Technetium Dichloride: A New Binary Halide Containing Metal-Metal Multiple Bonds
Journal Article
·
· Journal of the American Chemical Society
- UNLV
Technetium dichloride has been discovered. It was synthesized from the elements and characterized by several physical techniques, including single crystal X-ray diffraction. In the solid state, technetium dichloride exhibits a new structure type consisting of infinite chains of face sharing [Tc{sub 2}Cl{sub 8}] rectangular prisms that are packed in a commensurate supercell. The metal-metal separation in the prisms is 2.127(2) {angstrom}, a distance consistent with the presence of a Tc {triple_bond} Tc triple bond that is also supported by electronic structure calculations.
- Research Organization:
- Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)
- Sponsoring Organization:
- USDOE Office of Science (SC)
- OSTI ID:
- 1027660
- Journal Information:
- Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 23 Vol. 133; ISSN JACSAT; ISSN 0002-7863
- Country of Publication:
- United States
- Language:
- ENGLISH
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