Technetium dichloride : a new binary halide containing metal-metal multiple bonds.
- Materials Science Division
Technetium dichloride has been discovered. It was synthesized from the elements and characterized by several physical techniques, including single crystal X-ray diffraction. In the solid state, technetium dichloride exhibits a new structure type consisting of infinite chains of face sharing [Tc{sub 2}Cl{sub 8}] rectangular prisms that are packed in a commensurate supercell. The metal-metal separation in the prisms is 2.127(2) {angstrom}, a distance consistent with the presence of a Tc {triple_bond} Tc triple bond that is also supported by electronic structure calculations.
- Research Organization:
- Argonne National Laboratory (ANL)
- Sponsoring Organization:
- SC; NEUP Grant
- DOE Contract Number:
- AC02-06CH11357
- OSTI ID:
- 1019254
- Report Number(s):
- ANL/MSD/JA-70169
- Journal Information:
- J. Am. Chem. Soc., Journal Name: J. Am. Chem. Soc. Journal Issue: 23 ; Jun. 15, 2011 Vol. 133; ISSN 0002-7863
- Country of Publication:
- United States
- Language:
- ENGLISH
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