KINETICS OF CATHODIC REDUCTION OF OXYGEN ON NI-CR-MO-W ALLOY
Ni-Cr-Mo-W alloys (C-group alloys) are well known as materials with very high Corrosion resistance in very aggressive environments, an asset that has motivated the selection of Alloy 22 as a waste package material in the Yucca Mountain Project for the long-term geologic disposal of spent nuclear fuel and other high-level radioactive wastes. The aim of this project is to elucidate the corrosion performance of Alloy 22 under aggressive conditions and to provide a conceptual understanding and parameter data base that could act as a basis for modeling the corrosion performance of waste packages under Yucca Mountain conditions. A key issue in any corrosion process is whether or not the kinetics of the cathodic reactions involved can support a damaging rate of anodic metal (alloy) dissolution. Under Yucca Mountain conditions the primary oxidant available to drive corrosion (most likely in the form of crevice, or under-deposit, corrosion) will be oxygen. Here, we present results on the kinetics of oxygen reduction at the Alloy 22/solution interface.
- Research Organization:
- Yucca Mountain Project, Las Vegas, NV (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- NA
- OSTI ID:
- 886552
- Report Number(s):
- NA; MOL.20060505.0142, DC#48604; TRN: US0604009
- Country of Publication:
- United States
- Language:
- English
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