N-acyl oxazolidin-2-selones promoted aldol reactions
Conference
·
OSTI ID:975704
- Ruilian
- Louis A.
- Ryszard
Selenocarbonyls that are housed in a chiral environment have been found to play a pivotal role aldol reactions. We have found that, in general,, the aldol reaction affords the non-Evans aldol syn products. However, the use of glycolate donors with glycoaldehydes, under proper conditions, gave rise to predominately the anti aldol.
- Research Organization:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 975704
- Report Number(s):
- LA-UR-01-4752; TRN: US1006759
- Resource Relation:
- Conference: "Submitted to: Fifth International Electron Conference on Synthetic Chemistry"
- Country of Publication:
- United States
- Language:
- English
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