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Title: An Experimental and Chemical Kinetics Study of the Combustion of Syngas and High Hydrogen Content Fuels

Technical Report ·
DOI:https://doi.org/10.2172/1209913· OSTI ID:1209913
 [1];  [2];  [2]
  1. Pennsylvania State Univ., State College, PA (United States)
  2. Princeton Univ., NJ (United States)

An integrated and collaborative effort involving experiments and complementary chemical kinetic modeling investigated the effects of significant concentrations of water and CO2 and minor contaminant species (methane [CH4], ethane [C2H6], NOX, etc.) on the ignition and combustion of HHC fuels. The research effort specifically addressed broadening the experimental data base for ignition delay, burning rate, and oxidation kinetics at high pressures, and further refinement of chemical kinetic models so as to develop compositional specifications related to the above major and minor species. The foundation for the chemical kinetic modeling was the well validated mechanism for hydrogen and carbon monoxide developed over the last 25 years by Professor Frederick Dryer and his co-workers at Princeton University. This research furthered advance the understanding needed to develop practical guidelines for realistic composition limits and operating characteristics for HHC fuels. A suite of experiments was utilized that that involved a high-pressure laminar flow reactor, a pressure-release type high-pressure combustion chamber and a high-pressure turbulent flow reactor.

Research Organization:
Pennsylvania State Univ., University Park, PA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FE0000752
OSTI ID:
1209913
Country of Publication:
United States
Language:
English