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Hierarchical cooperative binary ionic porphyrin nanocomposites

Journal Article · · ChemComm
DOI:https://doi.org/10.1039/c2cc30845b· OSTI ID:1124601
 [1]; ; ; ; ; ; ;
  1. Washington University in St. Louis
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Cooperative binary ionic (CBI) solids comprise a versatile new class of opto-electronic and catalytic materials consisting of ionically self-assembled pairs of organic anions and cations. Herein, we report CBI nanocomposites formed by growing nanoparticles of one type of porphyrin CBI solid onto a second porphyrin CBI substructure with complementary functionality.

Research Organization:
Washington Univ., St. Louis, MO (United States); Energy Frontier Research Centers (EFRC) (United States). Photosynthetic Antenna Research Center (PARC)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
DOE Contract Number:
SC0001035
OSTI ID:
1124601
Report Number(s):
DE-SC0001035-107
Journal Information:
ChemComm, Journal Name: ChemComm Journal Issue: 40 Vol. 48; ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (11)

Cobalt−Porphyrin Catalyzed Electrochemical Reduction of Carbon Dioxide in Water. 2. Mechanism from First Principles journal September 2010
Self-assembled porphyrin nanostructures journal January 2009
Donor−Acceptor Biomorphs from the Ionic Self-Assembly of Porphyrins journal June 2010
Self-Assembled Molecular Rafts at Liquid|Liquid Interfaces for Four-Electron Oxygen Reduction journal December 2011
Binary ionic porphyrin nanosheets: electronic and light-harvesting properties regulated by crystal structure journal January 2012
Porphyrin Nanofiber Bundles from Phase‐Transfer Ionic Self‐Assembly and Their Photocatalytic Self‐Metallization journal September 2006
Hydrogen Generation by Hangman Metalloporphyrins journal June 2011
Electroreduction of carbon dioxide on gas-diffusion electrodes modified by metal phthalocyanines journal January 1989
Self-Organized Porphyrinic Materials journal May 2009
Morphological families of self-assembled porphyrin structures and their photosensitization of hydrogen generation journal January 2011
Porphyrin Nanotubes by Ionic Self-Assembly journal December 2004

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14 SOLAR ENERGY