Liquid-phase catalytic oxidation of CO by ammonium persulfate

Journal Article · Sun Jan 01 00:00:00 EST 1984 · Dokl. Phys. Chem. (Engl. Transl.); (United States)

OSTI ID:5940641

Golodov, V A; Abilov, M T; Sokol'skii, D V

The catalytic oxidation of carbon monoxide in aqueous solutions is investigated. The abilities of ammonium persulfate, palladium hydroxide, and silver oxide to force the oxidation are discussed. The rates for these reactions are displayed graphically. The reaction rates as a function of the concentrations of the above-mentioned reactants are determined. An excess of persulfate is found to oxidize Pd(II) to Pd(IV), and this produces a reduction in the rate of CO oxidation. The oxidation of CO is preceeded in the reaction by the interaction of the persulfate with the metal catalyst.

• Research Organization: Inst. of Organic Catalysis and Electrochemistry, Alma-Ata, USSR
• OSTI ID: 5940641
• Journal Information: Dokl. Phys. Chem. (Engl. Transl.); (United States), Vol. 274:1-3; Other Information: Translated from Dokl. Adad. Nauk SSSR; 274: No. 3, 629-632(Jan 1984)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBON MONOXIDE
OXIDATION
AMMONIUM COMPOUNDS
AQUEOUS SOLUTIONS
CHEMICAL REACTION KINETICS
PALLADIUM HYDROXIDES
PERSULFATES
SILVER OXIDES
CARBON COMPOUNDS
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
DISPERSIONS
HYDROGEN COMPOUNDS
HYDROXIDES
KINETICS
MIXTURES
OXIDES
OXYGEN COMPOUNDS
PALLADIUM COMPOUNDS
REACTION KINETICS
SILVER COMPOUNDS
SOLUTIONS
SULFUR COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
400201* - Chemical & Physicochemical Properties