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Title: Isomerization of 1,4-dioxane under the effect of {gamma}-radiation

Journal Article · · High Energy Chemistry
OSTI ID:255665
; ; ;  [1]
  1. D.I. Mendeleev Moscow Chemicotechnological Institute (Russian Federation)

Data were presented previously on the composition of products of {gamma}-radiolysis of 1,4-dioxane. The main products are called H{sub 2} and a polymer, the radiation yield of which does not exceed 1.5-3.5 molecules per 100 eV. Gaseous hydrocarbons and CO were identified in small amounts. The authors studied in detail the reaction mixture obtained as a result of radiation-chemical transformations of 1,4-dioxane (reaction time 10-15 h and temperature 130-150{degrees}C) by chromatography-mass spectrometry.

OSTI ID:
255665
Journal Information:
High Energy Chemistry, Vol. 26, Issue 2; Other Information: PBD: Sep 1992; TN: Translated from Khimiya Vysokikh Energii; 26: No. 2, 188-189(Mar-Apr 1992)
Country of Publication:
United States
Language:
English