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Title: Nanoscaled Components for Improved Efficiency in a Multiplanel Photocatalytic Water-Splitting System

Technical Report ·
DOI:https://doi.org/10.2172/1163869· OSTI ID:1163869
 [1];  [1]
  1. Univ. of California, San Diego, CA (United States)

The goal of this program was to construct a multicell photochemical device for the direct conversion of solar energy directly to hydrogen by water splitting. We have fabricated a practical photolytic system for quantum efficient production of hydrogen. Our approach is based on the assembly of a multi-component integrated system for direct photocatalytic splitting of water for the efficient production of hydrogen. We propose to produce hydrogen as an energy source that is cost competitive with fossil fuels and without the concomitant production of greenhouse gases. The concept is quite straightforward. In order to achieve the over potential required for direct water splitting, the device is composed of multiple dye-sensitized cells directly linked in series, as illustrated in the figure below. The advantage of this concept is that each cell need contribute only a fraction of the overall potential required for water splitting, thus permitting device engineering to maximized efficiently without regard to electric potential. Progress and barriers to practical application will be described.

Research Organization:
Univ. of California, San Diego, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC); USDOE Chicago Operations Office (CO)
DOE Contract Number:
SC0001038
OSTI ID:
1163869
Report Number(s):
DOE-UCSD-DE-SC0001038
Country of Publication:
United States
Language:
English

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