Unlike pair interactions in N{sub 2}-H{sub 2}O mixtures

Conference · Thu Jul 01 00:00:00 EDT 1993

OSTI ID:10112176

van Thiel, M; Ree, F H

Statisical-mechanical chemical equilibrium calculations have been performed to determined the deviation of the unlike species potential from that predicted by the Lorentz-Berthelot rule. The potentials of the water-water and nitrogen-nitrogen interactions have been reexamined in the light of remaining deviations from experiment. The resulting deviation of the constant from one (1), in the extended Lorentz-Berthelot rule, is determined from the best exp-6 potentials for nitrogen and water with consideration of possible deviations of the measured detonation velocity of RX-23-AB from its ideal equilibrium value.

• Research Organization: Lawrence Livermore National Lab., CA (United States)
• Sponsoring Organization: USDOE, Washington, DC (United States)
• DOE Contract Number: W-7405-ENG-48
• OSTI ID: 10112176
• Report Number(s): UCRL-JC-113295; CONF-930676-66; ON: DE94004867
• Resource Relation: Conference: 14. international conference of the International Association for the Advancement of High Pressure Science and Technology,Colorado Springs, CO (United States),27 Jun - 2 Jul 1993; Other Information: PBD: Jul 1993
• Country of Publication: United States
• Language: English

Related Subjects

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEFENSE
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
NITROGEN
EQUATIONS OF STATE
WATER VAPOR
CHEMICAL EXPLOSIVES
COMBUSTION PRODUCTS
DETONATIONS
STATISTICAL MECHANICS
BINARY MIXTURES
450100
400800
CHEMICAL EXPLOSIONS AND EXPLOSIVES
COMBUSTION, PYROLYSIS, AND HIGH-TEMPERATURE CHEMISTRY