Control of cerium oxidation state through metal complex secondary structures

Levin, Jessica R.; Dorfner, Walter L.; Carroll, Patrick J.; Schelter, Eric J.

doi:10.1039/C5SC02607E

Title: Control of cerium oxidation state through metal complex secondary structures

Journal Article · Tue Aug 11 00:00:00 EDT 2015 · Chemical Science

DOI:https://doi.org/10.1039/C5SC02607E· OSTI ID:1221895

Levin, Jessica R. ^[1]; Dorfner, Walter L. ^[1]; Carroll, Patrick J. ^[1]; Schelter, Eric J. ^[1]

Univ. of Pennsylvania, Philadelphia, PA (United States)

A series of alkali metal cerium diphenylhydrazido complexes, M_x(py)_y[Ce(PhNNPh)₄], M = Li, Na, and K, x = 4 (Li and Na) or 5 (K), and y = 4 (Li), 8 (Na), or 7 (K), were synthesized to probe how a secondary coordination sphere would modulate electronic structures at a cerium cation. The resulting electronic structures of the heterobimetallic cerium diphenylhydrazido complexes were found to be strongly dependent on the identity of the alkali metal cations. When M = Li⁺or Na⁺, the cerium(III) starting material was oxidized with concomitant reduction of 1,2-diphenylhydrazine to aniline. Reduction of 1,2-diphenylhydrazine was not observed when M = K⁺, and the complex remained in the cerium(III) oxidation state. Oxidation of the cerium(III) diphenylhydrazido complex to the Ce(_IV) diphenylhydrazido one was achieved through a simple cation exchange reaction of the alkali metals. As a result, UV-Vis spectroscopy, FTIR spectroscopy, electrochemistry, magnetic susceptibility, and DFT studies were used to probe the oxidation state and the electronic changes that occurred at the metal centre.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Univ. of Pennsylvania, Philadelphia, PA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Contributing Organization:: National Science Foundation (NSF), Washington, DC (United States)

Grant/Contract Number:: SC0006518

OSTI ID:: 1221895

Journal Information:: Chemical Science, Journal Name: Chemical Science; ISSN 2041-6520

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 26 works

Citation information provided by
Web of Science

References (100)

New Scale Factors for Harmonic Vibrational Frequencies Using the B3LYP Density Functional Method with the Triple-ζ Basis Set 6-311+G(d,p) Andersson, M. P.; Uvdal, P. The Journal of Physical Chemistry A, Vol. 109, Issue 12 https://doi.org/10.1021/jp045733a	journal	March 2005
Specific binding of cerium by human lactoferrin stimulates the oxidation of Ce3+ to Ce4+ Smith, Clyde A.; Ainscough, Eric W.; Baker, Heather M. Journal of the American Chemical Society, Vol. 116, Issue 17 https://doi.org/10.1021/ja00096a053	journal	August 1994
Synthesis and Properties of High-Valent Organouranium Complexes Containing Terminal Organoimido and Oxo Functional Groups. A New Class of Organo-f-Element Complexes Arney, David S. J.; Burns, Carol J. Journal of the American Chemical Society, Vol. 117, Issue 37 https://doi.org/10.1021/ja00142a011	journal	September 1995
Quantitative Evaluation of Lewis Acidity of Metal Ions with Different Ligands and Counterions in Relation to the Promoting Effects of Lewis Acids on Electron Transfer Reduction of Oxygen Ohkubo, Kei; Menon, Saija C.; Orita, Akihiro The Journal of Organic Chemistry, Vol. 68, Issue 12 https://doi.org/10.1021/jo034258u	journal	June 2003
Knowledge and Know‐How in Emission Control for Mobile Applications Burch, R. Catalysis Reviews, Vol. 46, Issue 3-4 https://doi.org/10.1081/CR-200036718	journal	December 2004
Reactivity of hydrazines with organometallic samarium complexes and the x-ray crystal structures of (C5Me5)2Sm(.eta.2-PhNHNPh)(THF), (C5Me5)2Sm(NHPh)(THF), and [(C5Me5)2Sm]2(.mu.-.eta.2:.eta.2-HNNH) Evans, William J.; Kociok-Koehn, Gabriele; Leong, Voon S. Inorganic Chemistry, Vol. 31, Issue 17 https://doi.org/10.1021/ic00043a020	journal	August 1992
Synthetic, structural, and reactivity studies of the reduction and carbon monoxide derivatization of azobenzene mediated by divalent lanthanide complexes Evans, William J.; Drummond, Donald K.; Chamberlain, L. R. Journal of the American Chemical Society, Vol. 110, Issue 15 https://doi.org/10.1021/ja00223a016	journal	July 1988
Ceric Ion Oxidation in Organic Chemistry Ho, Tse-Lok Synthesis, Vol. 1973, Issue 06 https://doi.org/10.1055/s-1973-22210	journal	January 1973
A direct-methane fuel cell with a ceria-based anode Murray, E. Perry; Tsai, T.; Barnett, S. A. Nature, Vol. 400, Issue 6745 https://doi.org/10.1038/23220	journal	August 1999
A Ligand Field Series for the 4f-Block from Experimental and DFT Computed Ce(IV/III) Electrochemical Potentials Bogart, Justin A.; Lewis, Andrew J.; Boreen, Michael A. Inorganic Chemistry, Vol. 54, Issue 6 https://doi.org/10.1021/ic503000z	journal	February 2015
Matrix Infrared Spectroscopic and Computational Investigations of the Lanthanide−Methylene Complexes CH ₂ LnF ₂ with Single Ln−C Bonds Wang, Xuefeng; Cho, Han-Gook; Andrews, Lester The Journal of Physical Chemistry A, Vol. 115, Issue 10 https://doi.org/10.1021/jp111592e	journal	March 2011
Lanthanide and Actinide Chemistry Cotton, Simon Wiley https://doi.org/10.1002/0470010088	book	January 2006
Unified View of Oxidative C–H Bond Cleavage and Sulfoxidation by a Nonheme Iron(IV)–Oxo Complex via Lewis Acid-Promoted Electron Transfer Park, Jiyun; Morimoto, Yuma; Lee, Yong-Min Inorganic Chemistry, Vol. 53, Issue 7 https://doi.org/10.1021/ic403124u	journal	March 2014
Development of heterogeneous base catalysts for biodiesel production Kawashima, Ayato; Matsubara, Koh; Honda, Katsuhisa Bioresource Technology, Vol. 99, Issue 9, p. 3439-3443 https://doi.org/10.1016/j.biortech.2007.08.009	journal	June 2008
Studies of the water-gas-shift reaction on ceria-supported Pt, Pd, and Rh: Implications for oxygen-storage properties Bunluesin, T.; Gorte, R. J.; Graham, G. W. Applied Catalysis B: Environmental, Vol. 15, Issue 1-2 https://doi.org/10.1016/S0926-3373(97)00040-4	journal	January 1998
Iron-Mediated Hydrazine Reduction and the Formation of Iron-Arylimide Heterocubanes Zdilla, Michael J.; Verma, Atul K.; Lee, Sonny C. Inorganic Chemistry, Vol. 50, Issue 4 https://doi.org/10.1021/ic1021627	journal	February 2011
Metal Ion-Catalyzed Cycloaddition vs Hydride Transfer Reactions of NADH Analogues with p -Benzoquinones Fukuzumi, Shunichi; Fujii, Yoshinori; Suenobu, Tomoyoshi Journal of the American Chemical Society, Vol. 123, Issue 42 https://doi.org/10.1021/ja016370k	journal	October 2001
Diamagnetic Corrections and Pascal's Constants Bain, Gordon A.; Berry, John F. Journal of Chemical Education, Vol. 85, Issue 4 https://doi.org/10.1021/ed085p532	journal	April 2008
Cerium(IV) Trifluoromethanesulfonate as a Strong Oxidizing Agent Imamoto, Tsuneo; Koide, Yasuhiro; Hiyama, Susumu Chemistry Letters, Vol. 19, Issue 8 https://doi.org/10.1246/cl.1990.1445	journal	August 1990
Activity of CeOx and TiOx Nanoparticles Grown on Au(111) in the Water-Gas Shift Reaction Rodriguez, J. A.; Ma, S.; Liu, P. Science, Vol. 318, Issue 5857 https://doi.org/10.1126/science.1150038	journal	December 2007
Synthesis and Reactivity of a Ruthenium(III) Bis(anilide) Dimer by Oxidative Addition of an N,N‘-Disubstituted Hydrazine Hoover, Jessica M.; DiPasquale, Antonio; Mayer, James M. Organometallics, Vol. 26, Issue 14 https://doi.org/10.1021/om0700462	journal	July 2007
Molecular Structure and Magnetic Properties of Acetato-Bridged Lanthanide(III) Dimers Panagiotopoulos, Athanassios; Zafiropoulos, Theodoros F.; Perlepes, Spyros P. Inorganic Chemistry, Vol. 34, Issue 19 https://doi.org/10.1021/ic00123a029	journal	September 1995
Catalytic Cracking Reaction of Heavy Oil in the Presence of Cerium Oxide Nanoparticles in Supercritical Water Dejhosseini, Mehdi; Aida, Tsutomu; Watanabe, Masaru Energy & Fuels, Vol. 27, Issue 8 https://doi.org/10.1021/ef400855k	journal	July 2013
Reduction of Hydrazines, Azo and Azoxy Compounds, and Amine N-Oxides with the NiCl2·2H2O–Li–DTBB (cat.) Combination Alonso, Francisco; Radivoy, Gabriel; Yus, Miguel Tetrahedron, Vol. 56, Issue 44 https://doi.org/10.1016/S0040-4020(00)00797-3	journal	October 2000
Utilizing the Evans method with a superconducting NMR spectrometer in the undergraduate laboratory Schubert, Ernest M. Journal of Chemical Education, Vol. 69, Issue 1 https://doi.org/10.1021/ed069p62.1	journal	January 1992
Synthesis, structure, and reactivity of homoleptic cerium(IV) and cerium(III) alkoxides Sen, Ayusman; Stecher, Hilmar A.; Rheingold, Arnold L. Inorganic Chemistry, Vol. 31, Issue 3 https://doi.org/10.1021/ic00029a025	journal	February 1992
Crystal lattice energy and the Madelung constant Quane, Denis Journal of Chemical Education, Vol. 47, Issue 5 https://doi.org/10.1021/ed047p396	journal	May 1970
A series of three-dimensional architectures constructed from lanthanide-substituted polyoxometalosilicates and lanthanide cations or lanthanide–organic complexes as linkers An, Haiyan; Zhang, Hua; Chen, Zhaofei Dalton Transactions, Vol. 41, Issue 27 https://doi.org/10.1039/c2dt30251a	journal	January 2012
Absorption Anomalies in Ratio and Subtraction FT-IR Spectroscopy Weis, David D.; Ewing, George E. Analytical Chemistry, Vol. 70, Issue 15 https://doi.org/10.1021/ac971174a	journal	August 1998
Oxidatively pure chiral (salen)Co(III)-X complexes in situ prepared by Lewis acid-promoted electron transfer from chiral (salen)Co(II) to oxygen: Their application in the hydrolytic kinetic resolution of terminal epoxides Kim, Dong Hyun; Shin, Ueon Sang; Song, Choong Eui Journal of Molecular Catalysis A: Chemical, Vol. 271, Issue 1-2 https://doi.org/10.1016/j.molcata.2007.02.033	journal	June 2007
Variation of electronic transitions and reduction potentials of cerium( iv ) complexes Williams, Ursula J.; Schneider, David; Dorfner, Walter L. Dalton Trans., Vol. 43, Issue 43 https://doi.org/10.1039/C4DT01386G	journal	January 2014
New perspective of electron transfer chemistry Fukuzumi, Shunichi Organic & Biomolecular Chemistry, Vol. 1, Issue 4 https://doi.org/10.1039/b300053b	journal	January 2003
400. The determination of the paramagnetic susceptibility of substances in solution by nuclear magnetic resonance Evans, D. F. Journal of the Chemical Society (Resumed) https://doi.org/10.1039/jr9590002003	journal	January 1959
Combined Triple and Double Bonds to Uranium: The N≡U═N−H Uranimine Nitride Molecule Prepared in Solid Argon Wang, Xuefeng; Andrews, Lester; Vlaisavljevich, Bess Inorganic Chemistry, Vol. 50, Issue 8 https://doi.org/10.1021/ic2003244	journal	April 2011
Application of lanthanide reagents in organic synthesis Molander, Gary A. Chemical Reviews, Vol. 92, Issue 1 https://doi.org/10.1021/cr00009a002	journal	January 1992
New Paradigm of Electron Transfer Chemistry in Organic Reactions Fukuzumi, Shunichi Journal of Synthetic Organic Chemistry, Japan, Vol. 61, Issue 11 https://doi.org/10.5059/yukigoseikyokaishi.61.1046	journal	January 2003
A homoleptic tetravalent cerium silylamide Crozier, Alan R.; Bienfait, Andre M.; Maichle-Mössmer, Cäcilia Chem. Commun., Vol. 49, Issue 1 https://doi.org/10.1039/C2CC37404H	journal	January 2013
Dearomatization Reactions of N-Heterocycles Mediated by Group 3 Complexes Miller, Kevin L.; Williams, Bryan N.; Benitez, Diego Journal of the American Chemical Society, Vol. 132, Issue 1 https://doi.org/10.1021/ja908489p	journal	January 2010
Renewable Hydrogen from Ethanol by Autothermal Reforming Deluga, G. A. Science, Vol. 303, Issue 5660 https://doi.org/10.1126/science.1093045	journal	February 2004
Cerium(IV) Ammonium Nitrate as a Catalyst in Organic Synthesis Sridharan, Vellaisamy; Menéndez, J. Carlos Chemical Reviews, Vol. 110, Issue 6 https://doi.org/10.1021/cr100004p	journal	June 2010
The Impact of Ligand Reorganization on Cerium(III) Oxidation Chemistry Robinson, Jerome R.; Carroll, Patrick J.; Walsh, Patrick J. Angewandte Chemie International Edition, Vol. 51, Issue 40 https://doi.org/10.1002/anie.201203481	journal	August 2012
The electrochemical behavior of cerium(III/IV) complexes: Thermodynamics, kinetics and applications in synthesis Piro, Nicholas A.; Robinson, Jerome R.; Walsh, Patrick J. Coordination Chemistry Reviews, Vol. 260 https://doi.org/10.1016/j.ccr.2013.08.034	journal	February 2014
Dimeric Rare-Earth BINOLate Complexes: Activation of 1,4-Benzoquinone through Lewis Acid Promoted Potential Shifts Robinson, Jerome R.; Booth, Corwin H.; Carroll, Patrick J. Chemistry - A European Journal, Vol. 19, Issue 19 https://doi.org/10.1002/chem.201300026	journal	March 2013
Cerium( iii ) dialkyl dithiocarbamates from [Ce{N(SiMe ₃ ) ₂ } ₃ ] and tetraalkylthiuram disulfides, and [Ce(κ ² -S ₂ CNEt ₂ ) ₄ ] from the Ce ^III precursor; Tb ^III and Nd ^III analogues Hitchcock, Peter B.; Hulkes, Alexander G.; Lappert, Michael F. Dalton Trans., Issue 1 https://doi.org/10.1039/B311397C	journal	January 2004
Reactivity of Organometallic Tantalum Complexes Containing a Bis(phenoxy)amide (ONO) ^3– Ligand with Aryl Azides and 1,2-Diphenylhydrazine Zarkesh, Ryan A.; Heyduk, Alan F. Organometallics, Vol. 30, Issue 18 https://doi.org/10.1021/om2004332	journal	September 2011
Homoleptic Cerium(III) and Cerium(IV) Nitroxide Complexes: Significant Stabilization of the 4+ Oxidation State Bogart, Justin A.; Lewis, Andrew J.; Medling, Scott A. Inorganic Chemistry, Vol. 52, Issue 19 https://doi.org/10.1021/ic401974t	journal	September 2013
A short history of SHELX Sheldrick, George M. Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122 https://doi.org/10.1107/S0108767307043930	journal	December 2007
Magnetic Nanoscaled Fe ₃ O ₄ /CeO ₂ Composite as an Efficient Fenton-Like Heterogeneous Catalyst for Degradation of 4-Chlorophenol Xu, Lejin; Wang, Jianlong Environmental Science & Technology, Vol. 46, Issue 18 https://doi.org/10.1021/es300303f	journal	September 2012
Synthesis of Tetranuclear, Four-Coordinate Manganese Clusters with “Pinned Butterfly” Geometry Formed by Metal-Mediated N−N Bond Cleavage in Diphenylhydrazine Hamilton, Clifton R.; Baglia, Regina A.; Gordon, Alexander D. Journal of the American Chemical Society, Vol. 133, Issue 12 https://doi.org/10.1021/ja110536t	journal	March 2011
Recent Advances in Synthetic Transformations Mediated by Cerium(IV) Ammonium Nitrate Nair, Vijay; Balagopal, Lakshmi; Rajan, Roshini Accounts of Chemical Research, Vol. 37, Issue 1 https://doi.org/10.1021/ar030002z	journal	January 2004
Lanthanide(II)−Alkali Sandwich Complexes with Cation−Arene π Interactions: Synthesis, Structure, and Solvent-Mediated Redox Transformations Pan, Cheng-Ling; Chen, Wan; Song, Jiangfeng Organometallics, Vol. 30, Issue 8 https://doi.org/10.1021/om200044j	journal	April 2011
Quantitative Evaluation of Lewis Acidity of Organotin Compounds and the Catalytic Reactivity in Electron Transfer Ohkubo, Kei; Suenobu, Tomoyoshi; Imahori, Hiroshi Chemistry Letters, Vol. 30, Issue 10 https://doi.org/10.1246/cl.2001.978	journal	October 2001
Infrared Spectra of the η ² -M(NC)-CH ₃ , CH ₃ -MNC, and CH ₂ ═M(H)NC Complexes Prepared by Reactions of Thorium and Uranium Atoms with Acetonitrile Cho, Han-Gook; Andrews, Lester Organometallics, Vol. 31, Issue 2 https://doi.org/10.1021/om200957j	journal	December 2011
Reductive N−N Bond Cleavage of Diphenylhydrazine and Azobenzene Induced by Coordinatively Unsaturated Cp*Fe{N(SiMe ₃ ) ₂ } Ohki, Yasuhiro; Takikawa, Yuko; Hatanaka, Tsubasa Organometallics, Vol. 25, Issue 13 https://doi.org/10.1021/om0602963	journal	June 2006
Stereochemistry of Discrete Eight-Coördination. I. Basic Analysis Hoard, J. L.; Silverton, J. V. Inorganic Chemistry, Vol. 2, Issue 2 https://doi.org/10.1021/ic50006a001	journal	April 1963
Factors Governing Oxygen Reduction in Solid Oxide Fuel Cell Cathodes ^† Adler, Stuart B. Chemical Reviews, Vol. 104, Issue 10 https://doi.org/10.1021/cr020724o	journal	October 2004
Idealized polytopal forms. Description of real molecules referenced to idealized polygons or polyhedra in geometric reaction path form Muetterties, E. L.; Guggenberger, L. J. Journal of the American Chemical Society, Vol. 96, Issue 6 https://doi.org/10.1021/ja00813a017	journal	March 1974
Catalytic oxidation of water by an oxo-bridged ruthenium dimer Gersten, Susan W.; Samuels, George J.; Meyer, Thomas J. Journal of the American Chemical Society, Vol. 104, Issue 14 https://doi.org/10.1021/ja00378a053	journal	July 1982
Low-temperature water-gas shift reaction over Cu- and Ni-loaded cerium oxide catalysts Li, Yue; Fu, Qi; Flytzani-Stephanopoulos, Maria Applied Catalysis B: Environmental, Vol. 27, Issue 3 https://doi.org/10.1016/S0926-3373(00)00147-8	journal	August 2000
Cerium (iv) ammonium nitrate (CAN) as a catalyst in tap water: A simple, proficient and green approach for the synthesis of quinoxalines More, Shivaji V.; Sastry, M. N. V.; Yao, Ching-Fa Green Chem., Vol. 8, Issue 1 https://doi.org/10.1039/B510677J	journal	January 2006
Uncertainties in Scaling Factors for ab Initio Vibrational Frequencies Irikura, Karl K.; Johnson, Russell D.; Kacker, Raghu N. The Journal of Physical Chemistry A, Vol. 109, Issue 37 https://doi.org/10.1021/jp052793n	journal	September 2005
Tuning Reactivity and Electronic Properties through Ligand Reorganization within a Cerium Heterobimetallic Framework Robinson, Jerome R.; Gordon, Zachary; Booth, Corwin H. Journal of the American Chemical Society, Vol. 135, Issue 50 https://doi.org/10.1021/ja410688w	journal	December 2013
Electronic structure and solution behavior of a tris(N,N′-diphenylhydrazido)manganese(iv) propeller complex Kondaveeti, Sandeep K.; Vaddypally, Shivaiah; McCall, Jeffrey D. Dalton Transactions, Vol. 41, Issue 26 https://doi.org/10.1039/c2dt30493g	journal	January 2012
Reactivity of a Sterically Hindered Fe(II) Thiolate Dimer with Amines and Hydrazines Zdilla, Michael J.; Verma, Atul K.; Lee, Sonny C. Inorganic Chemistry, Vol. 47, Issue 23 https://doi.org/10.1021/ic801349y	journal	December 2008
The lattice energies of the alkali halides Morris, D. F. C. Acta Crystallographica, Vol. 9, Issue 2 https://doi.org/10.1107/S0365110X56000498	journal	February 1956
Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts Fu, Q. Science, Vol. 301, Issue 5635 https://doi.org/10.1126/science.1085721	journal	August 2003
Structural variation in copper( i ) complexes with pyridylmethylamide ligands: structural analysis with a new four-coordinate geometry index, τ ₄ Yang, Lei; Powell, Douglas R.; Houser, Robert P. Dalton Trans., Issue 9 https://doi.org/10.1039/B617136B	journal	January 2007
Kinetic and mechanistic aspects of metal ion catalysis in cerium(IV) oxidation Das, Asim K. Coordination Chemistry Reviews, Vol. 213, Issue 1 https://doi.org/10.1016/S0010-8545(00)00376-3	journal	March 2001
Oxidation of substituted hydrazines by superoxide ion: the initiation step for the autoxidation of 1,2-diphenylhydrazine Calderwood, Thomas S.; Johlman, Carolyn L.; Roberts, Julian L. Journal of the American Chemical Society, Vol. 106, Issue 17 https://doi.org/10.1021/ja00329a007	journal	August 1984
Reduction of Azobenzene by Naphthaleneytterbium: A Tetranuclear Ytterbium(III) Complex Combining 1,2-Diphenylhydrazido(2−) and Phenylimido Ligands Trifonov, Alexander A.; Bochkarev, Mikhail N.; Schumann, Herbert Angewandte Chemie International Edition in English, Vol. 30, Issue 9 https://doi.org/10.1002/anie.199111491	journal	September 1991
Structural Chemistry of Alkali Metal Phenylhyrazides Gemünd, Birgit; Nöth, Heinrich; Sachdev, Hermann Chemische Berichte, Vol. 129, Issue 11 https://doi.org/10.1002/cber.19961291105	journal	November 1996
Direct oxidation of hydrocarbons in a solid-oxide fuel cell Park, Seungdoo; Vohs, John M.; Gorte, Raymond J. Nature, Vol. 404, Issue 6775 https://doi.org/10.1038/35005040	journal	March 2000
Molecular polyhedra of high co-ordination number Muetterties, E. L.; Wright, C. M. Quarterly Reviews, Chemical Society, Vol. 21, Issue 1 https://doi.org/10.1039/qr9672100109	journal	January 1967
Magnetism of Lanthanides in Molecular Materials with Transition-Metal Ions and Organic Radicals Benelli, Cristiano; Gatteschi, Dante Chemical Reviews, Vol. 102, Issue 6 https://doi.org/10.1021/cr010303r	journal	June 2002
Synthetic Water-Oxidation Catalysts for Artificial Photosynthetic Water Oxidation ^† Rüttinger, Wolfgang; Dismukes, G. Charles Chemical Reviews, Vol. 97, Issue 1 https://doi.org/10.1021/cr950201z	journal	February 1997
An isolable, metastable, geometrically unique manganese(iv) trihydrazide complex poised for reactivity Vaddypally, Shivaiah; Kondaveeti, Sandeep K.; Zdilla, Michael J. Chemical Communications, Vol. 47, Issue 34 https://doi.org/10.1039/c1cc13427b	journal	January 2011
Change in Spin State and Enhancement of Redox Reactivity of Photoexcited States of Aromatic Carbonyl Compounds by Complexation with Metal Ion Salts Acting as Lewis Acids. Lewis Acid-Catalyzed Photoaddition of Benzyltrimethylsilane and Tetramethyltin via Photoinduced Electron Transfer Fukuzumi, Shunichi; Satoh, Naoya; Okamoto, Toshihiko Journal of the American Chemical Society, Vol. 123, Issue 32 https://doi.org/10.1021/ja010125j	journal	August 2001
Enantioselective Organocatalysis Using SOMO Activation Beeson, T. D.; Mastracchio, A.; Hong, J. -B. Science, Vol. 316, Issue 5824 https://doi.org/10.1126/science. 1142696	journal	April 2007
Designing Catalysts for Nitrene Transfer Using Early Transition Metals and Redox-Active Ligands Heyduk, Alan F.; Zarkesh, Ryan A.; Nguyen, Andy I. Inorganic Chemistry, Vol. 50, Issue 20 https://doi.org/10.1021/ic200911b	journal	October 2011
Segmented contraction scheme for small-core lanthanide pseudopotential basis sets Cao, Xiaoyan; Dolg, Michael Journal of Molecular Structure: THEOCHEM, Vol. 581, Issue 1-3 https://doi.org/10.1016/S0166-1280(01)00751-5	journal	April 2002
Low co-ordination numbers in lanthanide and actinide compounds. Part I. The preparation and characterization of tris{bis(trimethylsilyl)-amido}lanthanides Bradley, Donald C.; Ghotra, Joginder S.; Hart, F. Alan Journal of the Chemical Society, Dalton Transactions, Issue 10 https://doi.org/10.1039/dt9730001021	journal	January 1973
Advanced exhaust gas aftertreatment systems for gasoline and diesel fuelled vehicles Kreuzer, T.; Lox, E. S.; Lindner, D. Catalysis Today, Vol. 29, Issue 1-4 https://doi.org/10.1016/0920-5861(95)00254-5	journal	May 1996
Electrical properties of ceria-based oxides and their application to solid oxide fuel cells Eguchi, K.; Setoguchi, T.; Inoue, T. Solid State Ionics, Vol. 52, Issue 1-3 https://doi.org/10.1016/0167-2738(92)90102-U	journal	May 1992
Chemical Redox Agents for Organometallic Chemistry Connelly, Neil G.; Geiger, William E. Chemical Reviews, Vol. 96, Issue 2 https://doi.org/10.1021/cr940053x	journal	January 1996
Cerium(IV) Ammonium NitrateA Versatile Single-Electron Oxidant Nair, Vijay; Deepthi, Ani Chemical Reviews, Vol. 107, Issue 5 https://doi.org/10.1021/cr068408n	journal	May 2007
Nanostructured materials for advanced automotive de-pollution catalysts Kašpar, Jan; Fornasiero, Paolo Journal of Solid State Chemistry, Vol. 171, Issue 1-2 https://doi.org/10.1016/S0022-4596(02)00141-X	journal	February 2003
Ceria-Based Solid Catalysts for Organic Chemistry Vivier, Laurence; Duprez, Daniel ChemSusChem, Vol. 3, Issue 6 https://doi.org/10.1002/cssc.201000054	journal	May 2010
Synthesis and magnetic properties of cerium macrocyclic complexes with tetramethyldibenzotetraaza[14]annulene, tmtaaH2 Walter, Marc D.; Fandos, Rosa; Andersen, Richard A. New Journal of Chemistry, Vol. 30, Issue 7 https://doi.org/10.1039/b602644c	journal	January 2006
Physical, chemical and electrochemical properties of pure and doped ceria Mogensen, M. Solid State Ionics, Vol. 129, Issue 1-4 https://doi.org/10.1016/S0167-2738(99)00318-5	journal	April 2000
Nitrogen−Nitrogen Bond Cleavage of Hydrazine Derivatives by a Trinuclear Pentahydride Complex of Ruthenium, (Cp‘Ru)₃(μ-H)₃(μ₃-H)₂ (Cp‘ = η⁵-C₅Me₅) Nakajima, Yumiko; Suzuki, Hiroharu Organometallics, Vol. 22, Issue 5 https://doi.org/10.1021/om020755+	journal	January 2003
Energy‐adjusted a b i n i t i o pseudopotentials for the rare earth elements Dolg, M.; Stoll, H.; Preuss, H. The Journal of Chemical Physics, Vol. 90, Issue 3 https://doi.org/10.1063/1.456066	journal	February 1989
Automotive catalytic converters: current status and some perspectives Kašpar, Jan; Fornasiero, Paolo; Hickey, Neal Catalysis Today, Vol. 77, Issue 4 https://doi.org/10.1016/S0920-5861(02)00384-X	journal	January 2003
Cerium(III/IV) Formamidinate Chemistry, and a Stable Cerium(IV) Diolate Werner, Daniel; Deacon, Glen B.; Junk, Peter C. Chemistry - A European Journal, Vol. 20, Issue 15 https://doi.org/10.1002/chem.201304582	journal	March 2014
Formation of the tetranuclear, tetrakis-terminal-imido Mn ₄ ^IV (N ^t Bu) ₈ cubane cluster by four-electron reductive elimination of ^t BuNN ^t Bu. The role of the s-block ion in stabilization of high-oxidation state intermediates Vaddypally, Shivaiah; Kondaveeti, Sandeep K.; Roudebush, John H. Chem. Commun., Vol. 50, Issue 9 https://doi.org/10.1039/C3CC42165A	journal	January 2014
New Perspective of Electron Transfer Chemistry Fukuzumi, Shunichi ChemInform, Vol. 34, Issue 24 https://doi.org/10.1002/chin.200324231	journal	June 2003
Recent Advances in Synthetic Transformations Mediated by Cerium(IV) Ammonium Nitrate Nair, Vijay; Balagopal, Lakshmi; Rajan, Roshini ChemInform, Vol. 35, Issue 16 https://doi.org/10.1002/chin.200416263	journal	April 2004
Cerium(IV) Ammonium Nitrate (CAN) as a Catalyst in Tap Water: A Simple, Proficient and Green Approach for the Synthesis of Quinoxalines. More, Shivaji V.; Sastry, M. N. V.; Yao, Ching-Fa ChemInform, Vol. 37, Issue 23 https://doi.org/10.1002/chin.200623166	journal	June 2006
The Impact of Ligand Reorganization on Cerium(III) Oxidation Chemistry Robinson, Jerome R.; Carroll, Patrick J.; Walsh, Patrick J. Angewandte Chemie, Vol. 124, Issue 40 https://doi.org/10.1002/ange.201203481	journal	August 2012
New Paradigm of Electron Transfer Chemistry in Organic Reactions Fukuzumi, Shunichi ChemInform, Vol. 35, Issue 14 https://doi.org/10.1002/chin.200414293	journal	April 2004
Cerium(IV) Ammonium Nitrate — A Versatile Single-Electron Oxidant Nair, Vijay; Deepthi, Ani ChemInform, Vol. 38, Issue 33 https://doi.org/10.1002/chin.200733259	journal	August 2007

Cited By (11)

Bright Photoluminescence of [{(CptBu2 ) ₂ Ce( μ -Cl)} ₂ ]: A Valuable Technique for the Determination of the Oxidation State of Cerium Suta, Markus; Harmgarth, Nicole; Kühling, Marcel Chemistry - An Asian Journal, Vol. 13, Issue 8 https://doi.org/10.1002/asia.201701818	journal	March 2018
Structure, Electronics and Reactivity of Ce(PNP) Complexes Zabula, Alexander V.; Qiao, Yusen; Kosanovich, Alex J. Chemistry - A European Journal, Vol. 23, Issue 71 https://doi.org/10.1002/chem.201703174	journal	October 2017
The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes Gregson, Matthew; Lu, Erli; Mills, David P. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14137	journal	February 2017
Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations Estes, Shanna L.; Qiao, Baofu; Jin, Geng Bang Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-018-07982-5	journal	January 2019
Dicerium letterbox-shaped tetraphenolates: f-block complexes designed for two-electron chemistry Arnold, Polly L.; Wang, Kai; Gray, Steven J. Dalton Transactions, Vol. 49, Issue 3 https://doi.org/10.1039/c9dt03291f	journal	January 2020
Stability Constants and Rate Constants of Intramolecular Redox Decomposition of Cerium(IV) Complexes with Certain Hydroxycarboxylic Acids in Nitrate Medium Voskresenskaya, O. O.; Skorik, N. A.; Sokovikova, N. I. Russian Journal of Inorganic Chemistry, Vol. 64, Issue 10 https://doi.org/10.1134/s0036023619100176	journal	October 2019
Reduction of a Cerium(III) Siloxide Complex To Afford a Quadruple-Decker Arene-Bridged Cerium(II) Sandwich Kelly, Rory P.; Maron, Laurent; Scopelliti, Rosario Angewandte Chemie, Vol. 129, Issue 49 https://doi.org/10.1002/ange.201709769	journal	November 2017
Rare‐Earth Metal Diimide Complexes via Alkylaluminate Templating, Including a Ceric Derivative Thim, Renita; Schädle, Dorothea; Maichle‐Mössmer, Cäcilia Chemistry – A European Journal https://doi.org/10.1002/chem.201805143	journal	December 2018
Thermodynamic and kinetic stability of cerium(IV) complexes with a series of aminopolyacetic acids Voskresenskaya, O. O.; Skorik, N. A.; Stepanova, N. V. Russian Journal of Applied Chemistry, Vol. 89, Issue 11 https://doi.org/10.1134/s1070427216110033	journal	November 2016
Redox-enhanced hemilability of a tris( tert -butoxy)siloxy ligand at cerium Friedrich, Jochen; Qiao, Yusen; Maichle-Mössmer, Cäcilia Dalton Transactions, Vol. 47, Issue 30 https://doi.org/10.1039/c8dt01878b	journal	January 2018
Reduction of a Cerium(III) Siloxide Complex To Afford a Quadruple-Decker Arene-Bridged Cerium(II) Sandwich Kelly, Rory P.; Maron, Laurent; Scopelliti, Rosario Angewandte Chemie International Edition, Vol. 56, Issue 49 https://doi.org/10.1002/anie.201709769	journal	November 2017

Linked Research (3)

Figures / Tables (9)

Similar Records

Oxidation of cerium(III) phosphate in steam in the presence of lithium halides and its use in thermochemical water-splitting cycles

Journal Article · Tue Jul 01 00:00:00 EDT 1980 · Inorg. Chem.; (United States) · OSTI ID:1221895

Bamberger, C E; Robinson, P R

Study of Ion Specific Interactions of Alkali Cations with Dicarboxylate Dianions

Journal Article · Fri Feb 10 00:00:00 EST 2012 · Journal of Physical Chemistry A · OSTI ID:1221895

Murdachaew, Garold; Valiev, Marat; Kathmann, Shawn M; +1 more

Intrazeolite half-sandwich complexes of rhodium and iridium: Spectroscopy and reactivity patterns

Journal Article · Thu Sep 07 00:00:00 EDT 1989 · Journal of Physical Chemistry; (USA) · OSTI ID:1221895

Ozin, G A; Haddleton, D M; Gil, C J

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

CCDC 1404762: Experimental Crystal Structure Determination: ZUVWIY : tetra-sodium tetrakis(1,2-diphenylhydrazine-1,2-diyl)-cerium pyridine solvate Levin, Jessica; Dorfner, Walter; Carroll, Patrick https://doi.org/10.5517/cc1j4rxb The current record is supplemented by this dataset	dataset	June 2015
CCDC 1404763: Experimental Crystal Structure Determination: ZUVWOE : Penta-potassium tetrakis(1,2-diphenylhydrazido)-cerium pyridine solvate Space Group: P 1 (2), Cell: a 15.2003(12)Å b 15.4668(12)Å c 18.0353(15)Å, α 93.849(5)° β 101.333(5)° γ 107.292(5)° Levin, Jessica R.; Dorfner, Walter L.; Carroll, Patrick J. https://doi.org/10.5517/cc1j4ryc The current record is supplemented by this dataset	dataset	June 2015
CCDC 1404761: Experimental Crystal Structure Determination: ZUVWEU : tetrakis(μ-1,2-diphenylhydrazine-1,2-diyl)-tetrapyridine-cerium-tetra-lithium Levin, Jessica R.; Dorfner, Walter L.; Carroll, Patrick J. https://doi.org/10.5517/cc1j4rw9 The current record is supplemented by this dataset	dataset	June 2015