Role of precursor chemistry in the direct fluorination to form titanium based conversion anodes for lithium ion batteries

Adcock, Jamie; Dai, Sheng; Veith, Gabriel M.; Bridges, Craig A.; Powell, Jonathan M.

doi:10.1039/C5RA17258F

Title: Role of precursor chemistry in the direct fluorination to form titanium based conversion anodes for lithium ion batteries

Journal Article · Tue Oct 13 00:00:00 EDT 2015 · RSC Advances

DOI:https://doi.org/10.1039/C5RA17258F· OSTI ID:1244191

Adcock, Jamie ^[1]; Dai, Sheng ^[2]; Veith, Gabriel M. ^[3]; Bridges, Craig A. ^[3]; Powell, Jonathan M. ^[1]

Univ. of Tennessee, Knoxville, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

In this study, a new synthetic route for the formation of titanium oxydifluoride (TiOF₂) through the process of direct fluorination via a fluidized bed reactor system and the associated electrochemical properties of the powders formed from this approach are reported. The flexibility of this synthetic route was demonstrated using precursor powders of titanium dioxide (TiO₂) nanoparticles, as well as a reduced TiO_xN_y. An advantage of this synthetic method is the ability to directly control the extent of fluorination as a function of reaction temperature and time. The reversible capacity of TiOF₂ anodes was found to depend greatly upon the precursor employed. The TiOF₂ synthesized from TiO₂ and TiO_xN_y showed reversible capacities of 300 mAh g^-1 and 440 mAh g^-1, respectively, over 100 cycles. The higher reversible capacity of the TiOF₂ powders derived from TiO_xN_y likely relate to the partial reduction of the Ti in the fluorinated electrode material, highlighting a route to optimize the properties of conversion electrode materials.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1244191

Journal Information:: RSC Advances, Vol. 5, Issue 108; ISSN 2046-2069

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 11 works

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36 MATERIALS SCIENCE
25 ENERGY STORAGE
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Title: Role of precursor chemistry in the direct fluorination to form titanium based conversion anodes for lithium ion batteries

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