The transformation of organic amines by transition metal cluster compounds

Technical Report · Tue Jan 01 00:00:00 EST 1991

OSTI ID:5959458

Adams, R D

This report from the Department of Chemistry, University of South Carolina contains the following sections: (1) hydrogenation of ynamines by metal cluster complexes; (2) synthesis and characterization of ynamine complexes of dirhenium; (3) ring opening of strained ring thioethers: (a) reaction of thietane with Os{sub 3}(CO){sub 11}NCMe, (b) reaction of 3,3 dimethylthietane with Os{sub 3}(CO){sub 10}(NCMe){sub 2}; (4) CO splitting: The reaction of Mn{sub 2}(CO){sub 9}NCMe with ynamine; and (5) publications under this project in 1990. 16 refs., 9 figs.

• Research Organization: South Carolina Univ., Columbia, SC (USA). Dept. of Chemistry
• Sponsoring Organization: USDOE; USDOE, Washington, DC (USA)
• DOE Contract Number: FG09-84ER13296
• OSTI ID: 5959458
• Report Number(s): DOE/ER/13296-7; ON: DE91010622
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
OSMIUM COMPLEXES
HYDROGENATION
RHENIUM COMPLEXES
CHEMICAL PREPARATION
ALKYNES
AMINES
CARBONYLS
DIMERS
LIGANDS
MANGANESE COMPLEXES
ORGANIC SULFUR COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PROGRESS REPORT
STRUCTURAL CHEMICAL ANALYSIS
CHEMICAL REACTIONS
COMPLEXES
DOCUMENT TYPES
HYDROCARBONS
ORGANIC COMPOUNDS
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties