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Title: Process for desulfurizing petroleum feedstocks

Patent ·
OSTI ID:1133955

A process for upgrading an oil feedstock includes reacting the oil feedstock with a quantity of an alkali metal, wherein the reaction produces solid materials and liquid materials. The solid materials are separated from the liquid materials. The solid materials may be washed and heat treated by heating the materials to a temperature above 400.degree. C. The heat treating occurs in an atmosphere that has low oxygen and water content. Once heat treated, the solid materials are added to a solution comprising a polar solvent, where sulfide, hydrogen sulfide or polysulfide anions dissolve. The solution comprising polar solvent is then added to an electrolytic cell, which during operation, produces alkali metal and sulfur.

Research Organization:
Ceramatec, Inc., Salt Lake City, UT (USA)
Sponsoring Organization:
USDOE
DOE Contract Number:
FE0000408
Assignee:
Ceramatec, Inc. (Salt Lake City, UT)
Patent Number(s):
8,747,660
Application Number:
13/753,918
OSTI ID:
1133955
Country of Publication:
United States
Language:
English

References (48)

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Nuclear Alkylation of Certain Aromatic Hydrocarbons with Alkali Metals as Catalysts patent May 1958
Treatment of Alkylation Feed Stock with Sodium, Potassium, or Lithium Hydroxide Solution patent February 1970
Process for the Desulfurization of Petroleum Oil Fractions patent January 1974
Alkali Metal Desulfurization Process For Petroleum Oil Stocks Using Low Pressure Hydrogen patent January 1974
Process for the Desulfurization of Petroleum Oil Stocks patent January 1974
Alkali Metal Desulfurization Process for Petroleum Oil Stocks patent February 1974
Process for upgrading a hydrocarbon fraction patent June 1976
Combined disulfurization and conversion with alkali metals patent February 1978
Upgrading hydrocarbonaceous oils with an aqueous liquid patent January 1984
Upgrading of low value hydrocarbons using a hydrogen donor and microwave radiation patent July 1994
Continuous in-situ combination process for upgrading heavy oil patent December 1997
Process for the alkylation of aromatics patent May 1998
Methods for adding value to heavy oil utilizing a soluble metal catalyst patent August 1999
Continuous in-situ combination process for upgrading heavy oil patent August 1999
Process for desulfurization of petroleum feeds utilizing sodium metal patent April 2001
Apparatus and system for securing cargo patent August 2001
Low temperature alkali metal electrolysis patent April 2002
Zeolite/alumina catalyst support compositions and method of making the same patent July 2002
Desulfurization with improved sorbent regeneration patent October 2003
Continuous process for the synthesis of nano-scale precious metal particles patent March 2004
Surface-modified mixed oxides containing precious metal and titanium, for the selective oxidation of hydrocarbons patent May 2004
Low temperature alkali metal electrolysis patent September 2004
Process for the recovery of materials from a desulfurization reaction patent March 2011
Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides patent January 2012
Process for reducing the acidity of oil patent-application September 2002
Desulfurization of petroleum streams using metallic sodium patent-application July 2005
Process For The Recovery Of Materials From A Desulfurization Reaction patent-application July 2005
Emulsion neutralization of high total acid number (TAN) crude oil patent-application March 2006
Method of removing sulfur from sulfur-containing hydrocarbon streams patent-application June 2006
Porous composite materials having micro and meso/macroporosity patent-application April 2007
Process For The Reduction/Removal Of The Concentration Of Hydrogen Sulfide Contained In Natural Gas patent-application February 2008
Process For Recovering Alkali Metals and Sulfur From Alkali Metal Sulfides and Polysulfides patent-application May 2009
Integrated System and Method for Producing Fuel Composition From Biomass patent-application October 2009
Apparatus and Method For Reducing an Alkali Metal Electrochemically at a Temperature Below the Metal's Melting Temperature patent-application April 2010
Process for producing a high stability desulfurized heavy oils stream patent-application June 2010
Desulfurization Of Petroleum Streams Using Metallic Sodium patent-application November 2010
Immobilized Fluid Membranes For Gas Separation patent-application November 2010
Electrochemical Cell Comprising Ionically Conductive Membrane And Porous Multiphase Electrode patent-application November 2010
Zeolite Membranes for Separation of Mixtures Containing Water, Alcohols, or Organics patent-application December 2010
Production of Aromatics from Methane patent-application March 2011
Upgrading of Petroleum Oil Feedstocks Using Alkali Metals and Hydrocarbons patent-application May 2011
Process For Catalytic Hydrotreatment Of A Pyrolysis Oil patent-application May 2011
Process For De-Acidifying Hydrocarbons patent-application June 2011
Bio-Oil Upgrading Process patent-application December 2012
Upgrading Platform Using Alkali Metals patent-application February 2013
Method of Preventing Corrosion of Oil Pipelines, Storage Structures and Piping patent-application June 2013
Desulphurization of gasoline by metallic sodium journal July 1976

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