Reaction of hydroxy and carbonyl compounds with sulfur tetrafluoride. XVI. Reactions of vicinal dihydric alcohols with sulfur tetrafluoride

Journal Article · Thu Nov 20 00:00:00 EST 1986 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6137199

Burmakov, A I; Hassanein, S M; Kunshenko, B V; Alekseeva, L A; Yagupol'skii, L M

During the action of sulfur tetrafluoride on ethanediol, d,l-1,2-propanediol, d,l-3,3,3-trifluoro-1,2-propanediol regioselective substitution of one of the hydroxyl groups by a fluorine atom occurs, depending on the electronic nature of the groups present in the molecule. The second hydroxy group in converted into a fluorosulfite group.

• Research Organization: Odessa Polytechnic Institute, Kiev, USSR
• OSTI ID: 6137199
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Vol. 22:6; Other Information: Translated from Zh. Org. Khim.; 22: No. 6, 1273-1276(Jun 1986)
• Country of Publication: United States
• Language: Russian

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PHYSICAL AND ANALYTICAL CHEMISTRY
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NMR SPECTRA
GLYCOLS
FLUORINATION
SULFITES
SULFUR FLUORIDES
ACTIVATION ENERGY
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ELECTRON TRANSFER
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HYDROGEN 1
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MOLECULAR STRUCTURE
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VALENCE
ALCOHOLS
CHEMICAL REACTIONS
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DECOMPOSITION
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FLUORINE ISOTOPES
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
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HYDROXY COMPOUNDS
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ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
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OXYGEN COMPOUNDS
SEPARATION PROCESSES
SOLVOLYSIS
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STABLE ISOTOPES
SULFUR COMPOUNDS
YIELDS
400201* - Chemical & Physicochemical Properties
640302 - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory