Evolution of the magnetic and structural properties of Fe1-xCoxV2O4

Sinclair, R.; Ma, Jie; Cao, H. B.; Hong, Tao; Matsuda, Masaaki; Dun, Z. L.; Zhou, H. D.

doi:10.1103/PhysRevB.92.134410

Title: Evolution of the magnetic and structural properties of ${Fe}_{1 - x} {Co}_{x} V_{2} O_{4}$

Journal Article · Mon Oct 12 00:00:00 EDT 2015 · Physical Review. B, Condensed Matter and Materials Physics

DOI:https://doi.org/10.1103/PhysRevB.92.134410· OSTI ID:1344988

Sinclair, R. ^[1]; Ma, Jie ^[1]; Cao, H. B. ^[2]; Hong, Tao ^[2]; Matsuda, Masaaki ^[2]; Dun, Z. L. ^[1]; Zhou, H. D. ^[1]

Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

The magnetic and structural properties of single-crystal Fe_1-xCo_xV₂O₄ samples have been investigated by performing specific heat, susceptibility, neutron diffraction, and x-ray diffraction measurements. As the orbital-active Fe²⁺ ions with larger ionic size are gradually substituted by the orbital-inactive Co²⁺ ions with smaller ionic size, the system approaches the itinerant electron limit with decreasing V-V distance. Then, various factors such as the Jahn-Teller distortion and the spin-orbital coupling of the Fe²⁺ ions on the A sites and the orbital ordering and electronic itinerancy of the V³⁺ ions on the B sites compete with each other to produce a complex magnetic and structural phase diagram. Finally, this phase diagram is compared to those of Fe_1-xMn_xV₂O₄ and Mn_1-xCo_xV₂O₄ to emphasize several distinct features.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1344988

Alternate ID(s):: OSTI ID: 1224641

Journal Information:: Physical Review. B, Condensed Matter and Materials Physics, Vol. 92, Issue 13; ISSN 1098-0121

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 8 works

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Title: Evolution of the magnetic and structural properties of ${Fe}_{1 - x} {Co}_{x} V_{2} O_{4}$