty three of the High Level Waste (HLW) tanks at the Savannah River Site (SRS) have internal structures that hinder removal of the last approximately five thousand gallons of waste sludge solely by mechanical means. Chemical cleaning can be utilized to dissolve the sludge heel with oxalic acid (OA) and pump the material to a separate waste tank in preparation for final disposition. This dissolved sludge material is pH adjusted downstream of the dissolution process, precipitating the sludge components along with sodium oxalate solids. The large quantities of sodium oxalate and other metal oxalates formed impact downstream processes by requiring additional washing during sludge batch preparation and increase the amount of material that must be processed in the tank farm evaporator systems and the Saltstone Processing Facility. Enhanced Chemical Cleaning (ECC) was identified as a potential method for greatly reducing the impact of oxalate additions to the SRS Tank Farms without adding additional components to the waste that would extend processing or increase waste form volumes. In support of Savannah River Site (SRS) tank closure efforts, the Savannah River National Laboratory (SRNL) conducted Real Waste Testing (RWT) to evaluate an alternative to the baseline 8 wt. % OA chemical cleaning technology for tank sludge heel removal. The baseline OA technology results in the addition of significant volumes of oxalate salts to the SRS tank farm and there is insufficient space to accommodate the neutralized streams resulting from the treatment of the multiple remaining waste tanks requiring closure. ECC is a promising alternative to bulk OA cleaning, which utilizes a more dilute OA (nominally 2 wt. % at a pH of around 2) and an oxalate destruction technology. The technology is being adapted by AREVA from their decontamination technology for Nuclear Power Plant secondary side scale removal. This report contains results from the SRNL small scale testing of the ECC process using SRS sludge tank sample material. A Task Technical and Quality Assurance Plan (TTQAP) details the experimental plan as outlined by the Technical Task Request (TTR). The TTR identifies that the data produced by this testing and results included in this report will support the technical baseline with portions having a safety class functional classification. The primary goals for SRNL RWT are as follows: (1) to confirm ECC performance with real tank sludge samples, (2) to determine the impact of ECC on fate of actinides and the other sludge metals, and (3) to determine changes, if any, in solids flow and settling behavior.

• Research Organization: SRS
• Sponsoring Organization: DOE
• DOE Contract Number: AC09-08SR22470
• OSTI ID: 1023616
• Report Number(s): SRNL-STI-2011-00360
• Country of Publication: United States
• Language: English

Related Subjects

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES
21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS
ACTINIDES
CLEANING
CLOSURES
DECONTAMINATION
DISSOLUTION
EVAPORATORS
NUCLEAR POWER PLANTS
OXALATES
OXALIC ACID
QUALITY ASSURANCE
REMOVAL
SAVANNAH RIVER PLANT
SLUDGES
SODIUM
SOLIDS FLOW
STORAGE FACILITIES
TANKS
TESTING
WASHING
WASTE FORMS
WASTES