The transformation of organic amines by transition metal cluster compounds. Progress report, 1993--1994

Technical Report · Sat Jan 01 00:00:00 EST 1994

DOI:https://doi.org/10.2172/10175474· OSTI ID:10175474

Adams, R D

In the recent year, the authors extended investigations into insertion reactions by investigating the insertion of dicarboxylate acetylene into the metal-metal bond of Re{sub 2}(CO){sub 9}(NCMe). Secondly, the authors considered the ring opening reactions of the cyclic thioethers: tetrahydrothiophene and thiacyclohexane when complexed to Os{sub 3}(CO){sub 10}(NCMe){sub 2}. In a third effort, various osmium complexes of cyclobutynes were synthesized and the subsequent reactivity probed. Finally, energy storage (via absorption of UV-visible photons) in osmium cluster compounds was investigated.

• Research Organization: South Carolina Univ., Columbia, SC (United States). Dept. of Chemistry
• Sponsoring Organization: USDOE, Washington, DC (United States)
• DOE Contract Number: FG09-84ER13296
• OSTI ID: 10175474
• Report Number(s): DOE/ER/13296-10; ON: DE94017151; TRN: 94:007747
• Resource Relation: Other Information: PBD: Jan 1994
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
14 SOLAR ENERGY
ORGANOMETALLIC COMPOUNDS
CHEMICAL REACTIONS
ENERGY STORAGE
OSMIUM COMPOUNDS
RHENIUM COMPOUNDS
ALKYNES
PROGRESS REPORT
TRANSITION ELEMENT COMPOUNDS
ORGANIC SULFUR COMPOUNDS
ULTRAVIOLET RADIATION
VISIBLE RADIATION
PHOTOCHEMISTRY
400201
140505
400500
CHEMICAL AND PHYSICOCHEMICAL PROPERTIES
PHOTOCHEMICAL, PHOTOBIOLOGICAL, AND THERMOCHEMICAL CONVERSION