Unlike pair interactions in N[sub 2]-H[sub 2]O mixtures

Conference · Sun Jul 10 00:00:00 EDT 1994 · AIP Conference Proceedings (American Institute of Physics); (United States)

OSTI ID:6914960

van Thiel, M; Ree, F H ^[1]

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1. Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551 (United States)

Statistical-mechanical chemical equilibrium calculations have been performed to determine the deviation of the unlike species potential from that predicted by the Lorentz-Berthelot rule. The potentials of the water-water and nitrogen-nitrogen interactions have been reexamined in the light of remaining deviations from experiment. The resulting deviation of the constant from one (1), in the extended Lorentz-Berthelot rule, is determined from the best exp-6 potentials for nitrogen and water with consideration of possible deviations of the measured detonation velocity of RX-23-AB from its ideal equilibrium value. [copyright] 1994 American Institute of Physics

• DOE Contract Number: W-7405-ENG-48
• OSTI ID: 6914960
• Report Number(s): CONF-921145-; CODEN: APCPCS
• Journal Information: AIP Conference Proceedings (American Institute of Physics); (United States), Vol. 309:1; Conference: Production and neutralization of negative ions and beams, Upton, NY (United States), 9-13 Nov 1992; ISSN 0094-243X
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BINARY MIXTURES
INTERMOLECULAR FORCES
NITROGEN
EQUATIONS OF STATE
WATER
CHEMICAL COMPOSITION
EXPLOSIVES
POTENTIALS
PRESSURE DEPENDENCE
SHOCK WAVES
STATISTICAL MECHANICS
VERY HIGH PRESSURE
DISPERSIONS
ELEMENTS
EQUATIONS
HYDROGEN COMPOUNDS
MECHANICS
MIXTURES
NONMETALS
OXYGEN COMPOUNDS
400201* - Chemical & Physicochemical Properties