Tunable trimers: Using temperature and pressure to control luminescent emission in gold(I) pyrazolate-based trimers

Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M.; Hatcher, Lauren E.; Parlett, Andrew; Shepherd, Helena J.; Christensen, Jeppe; Teat, Simon J.; Intissar, Mourad; Rodrigue-Witchel, Alexandre; Suffren, Yan; Reber, Christian; Hendon, Christopher H.; Tiana, Davide; Walsh, Aron; Raithby, Paul R.

doi:10.1002/chem.201404058

Title: Tunable trimers: Using temperature and pressure to control luminescent emission in gold(I) pyrazolate-based trimers

Journal Article · Tue Oct 21 00:00:00 EDT 2014 · Chemistry - A European Journal

DOI:https://doi.org/10.1002/chem.201404058· OSTI ID:1213528

Woodall, Christopher H. ^[1]; Fuertes, Sara ^[1]; Beavers, Christine M. ^[2]; Hatcher, Lauren E. ^[1]; Parlett, Andrew ^[1]; Shepherd, Helena J. ^[1]; Christensen, Jeppe ^[1]; Teat, Simon J. ^[2]; Intissar, Mourad ^[3]; Rodrigue-Witchel, Alexandre ^[3]; Suffren, Yan ^[3]; Reber, Christian ^[3]; Hendon, Christopher H. ^[1]; Tiana, Davide ^[1]; Walsh, Aron ^[1]; Raithby, Paul R. ^[1]

Univ. of Bath, Bath (United Kingdom). Dept. of Chemistry.
Lawrence Berkeley National Lab., CA (United States). Advanced Light Source.
Universite de Montreal, Montreal, QC (Canada). Departement de Chimie.

A systematic investigation into the relationship between the solid-state luminescence and the intermolecular Au∙∙∙Au interactions in a series of pyrazolate-based gold(I) trimers; tris(μ₂-pyrazolato-N,N')-tri-gold(I) (1), tris(μ₂-3,4,5-trimethylpyrazolato-N,N')-tri-gold(I) (2), tris(μ₂-3-methyl-5-phenylpyrazolato-N,N')-tri-gold(I) (3) and tris(μ₂-3,5-diphenylpyrazolato-N,N')-tri-gold(I) (4) has been carried out using variable temperature and high pressure X-ray crystallography, solid-state emission spectroscopy, Raman spectroscopy and computational techniques. Single-crystal X-ray studies show that there is a significant reduction in the intertrimer Au∙∙∙Au distances both with decreasing temperature and increasing pressure. In the four complexes, the reduction in temperature from 293 to 100 K is accompanied by a reduction in the shortest intermolecular Au∙∙∙Au contacts of between 0.04 and 0.08 Å. The solid-state luminescent emission spectra of 1 and 2 display a red shift with decreasing temperature or increasing pressure. Compound 3 does not emit under ambient conditions but displays increasingly red-shifted luminescence upon cooling or compression. Compound 4 remains emissionless, consistent with the absence of intermolecular Au∙∙∙Au interactions. The largest pressure induced shift in emission is observed in 2 with a red shift of approximately 630 cm^-1 per GPa between ambient and 3.80 GPa. The shifts in all the complexes can be correlated with changes in Au∙∙∙Au distance observed by diffraction.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1213528

Journal Information:: Chemistry - A European Journal, Vol. 20, Issue 51; ISSN 0947-6539

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 21 works

Citation information provided by
Web of Science

References (75)

Extreme Pressure-Induced Shifts of Emission Energies in M[Au(CN)2] and M2[Pt(CN)4].cntdot.nH2O. Compounds with Low-Dimensional and Metal-Metal Interactions Yersin, Hartmut; Riedl, Ulrich Inorganic Chemistry, Vol. 34, Issue 7 https://doi.org/10.1021/ic00111a006	journal	March 1995
Pressure Dependence Investigation of the Low-Temperature Structure of TlAu(CN) ₂ by High-Resolution Neutron Powder Diffraction and Optical Studies Fischer, Peter; Mesot, Joël; Lucas, Brian Inorganic Chemistry, Vol. 36, Issue 13 https://doi.org/10.1021/ic961405g	journal	June 1997
Trinuclear Gold(I) Triazolates: A New Class of Wide-Band Phosphors and Sensors Yang, Chi; Messerschmidt, Marc; Coppens, Philip Inorganic Chemistry, Vol. 45, Issue 17 https://doi.org/10.1021/ic060943i	journal	August 2006
Oxidation of gold(i) pyrazolates by aqua regia. X-Ray crystal structures of the first examples of trinuclear AuIII3 and AuIAuIII2 pyrazolato complexes Yang, Guang; Raptis, Raphael G. Journal of the Chemical Society, Dalton Transactions, Issue 21 https://doi.org/10.1039/b207600d	journal	October 2002
WinGX and ORTEP for Windows : an update Farrugia, Louis J. Journal of Applied Crystallography, Vol. 45, Issue 4 https://doi.org/10.1107/S0021889812029111	journal	July 2012
Comparison of Polymorphic Molecular Crystal Structures through Hirshfeld Surface Analysis McKinnon, Joshua J.; Fabbiani, Francesca P. A.; Spackman, Mark A. Crystal Growth & Design, Vol. 7, Issue 4 https://doi.org/10.1021/cg060773k	journal	April 2007
Ab initio study on luminescent properties of triangular Au(I) complexes Zhang, Mingxin; Mang, Chaoyong; Wu, Kechen Journal of Molecular Structure: THEOCHEM, Vol. 759, Issue 1-3 https://doi.org/10.1016/j.theochem.2005.11.010	journal	February 2006
Dinuclear gold(III) pyrazolato complexes – Synthesis, structural characterization and transformation to their trinuclear gold(I) and gold(I/III) analogues Yang, Guang; Martínez, José R.; Raptis, Raphael G. Inorganica Chimica Acta, Vol. 362, Issue 5 https://doi.org/10.1016/j.ica.2008.07.028	journal	April 2009
PASCal : a principal axis strain calculator for thermal expansion and compressibility determination Cliffe, Matthew J.; Goodwin, Andrew L. Journal of Applied Crystallography, Vol. 45, Issue 6 https://doi.org/10.1107/S0021889812043026	journal	November 2012
Supramolecular Assembly of Trimeric Gold(I) Pyrazolates through Aurophilic Attractions Yang, Guang; Raptis, Raphael G. Inorganic Chemistry, Vol. 42, Issue 2 https://doi.org/10.1021/ic026051+	journal	December 2002
A simple and robust method for the identification of π–π packing motifs of aromatic compounds Loots, Leigh; Barbour, Leonard J. CrystEngComm, Vol. 14, Issue 1 https://doi.org/10.1039/C1CE05763D	journal	January 2012
Hingeless Negative Linear Compression in the Mechanochromic Gold Complex [(C ₆ F ₅ Au) ₂ (μ-1,4-diisocyanobenzene)] Woodall, Christopher H.; Beavers, Christine M.; Christensen, Jeppe Angewandte Chemie, Vol. 125, Issue 37 https://doi.org/10.1002/ange.201302825	journal	August 2013
X-Seed — A Software Tool for Supramolecular Crystallography Barbour, Leonard J. Journal of Supramolecular Chemistry, Vol. 1, Issue 4-6 https://doi.org/10.1016/S1472-7862(02)00030-8	journal	July 2001
Solvent-Stimulated Luminescence from the Supramolecular Aggregation of a Trinuclear Gold(I) Complex that Displays Extensive Intermolecular AuċAu Interactions Vickery, Jess C.; Olmstead, Marilyn M.; Fung, Ella Y. Angewandte Chemie International Edition in English, Vol. 36, Issue 11 https://doi.org/10.1002/anie.199711791	journal	June 1997
OLEX2 : a complete structure solution, refinement and analysis program Dolomanov, Oleg V.; Bourhis, Luc J.; Gildea, Richard J. Journal of Applied Crystallography, Vol. 42, Issue 2 https://doi.org/10.1107/S0021889808042726	journal	January 2009
Supramolecular assembly of molecular gold(I) compounds: An evaluation of the competition and complementarity between aurophilic (Au⋯Au) and conventional hydrogen bonding interactions Tiekink, Edward R. T. Coordination Chemistry Reviews, Vol. 275 https://doi.org/10.1016/j.ccr.2014.04.029	journal	September 2014
Hirshfeld Surfaces: A New Tool for Visualising and Exploring Molecular Crystals McKinnon, Joshua J.; Mitchell, Anthony S.; Spackman, Mark A. Chemistry - A European Journal, Vol. 4, Issue 11 https://doi.org/10.1002/(SICI)1521-3765(19981102)4:11<2136::AID-CHEM2136>3.0.CO;2-G	journal	November 1998
Syntheses and x-ray structures of group 11 pyrazole and pyrazolate complexes. X-ray crystal structures of bis(3,5-diphenylpyrazole)copper(II) dibromide, tris(.mu.-3,5-diphenylpyrazolato-N,N')trisilver(I)-2-tetrahydrofuran, tris(.mu.-3,5-diphenylpyrazolato-N,N')trigold(I), and hexakis(.mu.-3,5-diphenylpyrazolato-N,N')hexagold(I) Murray, H. H.; Raptis, Raphael G.; Fackler, John P. Inorganic Chemistry, Vol. 27, Issue 1 https://doi.org/10.1021/ic00274a008	journal	January 1988
Anisotropic Chemical Pressure Effects in Single-Component Molecular Metals Based on Radical Dithiolene and Diselenolene Gold Complexes Yzambart, Gilles; Bellec, Nathalie; Nasser, Ghassan Journal of the American Chemical Society, Vol. 134, Issue 41 https://doi.org/10.1021/ja3065649	journal	October 2012
Solvensstimulierte Lumineszenz eines supramolekular assoziierten dreikernigen Gold(I)-Komplexes mit starken intermolekularen Au-Au-Wechselwirkungen Vickery, Jess C.; Olmstead, Marilyn M.; Fung, Ella Y. Angewandte Chemie, Vol. 109, Issue 11 https://doi.org/10.1002/ange.19971091109	journal	June 1997
Theoretical study on electronic spectra and aurophilic attraction in <mml:math altimg="si83.gif" display="inline" overflow="scroll" xmlns:xocs="http://www.elsevier.com/xml/xocs/dtd" xmlns:xs="http://www.w3.org/2001/XMLSchema" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://www.elsevier.com/xml/ja/dtd" xmlns:ja="http://www.elsevier.com/xml/ja/dtd" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:tb="http://www.elsevier.com/xml/common/table/dtd" xmlns:sb="http://www.elsevier.com/xml/common/struct-bib/dtd" xmlns:ce="http://www.elsevier.com/xml/common/dtd" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:cals="http://www.elsevier.com/xml/common/cals/dtd"><mml:mrow><mml:mo stretchy="false">[</mml:mo><mml:msub><mml:mrow><mml:mtext>Au</mml:mtext></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub><mml:mo stretchy="false">(</mml:mo><mml:mtext>MeN<ce:glyph name="dbnd"/>COMe</mml:mtext><mml:msub><mml:mrow><mml:mo stretchy="false">)</mml:mo></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mo stretchy="false">]</mml:mo></mml:mrow><mml:mrow><mml:mi>n</mml:mi></mml:mrow></mml:msub><mml:mspace width="0.35em"/><mml:mo stretchy="false">(</mml:mo><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn>1</mml:mn><mml:ms>–</mml:ms><mml:mn>4</mml:mn><mml:mo stretchy="false">)</mml:mo></mml:mrow></mml:math> complexes Mendizabal, Fernando; Aguilera, Benjamín; Olea-Azar, Claudio Chemical Physics Letters, Vol. 447, Issue 4-6 https://doi.org/10.1016/j.cplett.2007.09.016	journal	October 2007
[Mn6] under Pressure: A Combined Crystallographic and Magnetic Study Prescimone, Alessandro; Milios, Constantinos J.; Moggach, Stephen Angewandte Chemie, Vol. 120, Issue 15 https://doi.org/10.1002/ange.200705819	journal	March 2008
WinGX suite for small-molecule single-crystal crystallography Farrugia, Louis J. Journal of Applied Crystallography, Vol. 32, Issue 4 https://doi.org/10.1107/S0021889899006020	journal	August 1999
Opening the Gate: Framework Flexibility in ZIF-8 Explored by Experiments and Simulations Fairen-Jimenez, D.; Moggach, S. A.; Wharmby, M. T. Journal of the American Chemical Society, Vol. 133, Issue 23 https://doi.org/10.1021/ja202154j	journal	June 2011
Negative Linear Compressibility of a Metal–Organic Framework Li, Wei; Probert, Michael R.; Kosa, Monica Journal of the American Chemical Society, Vol. 134, Issue 29 https://doi.org/10.1021/ja305196u	journal	July 2012
A novel definition of a molecule in a crystal Spackman, Mark A.; Byrom, Patrick G. Chemical Physics Letters, Vol. 267, Issue 3-4 https://doi.org/10.1016/S0009-2614(97)00100-0	journal	March 1997
Piezochromism in Nickel Salicylaldoximato Complexes: Tuning Crystal-Field Splitting with High Pressure Byrne, Peter J.; Richardson, Patricia J.; Chang, John Chemistry - A European Journal, Vol. 18, Issue 25 https://doi.org/10.1002/chem.201200213	journal	May 2012
Effect of high pressure on the emission spectrum of single crystals of Tl[Au(CN)2] Strasser, Johann; Yersin, Hartmut; Patterson, Howard H. Chemical Physics Letters, Vol. 295, Issue 1-2 https://doi.org/10.1016/S0009-2614(98)00915-4	journal	October 1998
High-pressure neutron diffraction study of L -serine-I and L -serine-II, and the structure of L -serine-III at 8.1 GPa Moggach, Stephen A.; Marshall, William G.; Parsons, Simon Acta Crystallographica Section B Structural Science, Vol. 62, Issue 5 https://doi.org/10.1107/S010876810601799X	journal	September 2006
High-pressure polymorphism in amino acids Moggach, Stephen A.; Parsons, Simon; Wood, Peter A. Crystallography Reviews, Vol. 14, Issue 2 https://doi.org/10.1080/08893110802037945	journal	April 2008
Intermolecular Interactions in Polymorphs of Trinuclear Gold(I) Complexes: Insight into the Solvoluminescence of Au ^I ₃ (MeNCOMe) ₃ White-Morris, Rochelle L.; Olmstead, Marilyn M.; Attar, Saeed Inorganic Chemistry, Vol. 44, Issue 14 https://doi.org/10.1021/ic050381n	journal	July 2005
Alteration of the Aurophilic Interactions in Trimeric Gold(I) Compounds through Charge Transfer. Behavior of Solvoluminescent Au ₃ (MeNCOMe) ₃ in the Presence of Electron Acceptors Olmstead, Marilyn M.; Jiang, Feilong; Attar, Saeed Journal of the American Chemical Society, Vol. 123, Issue 14 https://doi.org/10.1021/ja0029533	journal	April 2001
Structural origin of the gradual spin transition in a mononuclear iron(II) complex Shepherd, Helena J.; Rosa, Patrick; Fallis, Ian A. Journal of Physics and Chemistry of Solids, Vol. 73, Issue 2 https://doi.org/10.1016/j.jpcs.2011.11.003	journal	February 2012
The first sandwich silver cluster of a trinuclear cyclic gold(I) complex Burini, Alfredo; Galassi, Rossana; Pietroni, Bianca R. Chemical Communications, Issue 1 https://doi.org/10.1039/a706795j	journal	January 1998
Comparing entire crystal structures: structural genetic fingerprinting Parkin, Andrew; Barr, Gordon; Dong, Wei CrystEngComm, Vol. 9, Issue 8 https://doi.org/10.1039/b704177b	journal	January 2007
Searching for novel crystal forms by in situ high-pressure crystallisation: the example of gabapentin heptahydrate Fabbiani, Francesca P. A.; Levendis, Demetrius C.; Buth, Gernot CrystEngComm, Vol. 12, Issue 8 https://doi.org/10.1039/b924573a	journal	January 2010
A Reversible Polymorphic Phase Change Which Affects the Luminescence and Aurophilic Interactions in the Gold(I) Cluster Complex, [μ ₃ -S(AuCNC ₇ H ₁₃ ) ₃ ](SbF ₆ ) Gussenhoven, Emily M.; Fettinger, James C.; Pham, David M. Journal of the American Chemical Society, Vol. 127, Issue 31 https://doi.org/10.1021/ja052799q	journal	August 2005
Metal Effect on the Supramolecular Structure, Photophysics, and Acid−Base Character of Trinuclear Pyrazolato Coinage Metal Complexes ^† Omary, Mohammad A.; Rawashdeh-Omary, Manal A.; Gonser, M. W. Alexander Inorganic Chemistry, Vol. 44, Issue 23 https://doi.org/10.1021/ic0508730	journal	November 2005
Hingeless Negative Linear Compression in the Mechanochromic Gold Complex [(C ₆ F ₅ Au) ₂ (μ-1,4-diisocyanobenzene)] Woodall, Christopher H.; Beavers, Christine M.; Christensen, Jeppe Angewandte Chemie International Edition, Vol. 52, Issue 37 https://doi.org/10.1002/anie.201302825	journal	August 2013
The Anisotropic Compression of the Crystal Structure of 3-Aza-bicyclo(3.3.1)nonane-2,4-dione to 7.1 GPa Wood, Peter A.; Haynes, Delia A.; Lennie, Alistair R. Crystal Growth & Design, Vol. 8, Issue 2 https://doi.org/10.1021/cg0705815	journal	February 2008
Highlights on the recent advances in gold chemistry—a photophysical perspective Yam, Vivian Wing-Wah; Cheng, Eddie Chung-Chin Chemical Society Reviews, Vol. 37, Issue 9 https://doi.org/10.1039/b708615f	journal	January 2008
Use of a CCD diffractometer in crystal structure determinations at high pressure Dawson, Alice; Allan, David R.; Parsons, Simon Journal of Applied Crystallography, Vol. 37, Issue 3 https://doi.org/10.1107/S0021889804007149	journal	May 2004
Towards quantitative analysis of intermolecular interactions with Hirshfeld surfaces McKinnon, Joshua J.; Jayatilaka, Dylan; Spackman, Mark A. Chemical Communications, Issue 37 https://doi.org/10.1039/b704980c	journal	January 2007
Finite Elastic Strain of Cubic Crystals Birch, Francis Physical Review, Vol. 71, Issue 11 https://doi.org/10.1103/PhysRev.71.809	journal	June 1947
Polymorphism of a Model Arylboronic Azaester: Combined Experimental and Computational Studies Durka, Krzysztof; Hoser, Anna A.; Kamiński, Radosław Crystal Growth & Design, Vol. 11, Issue 5 https://doi.org/10.1021/cg200032e	journal	May 2011
CRYSTALS version 12: software for guided crystal structure analysis Betteridge, Paul W.; Carruthers, J. Robert; Cooper, Richard I. Journal of Applied Crystallography, Vol. 36, Issue 6 https://doi.org/10.1107/S0021889803021800	journal	November 2003
Glowing gold rings: solvoluminescence from planar trigold(I) complexes Fung, Ella Y.; Olmstead, Marilyn M.; Vickery, Jess C. Coordination Chemistry Reviews, Vol. 171 https://doi.org/10.1016/S0010-8545(98)90025-X	journal	April 1998
Crystal Chemistry of the Gold (I) Trimer, Au ₃ (NC ₅ H ₄ ) ₃ : Formation of Hourglass Figures and Self-Association through Aurophilic Attraction Hayashi, Akari; Olmstead, Marilyn M.; Attar, Saeed Journal of the American Chemical Society, Vol. 124, Issue 20 https://doi.org/10.1021/ja012416y	journal	May 2002
Fingerprinting intermolecular interactions in molecular crystals Spackman, Mark A.; McKinnon, Joshua J. CrystEngComm, Vol. 4, Issue 66 https://doi.org/10.1039/B203191B	journal	January 2002
High Pressure Study of Ru ₃ (CO) ₁₂ by X-ray Diffraction, Raman, and Infrared Spectroscopy Slebodnick, Carla; Zhao, Jing; Angel, Ross Inorganic Chemistry, Vol. 43, Issue 17 https://doi.org/10.1021/ic049617y	journal	August 2004
Molecular Crystals Under High Pressure: Theoretical and Experimental Investigations of the Solid-Solid Phase Transitions in [Co ₂ (CO) ₆ (XPh ₃ ) ₂ ] (X=P, As) Casati, Nicola; Macchi, Piero; Sironi, Angelo Chemistry - A European Journal, Vol. 15, Issue 17 https://doi.org/10.1002/chem.200801528	journal	April 2009
Structure and luminescence properties of a well-known macrometallocyclic trinuclear Au(i) complex and its adduct with a perfluorinated fluorophore showing cooperative anisotropic supramolecular interactions Elbjeirami, Oussama; Rashdan, Maher D.; Nesterov, Vladimir Dalton Transactions, Vol. 39, Issue 40 https://doi.org/10.1039/c0dt00736f	journal	January 2010
[Mn6] under Pressure: A Combined Crystallographic and Magnetic Study Prescimone, Alessandro; Milios, Constantinos J.; Moggach, Stephen Angewandte Chemie International Edition, Vol. 47, Issue 15 https://doi.org/10.1002/anie.200705819	journal	March 2008
Comparing entire crystal structures using cluster analysis and fingerprint plots Collins, Anna; Wilson, Chick C.; Gilmore, Christopher J. CrystEngComm, Vol. 12, Issue 3 https://doi.org/10.1039/B914683K	journal	January 2010
Calibration of the pressure dependence of the R ₁ ruby fluorescence line to 195 kbar Piermarini, G. J.; Block, S.; Barnett, J. D. Journal of Applied Physics, Vol. 46, Issue 6 https://doi.org/10.1063/1.321957	journal	June 1975
Shedding Light on the Structure of a Photoinduced Transient Excimer by Time-Resolved Diffraction Vorontsov, Ivan I.; Kovalevsky, Andrey Yu.; Chen, Yu-Sheng Physical Review Letters, Vol. 94, Issue 19 https://doi.org/10.1103/PhysRevLett.94.193003	journal	May 2005
Equations of State Angel, R. J. Reviews in Mineralogy and Geochemistry, Vol. 41, Issue 1 https://doi.org/10.2138/rmg.2000.41.2	journal	January 2000
Trinuclear Gold(I) Pyrazolate Complexes Exhibiting Hexagonal Columnar Mesophases with Only Three Side Chains ¹ Kim, Sung Jee; Kang, Seok Ho; Park, Ki-Min Chemistry of Materials, Vol. 10, Issue 7 https://doi.org/10.1021/cm9800534	journal	July 1998
Mercury CSD 2.0 – new features for the visualization and investigation of crystal structures Macrae, Clare F.; Bruno, Ian J.; Chisholm, James A. Journal of Applied Crystallography, Vol. 41, Issue 2 https://doi.org/10.1107/S0021889807067908	journal	March 2008
Hirshfeld surface analysis Spackman, Mark A.; Jayatilaka, Dylan CrystEngComm, Vol. 11, Issue 1 https://doi.org/10.1039/B818330A	journal	January 2009
A short history of SHELX Sheldrick, George M. Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122 https://doi.org/10.1107/S0108767307043930	journal	December 2007
Luminescent Chains Formed from Neutral, Triangular Gold Complexes Sandwiching Tl ^I and Ag ^I . Structures of {Ag([Au(μ-C ² ,N ³ -bzim)] ₃ ) ₂ }BF ₄ ·CH ₂ Cl ₂ , {Tl([Au(μ-C ² ,N ³ -bzim)] ₃ ) ₂ }PF ₆ ·0.5THF (bzim = 1-Benzylimidazolate), and {Tl([Au(μ-C(OEt)═NC ₆ H ₄ CH ₃ )] ₃ ) ₂ }PF ₆ ·THF, with MAu ₆ (M = Ag ⁺ , Tl ⁺ ) Cluster Cores Burini, Alfredo; Bravi, Rita; Fackler, John P. Inorganic Chemistry, Vol. 39, Issue 15 https://doi.org/10.1021/ic991492n	journal	June 2000
The aurophilicity phenomenon: A decade of experimental findings, theoretical concepts and emerging applications Schmidbaur, Hubert Gold Bulletin, Vol. 33, Issue 1 https://doi.org/10.1007/BF03215477	journal	March 2000
High-pressure polymorphism in salicylamide Johnstone, Russell D. L.; Lennie, Alistair R.; Parker, Stewart F. CrystEngComm, Vol. 12, Issue 4 https://doi.org/10.1039/b921288d	journal	January 2010
(Tetrahydrothiophene)Gold(I) or Gold(III) Complexes Uson, Rafael; Laguna, Antonio; Laguna, Mariano Inorganic Syntheses https://doi.org/10.1002/9780470132579.ch17	book	January 2007
Bowing to the Pressure of π⋅⋅⋅π Interactions: Bending of Phenyl Rings in a Palladium(II) Thioether Crown Complex Wong, Henry L. S.; Allan, David R.; Champness, Neil R. Angewandte Chemie, Vol. 125, Issue 19 https://doi.org/10.1002/ange.201209845	journal	April 2013
High-Pressure (up to 10.7 GPa) Crystal Structure of Single-Component Molecular Metal [Au(tmdt) ₂ ] Okano, Yoshinori; Zhou, Biao; Tanaka, Hishashi Journal of the American Chemical Society, Vol. 131, Issue 20 https://doi.org/10.1021/ja9010018	journal	May 2009
Pressure-Dependent Luminescence Properties of Gold(I) and Silver(I) Dithiocarbamate Compounds Baril-Robert, François; Radtke, M. Alex; Reber, Christian The Journal of Physical Chemistry C, Vol. 116, Issue 3 https://doi.org/10.1021/jp206766p	journal	November 2011
Phosphorescent Organogels via “Metallophilic” Interactions for Reversible RGB−Color Switching Kishimura, Akihiro; Yamashita, Takashi; Aida, Takuzo Journal of the American Chemical Society, Vol. 127, Issue 1 https://doi.org/10.1021/ja0441007	journal	January 2005
Bowing to the Pressure of π⋅⋅⋅π Interactions: Bending of Phenyl Rings in a Palladium(II) Thioether Crown Complex Wong, Henry L. S.; Allan, David R.; Champness, Neil R. Angewandte Chemie International Edition, Vol. 52, Issue 19 https://doi.org/10.1002/anie.201209845	journal	April 2013
Giant negative linear compressibility in zinc dicyanoaurate Cairns, Andrew B.; Catafesta, Jadna; Levelut, Claire Nature Materials, Vol. 12, Issue 3 https://doi.org/10.1038/nmat3551	journal	January 2013
Polymorphism of a model arylboronic azaester – combined experimental and computational studies Durka, K.; Hoser, A. A.; Kamiński, R. Acta Crystallographica Section A Foundations of Crystallography, Vol. 67, Issue a1 https://doi.org/10.1107/s0108767311085850	journal	August 2011
Comparing entire crystal structures: structural genetic fingerprinting Parkin, A.; Barr, G.; Dong, W. Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue a1 https://doi.org/10.1107/s0108767308084316	journal	August 2008
Novel tools for visualizing and exploring intermolecular interactions in molecular crystals McKinnon, Joshua J.; Spackman, Mark A.; Mitchell, Anthony S. Acta Crystallographica Section B Structural Science, Vol. 60, Issue 6 https://doi.org/10.1107/s0108768104020300	journal	November 2004
Exploration of the high-pressure behaviour of polycyclic aromatic hydrocarbons: naphthalene, phenanthrene and pyrene Fabbiani, Francesca P. A.; Allan, David R.; Parsons, Simon Acta Crystallographica Section B Structural Science, Vol. 62, Issue 5 https://doi.org/10.1107/s0108768106026814	journal	September 2006

Cited By (8)

Anion-, Solvent-, Temperature-, and Mechano-Responsive Photoluminescence in Gold(I) Diphosphine-Based Dimers Deák, Andrea; Jobbágy, Csaba; Marsi, Gábor Chemistry - A European Journal, Vol. 21, Issue 32 https://doi.org/10.1002/chem.201501066	journal	June 2015
Luminescent Thermochromism in a Gold(I)-Copper(I) Phosphine-Pyridine Complex: Luminescent Thermochromism in an Au Chen, Kelly; Catalano, Vincent J. European Journal of Inorganic Chemistry, Vol. 2015, Issue 31 https://doi.org/10.1002/ejic.201500925	journal	October 2015
A high-pressure crystallographic and magnetic study of Na 5 [Mn( l -tart) 2 ]·12H 2 O ( l -tart = l -tartrate) Craig, Gavin A.; Woodall, Christopher H.; McKellar, Scott C. Dalton Transactions, Vol. 44, Issue 42 https://doi.org/10.1039/c5dt03320a	journal	January 2015
Aurophilicity under pressure: a combined crystallographic and in situ spectroscopic study O'Connor, Alice E.; Mirzadeh, Nedaossadat; Bhargava, Suresh K. Chemical Communications, Vol. 52, Issue 41 https://doi.org/10.1039/c6cc00923a	journal	January 2016
Novel gold( i ) diphosphine-based dimers with aurophilicity triggered multistimuli light-emitting properties Jobbágy, Csaba; Baranyai, Péter; Marsi, Gábor Journal of Materials Chemistry C, Vol. 4, Issue 43 https://doi.org/10.1039/c6tc01427e	journal	January 2016
Observation of a re-entrant phase transition in the molecular complex tris(μ ₂ -3,5-diisopropyl-1,2,4-triazolato-κ ² N ¹ : N ² )trigold(I) under high pressure Woodall, Christopher H.; Christensen, Jeppe; Skelton, Jonathan M. IUCrJ, Vol. 3, Issue 5 https://doi.org/10.1107/s2052252516013129	journal	August 2016
A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine) Shepherd, Helena; Tonge, George; Hatcher, Lauren Magnetochemistry, Vol. 2, Issue 1 https://doi.org/10.3390/magnetochemistry2010009	journal	February 2016
Absorbate-Induced Piezochromism in a Porous Molecular Crystal Hendon, Christopher H.; Wittering, Kate E.; Chen, Teng-Hao Nano Letters, Vol. 15, Issue 3 https://doi.org/10.1021/acs.nanolett.5b00144	journal	March 2015

Linked Research (55)

Figures / Tables (13)

Similar Records

Molecular and Electronic Structure of Cyclic Trinuclear Gold(I) Carbeniate Complexes: Insights for Structure/Luminescence/Conductivity Relationships

Journal Article · Wed Jan 01 00:00:00 EST 2014 · Inorganic Chemistry · OSTI ID:1213528

McDougaldJr, Roy N; Chilukuri, Bhaskar; Jia, Huiping; +7 more

Solid state EXAFS and luminescence studies of neutral, dinuclear gold(I) complexes. Gold(I)-gold(I) interactions in the solid state

Journal Article · Wed Apr 12 00:00:00 EDT 1995 · Inorganic Chemistry · OSTI ID:1213528

Jones, W B; Yuan, J; Elder, R C; +4 more

Observation of a re-entrant phase transition in the molecular complex tris(μ₂-3,5-diisopropyl-1,2,4-triazolato-κ²N¹:N²)trigold(I) under high pressure

Journal Article · Thu Aug 18 00:00:00 EDT 2016 · IUCrJ · OSTI ID:1213528

Woodall, Christopher H.; Christensen, Jeppe; Skelton, Jonathan M.; +10 more

Related Subjects

74 ATOMIC AND MOLECULAR PHYSICS
aurophilicity
crystallography
gold
high pressure
luminescence

CCDC 971072: Experimental Crystal Structure Determination: JOSNOW02 : tris(μ-2-phenyl-5-methylpyrazolato)-tri-gold(i) unknown solvate Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lgx0 The current record is supplemented by this dataset	dataset	June 2014
CCDC 971073: Experimental Crystal Structure Determination: FUWXOK09 : tris(μ-3,5-diphenylPyrazolato-N,N')-tri-gold(i) Space Group: R 3 c (167), Cell: a 15.8344(7)Å b 15.8344(7)Å c 25.013(2)Å, α 90.00° β 90.00° γ 120.00° Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lgy1 The current record is supplemented by this dataset	dataset	June 2014
CCDC 971074: Experimental Crystal Structure Determination: FUWXOK10 : tris(μ-3,5-diphenylPyrazolato-N,N')-tri-gold(i) Space Group: R 3 c (167), Cell: a 15.7110(9)Å b 15.7110(9)Å c 24.560(3)Å, α 90.00° β 90.00° γ 120.00° Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lgz2 The current record is supplemented by this dataset	dataset	June 2014
CCDC 971075: Experimental Crystal Structure Determination: FUWXOK11 : tris(μ-3,5-diphenylPyrazolato-N,N')-tri-gold(i) Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lh04 The current record is supplemented by this dataset	dataset	June 2014
CCDC 971076: Experimental Crystal Structure Determination: FUWXOK12 : tris(μ-3,5-diphenylPyrazolato-N,N')-tri-gold(i) Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lh15 The current record is supplemented by this dataset	dataset	June 2014
CCDC 971077: Experimental Crystal Structure Determination: FUWXOK13 : tris(μ-3,5-diphenylPyrazolato-N,N')-tri-gold(i) Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lh26 The current record is supplemented by this dataset	dataset	June 2014
CCDC 971078: Experimental Crystal Structure Determination: FUWXOK14 : tris(μ-3,5-diphenylPyrazolato-N,N')-tri-gold(i) Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lh37 The current record is supplemented by this dataset	dataset	June 2014
CCDC 971081: Experimental Crystal Structure Determination: YOSRUU09 : tris(μ2-3,4,5-Trimethylpyrazolato-N,N')-tri-gold(i) Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lh6b The current record is supplemented by this dataset	dataset	June 2014
CCDC 971083: Experimental Crystal Structure Determination: YOSRUU11 : tris(μ2-3,4,5-Trimethylpyrazolato-N,N')-tri-gold(i) Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lh8d The current record is supplemented by this dataset	dataset	June 2014
CCDC 971084: Experimental Crystal Structure Determination: YOSRUU12 : tris(μ2-3,4,5-Trimethylpyrazolato-N,N')-tri-gold(i) Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lh9f The current record is supplemented by this dataset	dataset	June 2014
CCDC 971086: Experimental Crystal Structure Determination: YOSRUU14 : tris(μ2-3,4,5-Trimethylpyrazolato-N,N')-tri-gold(i) Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lhch The current record is supplemented by this dataset	dataset	June 2014
CCDC 971087: Experimental Crystal Structure Determination: YOSRUU15 : tris(μ2-3,4,5-Trimethylpyrazolato-N,N')-tri-gold(i) Space Group: P 21/c (14), Cell: a 8.289(5)Å b 21.438(5)Å c 9.569(5)Å, α 90.000° β 89.582(5)° γ 90.000° Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lhdj The current record is supplemented by this dataset	dataset	June 2014
CCDC 971088: Experimental Crystal Structure Determination: MUTKUH02 : tris(μ2-Pyrazolato-N,N')-tri-gold(i) Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lhfk The current record is supplemented by this dataset	dataset	June 2014
CCDC 971089: Experimental Crystal Structure Determination: MUTKUH03 : tris(μ2-Pyrazolato-N,N')-tri-gold(i) Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lhgl The current record is supplemented by this dataset	dataset	June 2014
CCDC 971090: Experimental Crystal Structure Determination: MUTKUH04 : tris(μ2-Pyrazolato-N,N')-tri-gold(i) Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lhhm The current record is supplemented by this dataset	dataset	June 2014
CCDC 971092: Experimental Crystal Structure Determination: MUTKUH06 : tris(μ2-Pyrazolato-N,N')-tri-gold(i) Space Group: P 21/c (14), Cell: a 7.8073(16)Å b 13.026(3)Å c 10.538(2)Å, α 90.00° β 107.26(3)° γ 90.00° Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lhkp The current record is supplemented by this dataset	dataset	June 2014
CCDC 971094: Experimental Crystal Structure Determination: MUTKUH08 : tris(μ2-Pyrazolato-N,N')-tri-gold(i) Space Group: P 21/c (14), Cell: a 7.6803(15)Å b 12.717(3)Å c 10.442(2)Å, α 90.00° β 107.23(3)° γ 90.00° Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lhmr The current record is supplemented by this dataset	dataset	June 2014
CCDC 971097: Experimental Crystal Structure Determination: MUTKUH16 : tris(μ2-Pyrazolato-N,N')-tri-gold(i) Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lhqv The current record is supplemented by this dataset	dataset	June 2014
CCDC 971098: Experimental Crystal Structure Determination: MUTKUH09 : tris(μ2-Pyrazolato-N,N')-tri-gold(i) Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lhrw The current record is supplemented by this dataset	dataset	June 2014
CCDC 971099: Experimental Crystal Structure Determination: MUTKUH10 : tris(μ2-Pyrazolato-N,N')-tri-gold(i) Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lhsx The current record is supplemented by this dataset	dataset	June 2014
CCDC 971100: Experimental Crystal Structure Determination: MUTKUH11 : tris(μ2-Pyrazolato-N,N')-tri-gold(i) Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lhty The current record is supplemented by this dataset	dataset	June 2014
CCDC 971101: Experimental Crystal Structure Determination: MUTKUH12 : tris(μ2-Pyrazolato-N,N')-tri-gold(i) Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lhvz The current record is supplemented by this dataset	dataset	June 2014
CCDC 971102: Experimental Crystal Structure Determination: MUTKUH13 : tris(μ2-Pyrazolato-N,N')-tri-gold(i) Space Group: P 21/c (14), Cell: a 8.3340(12)Å b 14.364(2)Å c 11.0508(16)Å, α 90.00° β 106.890(2)° γ 90.00° Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lhw0 The current record is supplemented by this dataset	dataset	June 2014
CCDC 971104: Experimental Crystal Structure Determination: FUWXOK02 : tris(μ-3,5-diphenylPyrazolato-N,N')-tri-gold(i) Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lhy2 The current record is supplemented by this dataset	dataset	June 2014
CCDC 971105: Experimental Crystal Structure Determination: FUWXOK03 : tris(μ-3,5-diphenylPyrazolato-N,N')-tri-gold(i) Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lhz3 The current record is supplemented by this dataset	dataset	June 2014
CCDC 971106: Experimental Crystal Structure Determination: FUWXOK04 : tris(μ-3,5-diphenylPyrazolato-N,N')-tri-gold(i) Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lj05 The current record is supplemented by this dataset	dataset	June 2014
CCDC 971107: Experimental Crystal Structure Determination: FUWXOK05 : tris(μ-3,5-diphenylPyrazolato-N,N')-tri-gold(i) Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lj16 The current record is supplemented by this dataset	dataset	June 2014
CCDC 971109: Experimental Crystal Structure Determination: FUWXOK07 : tris(μ-3,5-diphenylPyrazolato-N,N')-tri-gold(i) Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lj38 The current record is supplemented by this dataset	dataset	June 2014
CCDC 971113: Experimental Crystal Structure Determination Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lj7d The current record is supplemented by this dataset	dataset	June 2014
CCDC 971117: Experimental Crystal Structure Determination: JOSNOW04 : tris(μ-2-phenyl-5-methylpyrazolato)-tri-gold(i) unknown solvate Space Group: P n a 21 (33), Cell: a 7.2939(6)Å b 15.8792(13)Å c 26.144(2)Å, α 90.00° β 90.00° γ 90.00° Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11ljcj The current record is supplemented by this dataset	dataset	June 2014
CCDC 971118: Experimental Crystal Structure Determination: JOSNOW05 : tris(μ-2-phenyl-5-methylpyrazolato)-tri-gold(i) unknown solvate Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11ljdk The current record is supplemented by this dataset	dataset	June 2014
CCDC 971120: Experimental Crystal Structure Determination: YOSRUU02 : tris(μ2-3,4,5-Trimethylpyrazolato-N,N')-tri-gold(i) Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11ljgm The current record is supplemented by this dataset	dataset	June 2014
CCDC 971121: Experimental Crystal Structure Determination: YOSRUU03 : tris(μ2-3,4,5-Trimethylpyrazolato-N,N')-tri-gold(i) Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11ljhn The current record is supplemented by this dataset	dataset	June 2014
CCDC 971122: Experimental Crystal Structure Determination: YOSRUU04 : tris(μ2-3,4,5-Trimethylpyrazolato-N,N')-tri-gold(i) Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11ljjp The current record is supplemented by this dataset	dataset	June 2014
CCDC 971123: Experimental Crystal Structure Determination: YOSRUU05 : tris(μ2-3,4,5-Trimethylpyrazolato-N,N')-tri-gold(i) Space Group: P 21/c (14), Cell: a 8.8835(2)Å b 22.3125(5)Å c 10.8161(3)Å, α 90.00° β 94.256(3)° γ 90.00° Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11ljkq The current record is supplemented by this dataset	dataset	June 2014
CCDC 971124: Experimental Crystal Structure Determination: YOSRUU06 : tris(μ2-3,4,5-Trimethylpyrazolato-N,N')-tri-gold(i) Space Group: P 21/c (14), Cell: a 8.9143(2)Å b 22.3356(5)Å c 10.8211(3)Å, α 90.00° β 94.370(3)° γ 90.00° Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11ljlr The current record is supplemented by this dataset	dataset	June 2014
CCDC 971128: Experimental Crystal Structure Determination: YOSRUU08 : tris(μ2-3,4,5-Trimethylpyrazolato-N,N')-tri-gold(i) Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11ljqw The current record is supplemented by this dataset	dataset	June 2014
CCDC 971071: Experimental Crystal Structure Determination: JOSNOW01 : tris(μ-2-phenyl-5-methylpyrazolato)-tri-gold(i) unknown solvate Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lgwz The current record is supplemented by this dataset	dataset	June 2014
CCDC 971079: Experimental Crystal Structure Determination: FUWXOK15 : tris(μ-3,5-diphenylPyrazolato-N,N')-tri-gold(i) Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lh48 The current record is supplemented by this dataset	dataset	June 2014
CCDC 971085: Experimental Crystal Structure Determination: YOSRUU13 : tris(μ2-3,4,5-Trimethylpyrazolato-N,N')-tri-gold(i) Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lhbg The current record is supplemented by this dataset	dataset	June 2014
CCDC 971093: Experimental Crystal Structure Determination: MUTKUH07 : tris(μ2-Pyrazolato-N,N')-tri-gold(i) Space Group: P 21/c (14), Cell: a 7.7527(16)Å b 12.866(3)Å c 10.491(2)Å, α 90.00° β 107.21(3)° γ 90.00° Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lhlq The current record is supplemented by this dataset	dataset	June 2014
CCDC 971095: Experimental Crystal Structure Determination: MUTKUH14 : tris(μ2-Pyrazolato-N,N')-tri-gold(i) Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lhns The current record is supplemented by this dataset	dataset	June 2014
CCDC 971096: Experimental Crystal Structure Determination: MUTKUH15 : tris(μ2-Pyrazolato-N,N')-tri-gold(i) Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lhpt The current record is supplemented by this dataset	dataset	June 2014
CCDC 971103: Experimental Crystal Structure Determination: FUWXOK01 : tris(μ-3,5-diphenylPyrazolato-N,N')-tri-gold(i) Space Group: R 3 c (167), Cell: a 15.97110(10)Å b 15.97110(10)Å c 25.3408(3)Å, α 90.00° β 90.00° γ 120.00° Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lhx1 The current record is supplemented by this dataset	dataset	June 2014
CCDC 971108: Experimental Crystal Structure Determination: FUWXOK06 : tris(μ-3,5-diphenylPyrazolato-N,N')-tri-gold(i) Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lj27 The current record is supplemented by this dataset	dataset	June 2014
CCDC 971110: Experimental Crystal Structure Determination: FUWXOK08 : tris(μ-3,5-diphenylPyrazolato-N,N')-tri-gold(i) Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lj49 The current record is supplemented by this dataset	dataset	June 2014
CCDC 971111: Experimental Crystal Structure Determination: JOSNOW06 : tris(μ-2-phenyl-5-methylpyrazolato-N,N')-tri-gold(i) unknown solvate Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lj5b The current record is supplemented by this dataset	dataset	June 2014
CCDC 971112: Experimental Crystal Structure Determination: tris(μ-2-Phenyl-5-methylPyrazolato-N,N')-tri-gold(i) unknown solvate Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lj6c The current record is supplemented by this dataset	dataset	June 2014
CCDC 971114: Experimental Crystal Structure Determination: JOSNOW : tris(μ-2-phenyl-5-methylpyrazolato)-tri-gold(i) unknown solvate Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lj8f The current record is supplemented by this dataset	dataset	June 2014
CCDC 971115: Experimental Crystal Structure Determination: JOSNUC : tris(μ-2-phenyl-5-methylpyrazolato)-tri-gold(i) unknown solvate Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lj9g The current record is supplemented by this dataset	dataset	June 2014
CCDC 971119: Experimental Crystal Structure Determination: YOSRUU01 : tris(μ2-3,4,5-Trimethylpyrazolato-N,N')-tri-gold(i) Space Group: P 21/c (14), Cell: a 8.7843(2)Å b 22.2261(6)Å c 10.7865(2)Å, α 90.00° β 93.822(2)° γ 90.00° Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11ljfl The current record is supplemented by this dataset	dataset	June 2014
CCDC 971126: Experimental Crystal Structure Determination: YOSRUU07 : tris(μ2-3,4,5-Trimethylpyrazolato-N,N')-tri-gold(i) Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11ljnt The current record is supplemented by this dataset	dataset	June 2014
CCDC 971082: Experimental Crystal Structure Determination: YOSRUU10 : tris(μ2-3,4,5-Trimethylpyrazolato-N,N')-tri-gold(i) Woodall, Christopher; Fuertes, Sara; Beavers, Christine https://doi.org/10.5517/cc11lh7c The current record is supplemented by this dataset	dataset	June 2014
CCDC 971091: Experimental Crystal Structure Determination: MUTKUH05 : tris(μ2-Pyrazolato-N,N')-tri-gold(i) Space Group: P 21/c (14), Cell: a 7.8837(16)Å b 13.217(3)Å c 10.606(2)Å, α 90.00° β 107.21(3)° γ 90.00° Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11lhjn The current record is supplemented by this dataset	dataset	June 2014
CCDC 971116: Experimental Crystal Structure Determination: JOSNOW03 : tris(μ-2-phenyl-5-methylpyrazolato)-tri-gold(i) unknown solvate Woodall, Christopher H.; Fuertes, Sara; Beavers, Christine M. https://doi.org/10.5517/cc11ljbh The current record is supplemented by this dataset	dataset	June 2014