Method of concurrent reactions to describe Friedel-Crafts benzylation

Journal Article · Tue Dec 01 00:00:00 EST 1987 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:5251723

Kondratova, G B; Kondratov, S A; Shein, S M

It has been demonstrated that the dependence of the relative rates of reaction of benzyl chloride with toluene and benzene versus the concentration of catalyst, an AlCl/sub 3/ x CH/sub 3/NO/sub 2/ complex, can be explained quantitatively based on the assumption that the catalyst can exist in solution in two forms, monomeric and dimeric.

• OSTI ID: 5251723
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Vol. 28:3; Other Information: Translated from Kinet. Katal.; 28: No. 3, 730-732(May-Jun 1987)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALUMINIUM CHLORIDES
CATALYTIC EFFECTS
BENZENE
FRIEDEL-CRAFTS REACTION
CHLORINATED AROMATIC HYDROCARBONS
NITROMETHANE
TOLUENE
CATALYSIS
CATALYSTS
CHEMICAL REACTION KINETICS
KINETIC EQUATIONS
MATHEMATICAL MODELS
QUANTITY RATIO
ALKYLATED AROMATICS
ALUMINIUM COMPOUNDS
AROMATICS
CHEMICAL EXPLOSIVES
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
EQUATIONS
EXPLOSIVES
HALIDES
HALOGEN COMPOUNDS
HALOGENATED AROMATIC HYDROCARBONS
HYDROCARBONS
KINETICS
NITRO COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
REACTION KINETICS
400201* - Chemical & Physicochemical Properties