Method of preparing graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes

Liu, Jun; Lemmon, John P; Yang, Zhenguo; Cao, Yuliang; Li, Xiaolin

Title: Method of preparing graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes

Patent · Tue Apr 07 00:00:00 EDT 2015

OSTI ID:1177548

Liu, Jun; Lemmon, John P; Yang, Zhenguo; Cao, Yuliang; Li, Xiaolin

A method of preparing a graphene-sulfur nanocomposite for a cathode in a rechargeable lithium-sulfur battery comprising thermally expanding graphite oxide to yield graphene layers, mixing the graphene layers with a first solution comprising sulfur and carbon disulfide, evaporating the carbon disulfide to yield a solid nanocomposite, and grinding the solid nanocomposite to yield the graphene-sulfur nanocomposite. Rechargeable-lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the graphene sheets. The sulfur particles have an average diameter of less than 50 nm.

View Patent

Cite

Export

Save

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

Assignee:: Battelle Memorial Institute (Richland, WA)

Patent Number(s):: 8,999,574

Application Number:: 14/225,561

OSTI ID:: 1177548

Resource Relation:: Patent File Date: 2014 Mar 26

Country of Publication:: United States

Language:: English

References (10)

High Performance Batteries with Carbon Nanomaterials and Ionic Liquids Lu, Wen https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090246625 US Patent Application 12/412047; 20090246625	patent-application	October 2009
Lithium metal-sulfur and lithium ion-sulfur secondary batteries containing a nano-structured cathode and processes for producing same Zhamu, Aruna; Jang, Bor Z.; Yu, Zenning https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110165466 US Patent Application 12/655597; 20110165466	patent-application	July 2011
The preparation of nano-sulfur/MWCNTs and its electrochemical performance Jia-jia, Chen; Xin, Jia; Qiu-jie, She Electrochimica Acta, Vol. 55, Issue 27, p. 8062-8066 https://doi.org/10.1016/j.electacta.2010.01.069	journal	November 2010
Preparation of nano-structured LiFePO₄/graphene composites by co-precipitation method Ding, Y.; Jiang, Y.; Xu, F. Electrochemistry Communications, Vol. 12, Issue 1, p. 10-13 https://doi.org/10.1016/j.elecom.2009.10.023	journal	January 2010
New Method To Prepare Graphite Nanocomposites Du, Xusheng; Yu, Zhong-Zhen; Dasari, Aravind Chemistry of Materials, Vol. 20, Issue 6 https://doi.org/10.1021/cm703285s	journal	March 2008
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries Ji, Xiulei; Lee, Kyu Tae; Nazar, Linda F. Nature Materials, Vol. 8, Issue 6, p. 500-506 https://doi.org/10.1038/nmat2460	journal	May 2009
Ternary Self-Assembly of Ordered Metal Oxide−Graphene Nanocomposites for Electrochemical Energy Storage Wang, Donghai; Kou, Rong; Choi, Daiwon ACS Nano, Vol. 4, Issue 3, p. 1587-1595 https://doi.org/10.1021/nn901819n	journal	March 2010
Self-Assembled TiO ₂ –Graphene Hybrid Nanostructures for Enhanced Li-Ion Insertion Wang, Donghai; Choi, Daiwon; Li, Juan ACS Nano, Vol. 3, Issue 4, p. 907-914 https://doi.org/10.1021/nn900150y	journal	March 2009
Improvement of cycle property of sulfur-coated multi-walled carbon nanotubes composite cathode for lithium/sulfur batteries Yuan, Lixia; Yuan, Huiping; Qiu, Xinping Journal of Power Sources, Vol. 189, Issue 2, p. 1141-1146 https://doi.org/10.1016/j.jpowsour.2008.12.149	journal	April 2009
Novel nanosized adsorbing sulfur composite cathode materials for the advanced secondary lithium batteries Zheng, W.; Liu, Y. W.; Hu, X. G. Electrochimica Acta, Vol. 51, Issue 7, p. 1330-1335 https://doi.org/10.1016/j.electacta.2005.06.021	journal	January 2006

Similar Records

Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes

Patent · Tue Jun 17 00:00:00 EDT 2014 · OSTI ID:1177548

Liu, Jun; Lemmon, John P; Yang, Zhenguo; +2 more

Sandwich-Type Functionalized Graphene Sheet-Sulfur Nanocomposite for Rechargeable Lithium Batteries

Journal Article · Wed Mar 30 00:00:00 EDT 2011 · Physical Chemistry Chemical Physics. PCCP, 13(17):7660-7665 · OSTI ID:1177548

Cao, Yuliang; Li, Xiaolin; Aksay, Ilhan A; +4 more

Covalently Grafted Polysulfur–Graphene Nanocomposites for Ultrahigh Sulfur-Loading Lithium–Polysulfur Batteries

Journal Article · Wed Nov 29 00:00:00 EST 2017 · ACS Energy Letters · OSTI ID:1177548

Chang, Chi -Hao; Manthiram, Arumugam

Related Subjects

36 MATERIALS SCIENCE
25 ENERGY STORAGE

Title: Method of preparing graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes

Citation Formats

References (10)

Similar Records

Related Subjects