Reaction kinetics and product distributions in photoelectrochemical cells. Technical progress report, March 15, 1992--March 14, 1993
Hot electron reaction studies at p-InP/CH{sub 3}CN interface revealed essential/desirable features for redox systems used to investigate hot carriers in photoelectrocehmical cells. Reduction of dibromoethylbenzene (DBEB) in presence of metallocene couples is being studied using rotating rink disk electrodes of n-and p-InP disks and Pt rings. At highly doped p-InP electrodes, reduction of DBEB can be very efficient (>30%). A minielectrochemical cell was used to investigate electron transfer at nonilluminated n-WSe{sub 2}/dimethylferrocene{sup +/0} interfaces.
- Research Organization:
- Colorado Univ., Boulder, CO (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG02-84ER13247
- OSTI ID:
- 10190566
- Report Number(s):
- DOE/ER/13247--8; ON: DE93003885
- Country of Publication:
- United States
- Language:
- English
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