Effects of strain relaxation in Pr0.67Sr0.33MnO3 films probed by polarization dependent X-ray absorption near edge structure
Abstract
In this study, the Mn K edge X-ray absorption near edge structure (XANES) of Pr0.67Sr0.33MnO3 films with different thicknesses on (001) LaAlO3 substrate were measured, and the effects of strain relaxation on film properties were investigated. The films experienced in-plane compressive strain and out-of-plane tensile strain. Strain relaxation evolved with the film thickness. In the polarization dependent XANES measurements, the in-plane (parallel) and out-of-plane (perpendicular) XANES spectrocopies were anisotropic with different absorption energy Er. The resonance energy Er along two directions shifted towards each other with increasing film thickness. Based on the X-ray diffraction results, it was suggested that the strain relaxation weakened the difference of the local environment and probability of electronic charge transfer (between Mn 3d and O 2p orbitals) along the in-plane and out-of-plane directions, which was responsible for the change of Er. XANES is a useful tool to probe the electronic structures, of which the effects on magnetic properties with the strain relaxation was also been studied.
- Authors:
-
- National Univ. of Singapore (Singapore)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1248885
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 2; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
zhang, Bangmin, Chen, Jingsheng, Venkatesan, T., Sun, Cheng -Jun, Heald, Steve M., Chow, Gan Moog, Yang, Ping, Chi, Xiao, and Lin, Weinan. Effects of strain relaxation in Pr0.67Sr0.33MnO3 films probed by polarization dependent X-ray absorption near edge structure. United States: N. p., 2016.
Web. doi:10.1038/srep19886.
zhang, Bangmin, Chen, Jingsheng, Venkatesan, T., Sun, Cheng -Jun, Heald, Steve M., Chow, Gan Moog, Yang, Ping, Chi, Xiao, & Lin, Weinan. Effects of strain relaxation in Pr0.67Sr0.33MnO3 films probed by polarization dependent X-ray absorption near edge structure. United States. https://doi.org/10.1038/srep19886
zhang, Bangmin, Chen, Jingsheng, Venkatesan, T., Sun, Cheng -Jun, Heald, Steve M., Chow, Gan Moog, Yang, Ping, Chi, Xiao, and Lin, Weinan. Thu .
"Effects of strain relaxation in Pr0.67Sr0.33MnO3 films probed by polarization dependent X-ray absorption near edge structure". United States. https://doi.org/10.1038/srep19886. https://www.osti.gov/servlets/purl/1248885.
@article{osti_1248885,
title = {Effects of strain relaxation in Pr0.67Sr0.33MnO3 films probed by polarization dependent X-ray absorption near edge structure},
author = {zhang, Bangmin and Chen, Jingsheng and Venkatesan, T. and Sun, Cheng -Jun and Heald, Steve M. and Chow, Gan Moog and Yang, Ping and Chi, Xiao and Lin, Weinan},
abstractNote = {In this study, the Mn K edge X-ray absorption near edge structure (XANES) of Pr0.67Sr0.33MnO3 films with different thicknesses on (001) LaAlO3 substrate were measured, and the effects of strain relaxation on film properties were investigated. The films experienced in-plane compressive strain and out-of-plane tensile strain. Strain relaxation evolved with the film thickness. In the polarization dependent XANES measurements, the in-plane (parallel) and out-of-plane (perpendicular) XANES spectrocopies were anisotropic with different absorption energy Er. The resonance energy Er along two directions shifted towards each other with increasing film thickness. Based on the X-ray diffraction results, it was suggested that the strain relaxation weakened the difference of the local environment and probability of electronic charge transfer (between Mn 3d and O 2p orbitals) along the in-plane and out-of-plane directions, which was responsible for the change of Er. XANES is a useful tool to probe the electronic structures, of which the effects on magnetic properties with the strain relaxation was also been studied.},
doi = {10.1038/srep19886},
journal = {Scientific Reports},
number = 2,
volume = 6,
place = {United States},
year = {Thu Jan 28 00:00:00 EST 2016},
month = {Thu Jan 28 00:00:00 EST 2016}
}
Web of Science
Works referenced in this record:
Local atomic and electronic structures of epitaxial strained LaCoO thin films
journal, January 2012
- Sterbinsky, G. E.; Ryan, P. J.; Kim, J. -W.
- Physical Review B, Vol. 85, Issue 2
Low-temperature resistivity of La 0.7 Sr 0.3 Mn O 3 ultra thin films: Role of quantum interference effects
journal, March 2006
- Maritato, L.; Adamo, C.; Barone, C.
- Physical Review B, Vol. 73, Issue 9
Cooperative Jahn-Teller effect and electron-phonon coupling in
journal, April 1996
- Millis, A. J.
- Physical Review B, Vol. 53, Issue 13
Pressure-dependent electronic structures and orbital hybridization of Mn states in multiferroic BiMnO : A combined x-ray absorption, x-ray emission, and resonant x-ray emission study
journal, July 2012
- Chen, J. M.; Haw, S. C.; Lee, J. M.
- Physical Review B, Vol. 86, Issue 4
Octahedral Tilting in Perovskites. II. Structure Stabilizing Forces
journal, February 1997
- Woodward, P. M.
- Acta Crystallographica Section B Structural Science, Vol. 53, Issue 1
Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides
journal, May 2013
- Qiao, Ruimin; Chin, Timothy; Harris, Stephen J.
- Current Applied Physics, Vol. 13, Issue 3
Role of Interface Structure and Chemistry in Resistive Switching of NiO Nanocrystals on SrTiO3
journal, August 2015
- Cheng, Xuan; Sullaphen, Jivika; Weyland, Matthew
- Microscopy and Microanalysis, Vol. 21, Issue S3
Role of strain in magnetotransport properties of Pr0.67Sr0.33MnO3 thin films
journal, May 2000
- Wang, H. S.; Wertz, E.; Hu, Y. F.
- Journal of Applied Physics, Vol. 87, Issue 10
Strain-induced crystal structure change in ultrathin films of Pr0.7Sr0.3MnO3
journal, February 2002
- MacLaren, Ian; Wang, Zhong Lin; Wang, H. S.
- Applied Physics Letters, Vol. 80, Issue 8
Self-doping processes between planes and chains in the metal-to-superconductor transition of YBa2Cu3O6.9
text, January 2014
- Magnuson, Martin; Strocov, Thorsten Schmitt Vladimir N.; Schlappa, Justina
- arXiv
Surface Nanostructures in Manganite Films
journal, June 2014
- Gambardella, A.; Graziosi, P.; Bergenti, I.
- Scientific Reports, Vol. 4, Issue 1
Unipolar resistive switching behavior of amorphous gallium oxide thin films for nonvolatile memory applications
journal, January 2015
- Guo, D. Y.; Wu, Z. P.; An, Y. H.
- Applied Physics Letters, Vol. 106, Issue 4
Surface symmetry-breaking and strain effects on orbital occupancy in transition metal perovskite epitaxial films
journal, January 2012
- Pesquera, D.; Herranz, G.; Barla, A.
- Nature Communications, Vol. 3, Issue 1
Self-doping processes between planes and chains in the metal-to-superconductor transition of YBa2Cu3O6.9
journal, November 2014
- Magnuson, M.; Schmitt, T.; Strocov, V. N.
- Scientific Reports, Vol. 4, Issue 1
Octahedral Tilting in Perovskites. I. Geometrical Considerations
journal, February 1997
- Woodward, P. M.
- Acta Crystallographica Section B Structural Science, Vol. 53, Issue 1
CMR manganites: physics, thin films and devices
journal, April 2003
- Haghiri-Gosnet, A-M; Renard, J-P
- Journal of Physics D: Applied Physics, Vol. 36, Issue 8
A Minimal tight-binding model for ferromagnetic canted bilayer manganites
text, January 2014
- Baublitz, M.; Lane, C.; Lin, Hsin
- arXiv
Enhanced tunnelling electroresistance effect due to a ferroelectrically induced phase transition at a magnetic complex oxide interface
journal, February 2013
- Yin, Y. W.; Burton, J. D.; Kim, Y-M.
- Nature Materials, Vol. 12, Issue 5
Dynamic Jahn-Teller Effect and Colossal Magnetoresistance in
journal, July 1996
- Millis, A. J.; Shraiman, Boris I.; Mueller, R.
- Physical Review Letters, Vol. 77, Issue 1
Unit-cell determination of epitaxial thin films based on reciprocal-space vectors by high-resolution X-ray diffractometry
journal, January 2014
- Yang, Ping; Liu, Huajun; Chen, Zuhuang
- Journal of Applied Crystallography, Vol. 47, Issue 1
Strain modulated anisotropic electronic charge transfer in perovskite thin films
journal, May 2014
- Zhang, Bangmin; Sun, Cheng-Jun; Yang, Ping
- Physical Review B, Vol. 89, Issue 19
The PNC/XOR X-ray microprobe station at APS sector 20
journal, November 2007
- Heald, S. M.; Cross, J. O.; Brewe, D. L.
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 582, Issue 1
Self-doping processes between planes and chains in the metal-to-superconductor transition of YBa2Cu3O6.9
text, January 2014
- Magnuson, Martin; Strocov, Thorsten Schmitt Vladimir N.; Schlappa, Justina
- arXiv
Unusual ferromagnetism enhancement in ferromagnetically optimal manganite La0.7−yCa0.3+yMn1−yRuyO3 (0≤y<0.3): the role of Mn-Ru t2g super-exchange
journal, April 2015
- Liu, M. F.; Du, Z. Z.; Xie, Y. L.
- Scientific Reports, Vol. 5, Issue 1
Low-temperature resistivity minima in colossal magnetoresistive La 0.7 Ca 0.3 MnO 3 thin films
journal, February 2002
- Kumar, D.; Sankar, J.; Narayan, J.
- Physical Review B, Vol. 65, Issue 9
Double Exchange Alone Does Not Explain the Resistivity of
journal, June 1995
- Millis, A. J.; Littlewood, P. B.; Shraiman, B. I.
- Physical Review Letters, Vol. 74, Issue 25
Magnetoelectric transport and quantum interference effect in ultrathin manganite films
journal, April 2014
- Wang, Cong; Jin, Kui-juan; Gu, Lin
- Applied Physics Letters, Vol. 104, Issue 16
Quantifying strain dependence in “colossal” magnetoresistance manganites
journal, February 1998
- Millis, A. J.; Darling, T.; Migliori, A.
- Journal of Applied Physics, Vol. 83, Issue 3
Anisotropy of the core-hole relaxation in x-ray-absorption spectroscopy as probed in square planar cuprates
journal, April 1992
- Tolentino, H.; Medarde, M.; Fontaine, A.
- Physical Review B, Vol. 45, Issue 14
Magnetic phase diagrams of manganites
journal, November 1999
- Martin, C.; Maignan, A.; Hervieu, M.
- Physical Review B, Vol. 60, Issue 17
Colossal magnetoresistant materials: the key role of phase separation
journal, April 2001
- Dagotto, Elbio; Hotta, Takashi; Moreo, Adriana
- Physics Reports, Vol. 344, Issue 1-3
Considerations on Double Exchange
journal, October 1955
- Anderson, P. W.; Hasegawa, H.
- Physical Review, Vol. 100, Issue 2
Surface Magnetic Phase Diagram of Tetragonal Manganites
journal, November 2001
- Fang, Zhong; Terakura, Kiyoyuki
- Journal of the Physical Society of Japan, Vol. 70, Issue 11
Metal-insulator transitions
journal, June 1991
- Paesler, Michael
- Journal of Non-Crystalline Solids, Vol. 130, Issue 1
Coaction of electric field induced strain and polarization effects in structures
journal, May 2009
- Sheng, Z. G.; Gao, J.; Sun, Y. P.
- Physical Review B, Vol. 79, Issue 17
Unusual ferromagnetism enhancement in ferromagnetically optimal manganite La0.7−yCa0.3+yMn1−yRuyO3 (0≤y<0.3): the role of Mn-Ru t2g super-exchange
journal, April 2015
- Liu, M. F.; Du, Z. Z.; Xie, Y. L.
- Scientific Reports, Vol. 5, Issue 1
Effects of electrode material and configuration on the characteristics of planar resistive switching devices
journal, November 2013
- Peng, H. Y.; Pu, L.; Wu, J. C.
- APL Materials, Vol. 1, Issue 5
Metal-insulator transitions
journal, October 1998
- Imada, Masatoshi; Fujimori, Atsushi; Tokura, Yoshinori
- Reviews of Modern Physics, Vol. 70, Issue 4, p. 1039-1263
Effects of electrode material and configuration on the characteristics of planar resistive switching devices
journal, November 2013
- Peng, H. Y.; Pu, L.; Wu, J. C.
- APL Materials, Vol. 1, Issue 5
Orbital-State-Mediated Phase-Control of Manganites
journal, December 1999
- Konishi, Yoshinori; Fang, Zhong; Izumi, Makoto
- Journal of the Physical Society of Japan, Vol. 68, Issue 12
A Minimal tight-binding model for ferromagnetic canted bilayer manganites
journal, December 2014
- Baublitz, M.; Lane, C.; Lin, Hsin
- Scientific Reports, Vol. 4, Issue 1
Partially Oxidized Sub-10 nm MnO Nanocrystals with High Activity for Water Oxidation Catalysis
journal, May 2015
- Jin, Kyoungsuk; Chu, Arim; Park, Jimin
- Scientific Reports, Vol. 5, Issue 1
Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure
journal, September 1998
- Ankudinov, A. L.; Ravel, B.; Rehr, J. J.
- Physical Review B, Vol. 58, Issue 12
Nature of the Well Screened State in Hard X-Ray Mn Core-Level Photoemission Measurements of Films
journal, November 2004
- Horiba, K.; Taguchi, M.; Chainani, A.
- Physical Review Letters, Vol. 93, Issue 23
Strain Effects in Narrow-Bandwidth Manganites: The Case of Epitaxial Thin Films
journal, June 2014
- Moon, Eun Ju; Keavney, David J.; May, Steven J.
- Physical Review Applied, Vol. 1, Issue 5
A Minimal tight-binding model for ferromagnetic canted bilayer manganites
text, January 2014
- Baublitz, M.; Lane, C.; Lin, Hsin
- arXiv
The classification of tilted octahedra in perovskites
journal, November 1972
- Glazer, A. M.
- Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 28, Issue 11
Local structural distortions in manganites probed by comparative x-ray-emission and x-ray-absorption near-edge measurements
journal, June 2001
- Qian, Q.; Tyson, T. A.; Kao, C. -C.
- Physical Review B, Vol. 64, Issue 2
Role of interface structure and chemistry in resistive switching of NiO nanocrystals on SrTiO 3
journal, March 2014
- Cheng, Xuan; Sullaphen, Jivika; Weyland, Matthew
- APL Materials, Vol. 2, Issue 3
Interfacial Strain: The Driving Force for Selective Orbital Occupancy in Manganite Thin Films
journal, December 2007
- Abad, L.; Laukhin, V.; Valencia, S.
- Advanced Functional Materials, Vol. 17, Issue 18
Competition between lattice distortion and charge dynamics for the charge carriers of double-layered manganites
journal, November 1998
- Park, J. -H.; Kimura, T.; Tokura, Y.
- Physical Review B, Vol. 58, Issue 20
Quantifying strain dependence in “colossal” magnetoresistance manganites
journal, February 1998
- Millis, A. J.; Darling, T.; Migliori, A.
- Journal of Applied Physics, Vol. 83, Issue 3
Phase Diagram of Tetragonal Manganites
journal, April 2000
- Fang, Z.; Solovyev, I. V.; Terakura, K.
- Physical Review Letters, Vol. 84, Issue 14
Directional short range order in FeMnPt magnetic thin films
journal, October 2011
- Sun, Cheng-Jun; Xu, Dongbin; Heald, Steve M.
- Physical Review B, Vol. 84, Issue 14
One-center charge transfer transitions in manganites
journal, May 2002
- Moskvin, A. S.
- Physical Review B, Vol. 65, Issue 20
Surface symmetry-breaking and strain effects on orbital occupancy in transition metal perovskite epitaxial films
journal, January 2012
- Pesquera, D.; Herranz, G.; Barla, A.
- Nature Communications, Vol. 3, Issue 1
Role of interface structure and chemistry in resistive switching of NiO nanocrystals on SrTiO 3
journal, March 2014
- Cheng, Xuan; Sullaphen, Jivika; Weyland, Matthew
- APL Materials, Vol. 2, Issue 3
Glass-like recovery of antiferromagnetic spin ordering in a photo-excited manganite Pr0.7Ca0.3MnO3
journal, February 2014
- Zhou, S. Y.; Langner, M. C.; Zhu, Y.
- Scientific Reports, Vol. 4, Issue 1
Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides
text, January 2012
- Qiao, Ruimin; Chin, Timothy; Harris, Stephen J.
- arXiv
Partially Oxidized Sub-10 nm MnO Nanocrystals with High Activity for Water Oxidation Catalysis
journal, May 2015
- Jin, Kyoungsuk; Chu, Arim; Park, Jimin
- Scientific Reports, Vol. 5, Issue 1
Simple ways of determining perovskite structures
journal, November 1975
- Glazer, A. M.
- Acta Crystallographica Section A, Vol. 31, Issue 6
Works referencing / citing this record:
The particle size effect of Yb0.8R0.2MnO3 (R is Sm, Nd, and Eu) on some physical properties
journal, February 2020
- Abdel-Latif, I. A.
- Journal of Nanoparticle Research, Vol. 22, Issue 2
Atomic-scale investigation of MgO growth on fused quartz using angle-dependent NEXAFS measurements
journal, January 2018
- Singh, Jitendra Pal; Kim, So Hee; Won, Sung Ok
- RSC Advances, Vol. 8, Issue 55