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Title: Zeolite-like metal–organic frameworks (ZMOFs): Design, synthesis, and properties

Journal Article · · Chemical Society Reviews
DOI:https://doi.org/10.1039/C4CS00230J· OSTI ID:1214786
 [1];  [2];  [3];  [4];  [4]
  1. King Abdullah Univ. of Science and Technology, Thuwal (Saudi Arabia); Univ. of South Florida, Tampa, FL (United States)
  2. Sandia National Lab. (SNL-CA), Livermore, CA (United States); Univ. of South Florida, Tampa, FL (United States)
  3. Univ. of South Florida, Tampa, FL (United States); Florida Southern College, Lakeland, FL (United States)
  4. King Abdullah Univ. of Science and Technology, Thuwal (Saudi Arabia)
+ Show Author Affiliations

This study highlights various design and synthesis approaches toward the construction of ZMOFs, which are metal–organic frameworks (MOFs) with topologies and, in some cases, features akin to traditional inorganic zeolites. The interest in this unique subset of MOFs is correlated with their exceptional characteristics arising from the periodic pore systems and distinctive cage-like cavities, in conjunction with modular intra- and/or extra-framework components, which ultimately allow for tailoring of the pore size, pore shape, and properties towards specific applications.

Research Organization:
Sandia National Laboratories (SNL), Albuquerque, NM, and Livermore, CA (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC04-94AL85000
OSTI ID:
1214786
Journal Information:
Chemical Society Reviews, Vol. 44, Issue 1; ISSN 0306-0012
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 598 works
Citation information provided by
Web of Science

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Two new three-dimensional metal–organic frameworks with 4-connected diamondoid and unusual (6,16)-connected net topologies based on planar tetranuclear squares as secondary building units journal January 2016
Syntheses, structures, and properties of six cobalt( ii ) complexes based on a tripodal tris(4-(1H-1,2,4-triazol-1-yl)phenyl)amine ligand journal January 2015
Racemic cobalt phosphonates incorporating flexible bis(imidazole) co-ligands journal January 2015
Pore engineering of metal–organic frameworks: introduction of chemically accessible Lewis basic sites inside MOF channels journal January 2016
Synthesis of homochiral zeolitic metal–organic frameworks with amino acid and tetrazolates for chiral recognition journal January 2017
In situ large-scale construction of sulfur-functionalized metal–organic framework and its efficient removal of Hg( ii ) from water journal January 2016
Synthesis of zeolite-like metal–organic frameworks via a dual-ligand strategy journal January 2017
Synthesis of the homochiral metal–organic framework DUT-129 based on a chiral dicarboxylate linker with 6 stereocenters journal January 2017
Four coordination polymers based on dinuclear and trinuclear units with a new multifunctional pyridyl-dicarboxylate ligand: luminescence and magnetic properties journal January 2017
Five new 2D and 3D coordination polymers based on two new multifunctional pyridyl–tricarboxylate ligands: hydrothermal syntheses, structural diversity, luminescent and magnetic properties journal January 2017
A novel approach for the synthesis of phospholipid bilayer-coated zeolitic imidazolate frameworks: preparation and characterization as a pH-responsive drug delivery system journal January 2019
Green and rapid preparation of hierarchically porous metal–organic zeolites and simulation of their growth journal January 2019
Zinc/itaconate coordination polymers as first examples with long-lasting phosphorescence based on acyclic ligands journal January 2018
Multifunctional coordination compounds based on lanthanide ions and 5-bromonicotinic acid: magnetic, luminescence and anti-cancer properties journal January 2019
Facile controlled synthesis of core–shell/yolk–shell/hollow ZIF-67@Co-LDH/SiO 2 via a self-template method journal January 2020
Crystal structure of a chloride-bridged copper(II) dimer: piperazine-1,4-dium bis(di-μ-chlorido-bis[(4-carboxypyridine-2-carboxylato-κ 2 N , O 2 )chloridocuprate(II)] journal January 2017
Crystal structures of dimethyl 5-iodoisophthalate and dimethyl 5-ethynylisophthalate journal July 2018
Functional Composite Adsorbents of High Packing Density Based on Metal-Organic Framework Structures for Methane Accumulation journal September 2019
New Microbe Killers: Self-Assembled Silver(I) Coordination Polymers Driven by a Cagelike Aminophosphine journal October 2019
Supramolecular organization in confined nanospaces text January 2021
Unveiling the Mechanism of Water-Triggered Diplex Transformation and Correlating the Changes in Structures and Separation Properties journal September 2015
Hierarchical Nanostructures: Design for Sustainable Water Splitting journal July 2017
Robust Superhydrophobic/Superoleophilic Wrinkled Microspherical MOF@rGO Composites for Efficient Oil–Water Separation journal April 2019
Transition Metal–organic Coordination Polymers Containing 6‐(1H‐imidazol‐1‐yl)‐2(1H)‐Pyridinone: Synthesis, Structure and Fluorescent Sensing for Enoxacin journal February 2020
A Designed ZnO@ZIF-8 Core-Shell Nanorod Film as a Gas Sensor with Excellent Selectivity for H 2 over CO journal May 2017
Efficient Capture of Organic Dyes and Crystallographic Snapshots by a Highly Crystalline Amino-Acid-Derived Metal-Organic Framework journal November 2018
Switchable Room-Temperature Ferroelectric Behavior, Selective Sorption and Solvent-Exchange Studies of [H 3 O][Co 2 (dat)(sdba) 2 ]⋅H 2 sdba⋅5 H 2 O journal March 2016
Photoluminescence Tuning and Water Detection of Yttrium Diazinedicarboxylate Materials through Lanthanide Doping: Photoluminescence Tuning of Yttrium Materials journal April 2015
Scalable Synthesis and Supramolecular Assembly of trans -A 2 B 2 Porphyrins with Pendant Carboxylic Functional Groups journal January 2017
Heat capacities and thermodynamic properties of a Zn-based zeolitic imidazolate framework journal August 2018
Construction of four 3d–4f heterometallic pillar-layered frameworks containing left- and right-handed helical chains and a I − chemosensor journal January 2015
Structural and luminescence modulation in 8-hydroxyquinolinate-based coordination polymers by varying the dicarboxylic acid journal January 2015
Coordination assemblies of Zn(NO 3 ) 2 with 4-pyr-poly-2-ene and polycarboxylates: structural diversification and photoluminescence properties journal January 2015
An In III -based anionic metal–organic framework: sensitization of lanthanide (III) ions and selective absorption and separation of cationic dyes journal January 2015
A mixed-valent Cu I /Cu II metal–organic framework with selective chemical sensing properties journal January 2016
A multifunctional lanthanide metal–organic framework supported by Keggin type polyoxometalates journal January 2016
Mixed ligand two dimensional Cd( ii )/Ni( ii ) metal organic frameworks containing dicarboxylate and tripodal N-donor ligands: Cd( ii ) MOF is an efficient luminescent sensor for detection of picric acid in aqueous media journal January 2016
Bipyridine-triggered modulation of structure and properties of zinc-diphosphonates: coordination role vs. template rule journal January 2018
Evolution from linear tetranuclear clusters into one-dimensional chains of Dy( iii ) single-molecule magnets with an enhanced energy barrier journal January 2017
Chiral coordination polymers based on d 10 metals and 2-aminonicotinate with blue fluorescent/green phosphorescent anisotropic emissions journal January 2018
Accordion and layer-sliding motion to produce anomalous thermal expansion behaviour in 2D-coordination polymers journal January 2019
Efficient gas and alcohol uptake and separation driven by two types of channels in a porous MOF: an experimental and theoretical investigation journal January 2020
Crystal structures of 2-acetyl-4-ethynylphenol and 2-acetyl-4-(3-hydroxy-3-methylbut-1-yn-1-yl)phenol journal September 2016
Synthesis and characterization of surface-modified mesoporous silica materials with β-cyclodextrin text January 2016
Encapsulation of Isolated Luminophores within Supramolecular Cages journal September 2017
Zeolite‐Type Metal Oxalate Frameworks journal January 2019
Imidazolium Ionic Liquids, Imidazolylidene Heterocyclic Carbenes, and Zeolitic Imidazolate Frameworks for CO 2 Capture and Photochemical Reduction journal December 2015
Integration of Open Metal Sites and Lewis Basic Sites for Construction of a Cu MOF with a Rare Chiral O h -type cage for high performance in methane purification journal February 2018
A Porous Framework as a Variable Chemosensor: From the Response of a Specific Carcinogenic Alkyl-Aromatic to Selective Detection of Explosive Nitroaromatics journal July 2018
Efficient Capture of Organic Dyes and Crystallographic Snapshots by a Highly Crystalline Amino-Acid-Derived Metal-Organic Framework journal September 2018
A New Biscarbazole‐Based Metal–Organic Framework for Efficient Host–Guest Energy Transfer journal January 2019
Methane storage in nanoporous material at supercritical temperature over a wide range of pressures journal September 2016
Four metal–organic frameworks based on the 5-(1H-tetrazol-5-yl)isophthalic acid ligand: luminescence and magnetic properties journal January 2016
Nanostructured metal–organic frameworks, TMU-4, TMU-5, and TMU-6, as novel adsorbents for solid phase microextraction of polycyclic aromatic hydrocarbons journal January 2017
Tetrahedral crosslinking of dia-type nets into a zeolitic GIS-type framework for optimizing stability and gas sorption journal January 2017
Synthesis of homochiral zeolitic imidazolate frameworks via solvent-assisted linker exchange for enantioselective sensing and separation journal January 2018
Design of a Zn-MOF biosensor via a ligand “lock” for the recognition and distinction of S-containing amino acids journal January 2019
Light-controllable systems based on TiO 2 -ZIF-8 composites for targeted drug release: communicating with tumour cells journal January 2019
One Novel 2D Manganese(II) Coordination Polymer From Carboxylphenyl Imidazole Dicarboxylate: Synthesis, Crystal Structure, and Properties journal March 2016
Anion-induced structural varieties of Cu II coordination complexes with 3-phenyl-4-(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazole journal July 2018
A new two-dimensional extended adenine and thiophenecarboxylate mixed-ligand zinc(II) complex: synthesis, structure, thermostability and luminescent properties journal November 2015
Crystal structure of poly[bis(μ-2-amino-4,5-dicyanoimidazolato-κ 2 N 1 : N 3 )- trans -bis( N , N ′-dimethylformamide-κ O )cadmium] journal August 2015
Photoreduction of Carbon Dioxide to Methanol over Copper Based Zeolitic Imidazolate Framework-8: A New Generation Photocatalyst journal November 2018
Hollow Functional Materials Derived from Metal–Organic Frameworks: Synthetic Strategies, Conversion Mechanisms, and Electrochemical Applications journal January 2019
Heterogeneous Molecular Systems for Photocatalytic CO 2 Reduction with Water Oxidation journal October 2016
A New Structural Family of Gas-Sorbing Coordination Polymers Derived from Phenolic Carboxylic Acids journal November 2015
A Lamellar Coordination Polymer with Remarkable Catalytic Activity journal August 2016
Imaging defects and their evolution in a metal–organic framework at sub-unit-cell resolution journal May 2019
Light-triggered Supramolecular Isomerism in a Self-catenated Zn(II)-organic Framework: Dynamic Photo-switching CO2 Uptake and Detection of Nitroaromatics journal October 2016
Synthesis and characterization of surface-modified mesoporous silica materials with ��-cyclodextrin journal January 2016
Synthesis, structure, thermostability and luminescence properties of Zn II and Cd II coordination polymers based on dimethysuccinate and flexible 1,4-bis(imidazol-1-ylmethyl)benzene ligands journal August 2016
Metal-Organic Frameworks Encapsulating Active Nanoparticles as Emerging Composites for Catalysis: Recent Progress and Perspectives journal September 2018
A Novel Zinc Luminescent Coordination Polymer Based on a Tetracarboxylate Acid Ligand for the Detection of Nitrobenzene journal January 2019
Construction and Properties of Two MOFs Based on 2- p -Bromophenyl Imidazole Dicarboxylate : MOFs Based on 2- journal February 2015
Triazine-based 2D covalent organic frameworks improve the electrochemical performance of enzymatic biosensors journal December 2019
Metal–organic framework with optimally selective xenon adsorption and separation journal June 2016
Zn-MOFs containing flexible α,ω-alkane (or alkene)-dicarboxylates with 1,2-bis(4-pyridyl)ethylene: comparison with Zn-MOFs containing 1,2-bis(4-pyridyl)ethane ligands journal January 2017
Metal–organic framework technologies for water remediation: towards a sustainable ecosystem journal January 2018
Adjustment of the performance and stability of isostructural zeolitic tetrazolate-imidazolate frameworks journal January 2020
A lamellar coordination polymer with remarkable catalytic activity text January 2016

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY