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Title: Preparation of cerium halide solvate complexes

Patent ·
OSTI ID:1089402
; ; ; ;

Crystals of a solvated cerium(III) halide solvate complex resulted from a process of forming a paste of a cerium(III) halide in an ionic liquid, adding a solvent to the paste, removing any undissolved solid, and then cooling the liquid phase. Diffusing a solvent vapor into the liquid phase also resulted in crystals of a solvated cerium(III) halide complex.

Research Organization:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC52-06NA25396
Assignee:
Los Alamos National Security, LLC (Los Alamos, NM)
Patent Number(s):
8,501,484
Application Number:
13/420,159
OSTI ID:
1089402
Country of Publication:
United States
Language:
English

References (17)

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Room-Temperature Molten Salts Based on the Quaternary Ammonium Ion journal October 1998
An Ionic Liquid-Mediated Route to Cerium(III) Bromide Solvates journal May 2011
Controlled Hydrolysis of Lanthanide Complexes of the N-Donor Tripod Tris(2-pyridylmethyl)amine versus Bisligand Complex Formation journal May 2005
Oxidation in Nonclassical Organolanthanide Chemistry:  Synthesis, Characterization, and X-ray Crystal Structures of Cerium(III) and -(IV) Amides journal February 2004
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Synthesis of Heteroleptic Cerium(III) Anionic Amido-Tethered N-Heterocyclic Carbene Complexes journal April 2005
Room temperature ionic liquids of alkylimidazolium cations and fluoroanions journal September 2000
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A short history of SHELX journal December 2007
Hydrophobic ionic liquids patent October 1998
Ionic Liquids for Lanthanide and Actinide Chemistry journal May 2010
Ionic liquid mediated routes to polydentate oxygen-donor adducts of cerium( iii ) bromide journal January 2012

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY