Anodic electrosynthesis of some peroxy compounds on glassy carbon electrodes

Journal Article · Tue Nov 10 00:00:00 EST 1987 · J. Appl. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5023107

Khomutov, N E; Zakhodyakina, N A; Svirida, L V; Nesvat, N V

The authors present the results of a study of the anodic electrosynthesis of hydrogen peroxide and its derivatives on glassy carbon in solutions of sodium carbonate and sodium carbonate with sodium borate. We studied the kinetics of anodic processes on glassy carbon with the aid of polarization measurements and a method for determining the concentrations of active oxygen in the anolyte and the current efficiency. The current efficiencies with respect to active oxygen obtained on glassy carbon in the mixed solution of sodium borate and sodium carbonate are close to the current efficiencies which are observed on platinum anodes in the industrial electrosynthesis of perborates.

• Research Organization: D. I. Mendeleev Moscow Chemical Technology Institute (USSR)
• OSTI ID: 5023107
• Journal Information: J. Appl. Chem. USSR (Engl. Transl.); (United States), Vol. 60:5; Other Information: Translated from Zh. Prikl. Khim.; 60: No. 5, 1185-1188(May 1987)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION
CARBON
CATALYTIC EFFECTS
CURRENT DENSITY
ELECTROCATALYSTS
MATERIALS TESTING
ELECTROLYTIC CELLS
ENERGY EFFICIENCY
GLASS
PEROXIDES
SYNTHESIS
BORATES
COMPARATIVE EVALUATIONS
DESORPTION
ELECTRIC POTENTIAL
ELECTRODES
ELECTROLYTES
HETEROGENEOUS CATALYSIS
HYDROGEN PEROXIDE
OXYGEN
PLATINUM
SODIUM CARBONATES
ALKALI METAL COMPOUNDS
BORON COMPOUNDS
CARBON COMPOUNDS
CARBONATES
CATALYSIS
CATALYSTS
EFFICIENCY
ELEMENTS
HYDROGEN COMPOUNDS
METALS
NONMETALS
OXYGEN COMPOUNDS
PLATINUM METALS
SODIUM COMPOUNDS
TESTING
TRANSITION ELEMENTS
400201* - Chemical & Physicochemical Properties
320302 - Energy Conservation
Consumption
& Utilization- Industrial & Agricultural Processes- Materials