Microcalorimetric determination of the thermodynamics of formation of the mono- and bi-sulfato complexes of lanthanum in aqueous solutions between 25 and 55 degrees C
Journal Article
·
· J. Solution Chem.; (United States)
Using a differential microcalorimeter, the formation constants and enthalpies of formation of the mono- and bi-sulfato complexes of lanthanum ion have been evaluated for aqueous acidic solutions over a temperature range of 25 to 55/sup 0/C.
- Research Organization:
- Clarkson Univ., Potsdam, NY
- OSTI ID:
- 6042919
- Journal Information:
- J. Solution Chem.; (United States), Vol. 16:5
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
LANTHANUM COMPLEXES
CALORIMETRY
FORMATION HEAT
LANTHANUM SULFATES
AQUEOUS SOLUTIONS
LEAST SQUARE FIT
MEDIUM TEMPERATURE
PH VALUE
VALENCE
COMPLEXES
DISPERSIONS
ENTHALPY
LANTHANUM COMPOUNDS
MAXIMUM-LIKELIHOOD FIT
MIXTURES
NUMERICAL SOLUTION
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
RARE EARTH COMPLEXES
RARE EARTH COMPOUNDS
REACTION HEAT
SOLUTIONS
SULFATES
SULFUR COMPOUNDS
THERMODYNAMIC PROPERTIES
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
LANTHANUM COMPLEXES
CALORIMETRY
FORMATION HEAT
LANTHANUM SULFATES
AQUEOUS SOLUTIONS
LEAST SQUARE FIT
MEDIUM TEMPERATURE
PH VALUE
VALENCE
COMPLEXES
DISPERSIONS
ENTHALPY
LANTHANUM COMPOUNDS
MAXIMUM-LIKELIHOOD FIT
MIXTURES
NUMERICAL SOLUTION
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
RARE EARTH COMPLEXES
RARE EARTH COMPOUNDS
REACTION HEAT
SOLUTIONS
SULFATES
SULFUR COMPOUNDS
THERMODYNAMIC PROPERTIES
400201* - Chemical & Physicochemical Properties