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Submicrometer-Resolution Mapping of Ultraweak 355-nm Absorption in HfO2 Monolayers Using Photothermal Heterodyne Imaging

Journal Article · · Laser-Induced Damage in Optical Materials: 2010
OSTI ID:1004172
 [1]; ; ; ; ;
  1. Laboratory for Laser Energetics, University of Rochester, Rochester, NY
Nanosecond-pulse UV-laser-damage initiation in multilayer coatings comprised from metal oxide as a high-index component, and silica oxide as a low-index material, is strongly linked to metal oxide. The nature of the absorbing species and their physical properties remain unknown because of extremely small sizes. Previous experimental evidence provided by high-resolution mapping of damage morphology points to a few-nanometer scale of these absorbers. This work demonstrates submicrometer mapping of 355-nm absorption in HfO2 monolayers using a recently developed photothermal heterodyne imaging technique. Comparison of absorption maps with spatial distribution of UV pulsed-laser–induced damage morphology allows one to better estimate the size and densities of nanoscale absorbing defects in hafnia thin films. Possible defect-formation mechanisms are discussed.
Research Organization:
Laboratory for Laser Energetics, University of Rochester
Sponsoring Organization:
USDOE
DOE Contract Number:
FC52-08NA28302
OSTI ID:
1004172
Report Number(s):
DOE/NA/28302-990; 2010-62; 1972
Journal Information:
Laser-Induced Damage in Optical Materials: 2010, Journal Name: Laser-Induced Damage in Optical Materials: 2010 Vol. 7842
Country of Publication:
United States
Language:
English

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