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Structural simulations of nanomaterials self-assembled from ionic macrocycles.

Technical Report ·
DOI:https://doi.org/10.2172/1008138· OSTI ID:1008138
;  [1]
  1. University of New Mexico, Albuquerque, NM

Recent research at Sandia has discovered a new class of organic binary ionic solids with tunable optical, electronic, and photochemical properties. These nanomaterials, consisting of a novel class of organic binary ionic solids, are currently being developed at Sandia for applications in batteries, supercapacitors, and solar energy technologies. They are composed of self-assembled oligomeric arrays of very large anions and large cations, but their crucial internal arrangement is thus far unknown. This report describes (a) the development of a relevant model of nonconvex particles decorated with ions interacting through short-ranged Yukawa potentials, and (b) the results of initial Monte Carlo simulations of the self-assembly binary ionic solids.

Research Organization:
Sandia National Laboratories
Sponsoring Organization:
USDOE
DOE Contract Number:
AC04-94AL85000
OSTI ID:
1008138
Report Number(s):
SAND2010-7014
Country of Publication:
United States
Language:
English

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