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Title: Monitoring corrosion and chemistry phenomena in supercritical aqueous systems

Book ·
OSTI ID:83100
; ; ;  [1]; ; ;  [2]
  1. Pennsylvania State Univ., University Park, PA (United States). Center for Advanced Materials
  2. Union Electrica Fenosa, S.A., Madrid (Spain). Investigacion y Nuevas Tecnologias

The in situ monitoring of the chemistry and electrochemistry of aqueous heat transport fluids in thermal (nuclear and fossil) power plants is now considered essential if adequate assessment and close control of corrosion and mass transfer phenomena are to be achieved. Because of the elevated temperatures and pressures involved. new sensor technologies are required that are able to measure key parameters under plant operating conditions for extended periods of time. In this paper, the authors outline a research and development program that is designed to develop practical sensors for use in thermal power plants. The current emphasis is on sensors for measuring corrosion potential, pH, the concentrations of oxygen and hydrogen, and the electrochemical noise generated by corrosion processes at temperatures ranging from {approximately}250 C to 500 C. The program is currently at the laboratory stage, but testing of prototype sensors in a coal-fired supercritical power plant in Spain will begin shortly.

OSTI ID:
83100
Report Number(s):
CONF-940222-; TRN: IM9533%%522
Resource Relation:
Conference: Corrosion 94: National Association of Corrosion Engineers (NACE) international annual conference, Baltimore, MD (United States), 28 Feb - 4 Mar 1994; Other Information: PBD: 1994; Related Information: Is Part Of Corrosion/94 conference papers; PB: 5005 p.
Country of Publication:
United States
Language:
English