Distribution of LiCl, NaCl, KCl, HCl, MgCl sub 2 , and CaCl sub 2 between octanol and water
Journal Article
·
· Environmental Science and Technology; (USA)
- Oregon State Univ., Corvallis (USA)
The distributions of LiCl, NaCl, KCl, HCl, MgCl{sub 2}, and CaCl{sub 2} between octanol and water were determined for concentrations of the salts in the aqueous phase between 0.01 and 1 M. Evidence for both ion pairs and free ions in the water-saturated octanol was seen. For calculation of the equilibrium constants, mean salt activity coefficients in the aqueous phase were determined through the equations of Pitzer, and activity coefficients in the organic phase were set equal to unity, consistent with the very low concentrations. The specific conductivity of the organic phase was determined and found to be consistent with the speciation determined from the distributions.
- DOE Contract Number:
- AC06-76RL01830
- OSTI ID:
- 5868506
- Journal Information:
- Environmental Science and Technology; (USA), Vol. 24:12; ISSN 0013-936X
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
54 ENVIRONMENTAL SCIENCES
CALCIUM CHLORIDES
REACTION KINETICS
THERMODYNAMIC ACTIVITY
HYDROCHLORIC ACID
LITHIUM CHLORIDES
MAGNESIUM CHLORIDES
POTASSIUM CHLORIDES
SODIUM CHLORIDES
AQUEOUS SOLUTIONS
EXPERIMENTAL DATA
ION PAIRS
MEASURING METHODS
OCTANOLS
SOLUBILITY
WATER
ALCOHOLS
ALKALI METAL COMPOUNDS
ALKALINE EARTH METAL COMPOUNDS
CALCIUM COMPOUNDS
CALCIUM HALIDES
CHLORIDES
CHLORINE COMPOUNDS
DATA
DISPERSIONS
HALIDES
HALOGEN COMPOUNDS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
INFORMATION
INORGANIC ACIDS
KINETICS
LITHIUM COMPOUNDS
LITHIUM HALIDES
MAGNESIUM COMPOUNDS
MIXTURES
NUMERICAL DATA
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
POTASSIUM COMPOUNDS
SODIUM COMPOUNDS
SOLUTIONS
540310* - Environment
Aquatic- Basic Studies- (1990-)
540210 - Environment
Terrestrial- Basic Studies- (1990-)
CALCIUM CHLORIDES
REACTION KINETICS
THERMODYNAMIC ACTIVITY
HYDROCHLORIC ACID
LITHIUM CHLORIDES
MAGNESIUM CHLORIDES
POTASSIUM CHLORIDES
SODIUM CHLORIDES
AQUEOUS SOLUTIONS
EXPERIMENTAL DATA
ION PAIRS
MEASURING METHODS
OCTANOLS
SOLUBILITY
WATER
ALCOHOLS
ALKALI METAL COMPOUNDS
ALKALINE EARTH METAL COMPOUNDS
CALCIUM COMPOUNDS
CALCIUM HALIDES
CHLORIDES
CHLORINE COMPOUNDS
DATA
DISPERSIONS
HALIDES
HALOGEN COMPOUNDS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
INFORMATION
INORGANIC ACIDS
KINETICS
LITHIUM COMPOUNDS
LITHIUM HALIDES
MAGNESIUM COMPOUNDS
MIXTURES
NUMERICAL DATA
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
POTASSIUM COMPOUNDS
SODIUM COMPOUNDS
SOLUTIONS
540310* - Environment
Aquatic- Basic Studies- (1990-)
540210 - Environment
Terrestrial- Basic Studies- (1990-)