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Method for rapid, controllable growth and thickness, of epitaxial silicon films

Patent ·
OSTI ID:1001799

A method of producing epitaxial silicon films on a c-Si wafer substrate using hot wire chemical vapor deposition by controlling the rate of silicon deposition in a temperature range that spans the transition from a monohydride to a hydrogen free silicon surface in a vacuum, to obtain phase-pure epitaxial silicon film of increased thickness is disclosed. The method includes placing a c-Si substrate in a HWCVD reactor chamber. The method also includes supplying a gas containing silicon at a sufficient rate into the reaction chamber to interact with the substrate to deposit a layer containing silicon thereon at a predefined growth rate to obtain phase-pure epitaxial silicon film of increased thickness.

Research Organization:
Midwest Research Institute
Sponsoring Organization:
USDOE
DOE Contract Number:
AC36-99GO10337
Assignee:
Alliance for Sustainable Energy, LLC (Golden, CO)
Patent Number(s):
7,601,215
Application Number:
11/560,886
OSTI ID:
1001799
Country of Publication:
United States
Language:
English

References (13)

Roughness, impurities and strain in low-temperature epitaxial silicon films grown by tantalum filament hot-wire chemical vapor deposition journal January 2006
Silicon epitaxy at 650–800 °C using low‐pressure chemical vapor deposition both with and without plasma enhancement journal April 1985
Low-temperature epitaxial growth of Si by electron cyclotron resonance chemical vapor deposition journal January 2001
Epitaxial growth of Fe-Si compounds on the silicon (111) face journal December 1992
Low temperature epitaxial silicon film growth using high vacuum electron‐cyclotron‐resonance plasma deposition journal May 1995
Atomic Structure of Clean Si(113) Surfaces: Theory and Experiment journal September 1994
Self-consistent pseudopotential calculations for Si (111) surfaces: Unreconstructed (1×1) and reconstructed (2×1) model structures journal November 1975
Hot-wire CVD-grown epitaxial Si films on Si (100) substrates and a model of epitaxial breakdown journal April 2006
Physics of Solid-Phase Epitaxy of Hydrogenated Amorphous Silicon for Thin Film Si Photovoltaics journal January 2006
Kinetics of solid phase epitaxy in thick amorphous Si layers formed by MeV ion implantation journal September 1990
Explanation of the limiting thickness observed in low-temperature silicon epitaxy journal November 2000
How deposition parameters control growth dynamics of nc-Si deposited by hot-wire chemical vapor deposition journal January 2006
Role of hydrogen desorption in the chemical-vapor deposition of Si(100) epitaxial films using disilane journal July 1991

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